埋地管道防腐涂层破裂时的钢材腐蚀模拟研究
Simulation Study on Steel Corrosion of Buried Pipeline When Anticorrosion Coating Is Broken
DOI: 10.12677/JOGT.2021.434080, PDF,   
作者: 王泽琦*, 王进波:中国石油管道局工程有限公司国际事业部,河北 廊坊;李韵丽:石钢京诚装备技术有限公司,辽宁 营口
关键词: 有限元模拟管道外腐蚀3PE防腐涂层应力腐蚀模型Finite Element Simulation Pipeline Corrosion 3PE Coating Stress Corrosion Model
摘要: 本文运用有限元模拟软件分析埋地管道在不同纵向应变和腐蚀缺陷深度下的腐蚀规律,探究在埋地环境下的腐蚀行为并给出腐蚀机理与建立CO2与O2腐蚀的协同作用模型。通过有限元模拟结果表明:随着纵向应变的逐渐增加,von Mises应力不断增大且向腐蚀缺陷中心集中,此时由于塑性变形导致阴极反应被加强,腐蚀电流密度也逐渐增大,在管壁与3PE防腐层交界处达到最大;随着腐蚀缺陷的逐渐加深,von Mises应力也不断增大并集中在整个缺陷方向,有向缺陷外延展的趋势,腐蚀电流密度分布不均匀,3PE防腐层与管壁交界处分布最集中,此处腐蚀最严重。
Abstract: Finite element simulation software is used to analyze the corrosion laws of buried pipelines under different longitudinal strains and corrosion defect depths, explore the corrosion behavior in the buried environment, give the corrosion mechanism and establish the CO2 and O2 corrosion synergistic model. The results of finite element simulation show that the von Mises stress increases and focuses on the center of the corrosion defect with the increasing of the longitudinal strain. At the same time, the corrosion current density increases gradually due to the strengthening of the cathode due to the plastic deformation, and reaches the maximum at the junction between the tube wall and the 3PE coating. With the gradual deepening of the corrosion defects, von Mises stress increased and concentrated in the whole direction of the defects; with the trend of the extension of the defects, the distribution of corrosion current density is not uniform; and the junction of 3PE corrosion coating and pipe wall is the most concentrated, where the corrosion is the most serious.
文章引用:王泽琦, 李韵丽, 王进波. 埋地管道防腐涂层破裂时的钢材腐蚀模拟研究[J]. 石油天然气学报, 2021, 43(4): 115-122. https://doi.org/10.12677/JOGT.2021.434080

参考文献

[1] 崔文岩. 浅析长距离输油管道的腐蚀[J]. 中国化工贸易, 2018, 10(2): 20.
[2] 杨晶华, 卜星淇. 输气管道的腐蚀与防腐[J]. 石化技术, 2018, 25(2): 1.
[3] 杨怀玉, 陈家坚, 曹楚南. H2S水溶液中的腐蚀与缓蚀作用机理的研究III. 不同pH值H2S溶液中碳钢的腐蚀电化学行为[J]. 中国腐蚀与防护学报, 2000, 20(2): 97-104.
[4] 符传福, 杨丙坤, 杨大宁, 等. 海南土壤中Q235钢的杂散电流腐蚀[J]. 腐蚀与防护, 2017, 38(10): 756-760, 766.
[5] Sun, D., Ming, W. and Fei, X. (2018) Effect of Sulfate-Reducing Bacteria and Cathodic Potential on Stress Corrosion Cracking of X70 Steel in Sea-Mud Simulated Solution. Materials Science and Engineering A, 721, 135-144. [Google Scholar] [CrossRef
[6] Wang, D., Xie, F., Wu, M., et al. (2017) The Effect of Sul-fate-Reducing Bacteria on Hydrogen Permeation of X80 Steel under Cathodic Protection Potential. International Journal of Hydrogen Energy, 42, 27206-27213. [Google Scholar] [CrossRef
[7] 张洁娜. 石油管道工程的防腐技术分析[J]. 化工管理, 2019(19): 55.
[8] Cheng, Y.F. and Xu, L.Y. (2013) Development of a Finite Element Model for Simulation and Prediction of Mechano-Electrochemical Effect of Pipeline Corrosion. Corrosion Science, 73, 150-160.
[9] 翟心心. 岩溶区土壤CO2浓度和土壤酶活性的变化规律及其关系——以重庆青木关岩溶槽谷为例[D]: [硕士学位论文]. 重庆: 西南大学, 2011.
[10] Gutman, E.M. (1994) Mechanochemistry of Solid Surfaces. World Scientific Publication, Singapore. [Google Scholar] [CrossRef
[11] Xu, L.Y. and Cheng, Y.F. (2012) Corrosion of X100 Pipeline Steel under Plastic Strain in a Neutral pH Bicarbonate Solution. Corrosion Science, 64, 145-152. [Google Scholar] [CrossRef
[12] Starosvetsky, J., Armon, R., Starosvetsky, D., et al. (1999) Fouling of Carbon Steel Heat Exchanger Caused by Iron Bacteria. Materials Performance, 38, 55-62.
[13] Wei, L., Pang, X., Liu, C., et al. (2015) Formation Mechanism and Protective Property of Corrosion Product Scale on X70 Steel under Supercritical CO2 Environment. Corrosion Science, 100, 404-420. [Google Scholar] [CrossRef
[14] 谢飞, 王丹, 吴明, 孙东旭, 王宸, 任胜华. 溶解氧对X80管线钢腐蚀行为的影响及其机制[J]. 钢铁研究学报, 2015, 27(3): 60-64.
[15] Song, F.M., Kirk, D.W., Graydon, J.W., et al. (2002) CO2 Corrosion of Bare Steel under an Aqueous Boundary Layer with Oxygen. Cheric, 49, 479-486. [Google Scholar] [CrossRef
[16] Ruhl, A.S. and Kranzmann, A. (2013) Investigation of Corrosive Effects of Sulphur Dioxide, Oxygen and Water Vapour on Pipeline Steels. International Journal of Greenhouse Gas Control, 13, 9-16. [Google Scholar] [CrossRef
[17] Zhang, Y., Pang, X., Qu, S., et al. (2012) Discussion of the CO2 Corrosion Mechanism between Low Partial Pressure and Supercritical Condition. Corrosion Science, 59, 186-197. [Google Scholar] [CrossRef