秸秆生物炭处理含砷废水的研究
Study on the Treatment of Arsenic-Containing Wastewater with Straw Biochar
DOI: 10.12677/AEP.2021.116144, PDF,    科研立项经费支持
作者: 袁峰平, 成 岳*, 牛海亮, 曹 婷, 朱海杰:景德镇陶瓷大学材料科学与工程学院,江西 景德镇;江嘉翔, 段俊玲:景德镇艺术职业大学,江西 景德镇
关键词: 秸秆生物炭水处理Straw Biochar Arsenic Water Treatment
摘要: 面对日益严重的水污染问题,本文以生物质秸秆为原材料对含砷废水进行处理。在300℃、400℃、500℃进行热解制备生物炭,探讨生物炭在含砷废水中的吸附机理。实验结果表明,在pH = 5时,生物炭对As (V)的去除率达到74.7%,随着pH的继续增大,去除效率逐渐变差;随着温度的不断上升,去除效率不断增大,在65℃的时候对As (V)的去除率达到69.7%。表明温度的变化和去除效率基本成正比;随着投加量的不断变大,去除率随之不断增大,BC400在投加量为1.5 g/L的条件下,去除率为96.3%。表明投加量的变大和吸附效率也是成正比。
Abstract: Facing the increasingly serious water pollution problem, this article uses biomass straw As (V) raw material to treat arsenic-containing wastewater and discusses the removal mechanism of arsenic in arsenic-containing wastewater with preparation of biochar by pyrolysis at 300˚C, 400˚C, 500˚C. The results show that the adsorption capacity of biochar to arsenic reaches the maximum at pH = 5 and the removal rate of As (V) by biochar reached 74.7%. As the pH continues to increase, the removal efficiency gradually deteriorates. As the temperature continues to rise, the removal efficiency continues to increase, and the removal rate of As (V) reaches 69.7% at 65˚C. That shows the temperature change is basically proportional to the removal efficiency. As the dosage increases, the removal rate increases accordingly. When the dosage of BC400 is 1.5g/L, the removal rate is 96.3%, indicating that the increase in dosage is directly proportional to the adsorption efficiency.
文章引用:袁峰平, 成岳, 牛海亮, 曹婷, 朱海杰, 江嘉翔, 段俊玲. 秸秆生物炭处理含砷废水的研究[J]. 环境保护前沿, 2021, 11(6): 1190-1200. https://doi.org/10.12677/AEP.2021.116144

参考文献

[1] 黄益宗, 郝晓伟, 雷鸣, 铁柏清. 重金属污染土壤修复技术及其修复实践[J]. 农业环境科学学报, 2013, 32(3): 409-417.
[2] 陈能场, 郑煜基, 何晓峰, 等. 《全国土壤污染状况调查公报》探析[J]. 农业环境科学学报, 2017, 36(9): 1689-1692.
[3] 谢小林, 李如旭, 殷亮, 朱刘. 高浓度含砷废水处理的实验研究[J]. 化工技术与开发, 2021, 50(5): 71-73.
[4] 李凤英. 发砷作为环境中砷危害健康评价指标的研究[J]. 环境与健康杂志, 1984(4): 29-30.
[5] Hayes, M.H. (2006) Biochar and Biofuels for a Brighter Future. Nature, 443, 144. [Google Scholar] [CrossRef] [PubMed]
[6] Haghighatjou, M. and Shirvani, M. (2020) Sugarcane BagAsse Biochar: Preparation, Characterization, and Its Effects on Soil Properties and Zinc Sorption-Desorption. Communications in Soil Science and Plant Analysis, 51, 1391-1405. [Google Scholar] [CrossRef
[7] 王璐瑶, 谢潇. 生物炭的制备及应用研究进展[J]. 农业与技术, 2020, 40(22): 34-36.
[8] 崔梦, 李佳琳, 巨龙, 张志. 生物炭、磁性炭的制备与应用研究进展[J]. 安徽农学通报, 2021, 27(8): 89-93.
[9] Yang, F., Wang, C. and Sun, H. (2021) A Comprehensive Review of Biochar-Derived Dissolved Matters in Biochar Application: Production, Characteristics, and Potential Environmental Effects and Mechanisms. Journal of Environmental Chemical Engineering, 9, Article ID: 105258. [Google Scholar] [CrossRef
[10] 李胜红, 朱芬芬. 原污泥与脱脂污泥制备生物炭的比较及其特性研究[J/OL]. 环境工程, 2021: 1-9.
http://kns.cnki.net/kcms/detail/11.2097.X.20210621.0917.002.html, 2021-10-20.
[11] 季雪琴, 吕黎, 陈芬, 杨春平. 秸秆生物炭对有机染料的吸附作用及机制[J]. 环境科学学报, 2016, 36(5): 1648-1654.
[12] 郭家骏. 污泥基生物炭的制备及其改性材料对水体中有机砷的吸附性能研究[D]: [硕士学位论文]. 湖南农业大学, 2019.
[13] 刘喜, 敖鸿毅, 刘剑彤. 铁改性竹炭去除水中的As(Ⅲ)和As(Ⅴ) [J]. 环境工程学报, 2012, 6(9): 2958-2962.
[14] 李景心, 唐东山, 许婉冰, 王宝茹. 磁性生物炭对镉、砷的吸附效果研究[J]. 现代化工, 2020, 40(7): 160-165.
[15] 刘玉玲, 朱虎成, 彭鸥, 李丹阳, 杨蕊嘉, 彭晶, 铁柏清. 玉米秸秆生物炭固化细菌对镉砷吸附[J]. 环境科学, 2020, 41(9): 4322-4332.
[16] 董双快, 贾宏涛, 吴福飞. 改性生物炭的光谱表征及砷的吸附效果研究[J]. 水资源与水工程学报, 2020, 31(5): 51-55+61.