Ti-MWW分子筛的合成进展
Progress in Synthesis of Ti-MWW
DOI: 10.12677/AAC.2022.122006, PDF,   
作者: 徐 稳*, 汪晓淑, 侯威龙:浙江师范大学含氟新材料研究所,浙江 金华
关键词: Ti-MWW分子筛合成改性Ti-MWW Zeolite Synthesis Modify
摘要: Ti-MWW分子筛的合成方法主要包括后处理合成法、水热合成法、干胶合成法和双模板合成法。通过对Ti-MWW分子筛改性,可以提高其催化性能,特别是在选择性氧化反应中表现出优异的催化活性。本文总结了Ti-MWW分子筛的合成方法及其改性方法。
Abstract: The synthesis methods of Ti-MWW zeolites mainly include post-synthesis, hydrothermal synthesis, dry gel conversion and dual structure-directing agents synthesis. The modification of Ti-MWW can improve catalytic performance, especially in selective oxidations. The synthesis and modification methods of Ti-MWW are summarized in this paper.
文章引用:徐稳, 汪晓淑, 侯威龙. Ti-MWW分子筛的合成进展[J]. 分析化学进展, 2022, 12(2): 41-46. https://doi.org/10.12677/AAC.2022.122006

参考文献

[1] Taramasso, M.P.G. and Notari, B. (1983) Preparation of Porous Crystalline Synthetic Material Comprised of Silicon and Titanium Oxides. United States Patent 4410501.
[2] Thangaraj, A., Kumar, R. and Ratnasamy, P. (1991) Catalytic Properties of Crystalline Titanium Silicalites. II, Hydroxylation of Phenol with Hydrogen Peroxide over TS-1 Zeolites. Journal of Catalysis, 131, 294-297.
[Google Scholar] [CrossRef
[3] Tuel, A., Moussa-Khouzami, S., Taarit, Y.B. and Naccache, C. (1991) Hydroxylation of Phenol over TS-1: Surface and Solvent Effects. Journal of Molecular Catalysis, 68, 45-52.
[Google Scholar] [CrossRef
[4] Gleeson, D., Sankar, G., Catlow, C.R.A., Thomas, J.M., Spanó, G., Bordiga, S., Zecchina, A. and Lamberti, C. (2000) The Architecture of Catalytically Active Centers in Titanosilicate (TS-1) and Related Selective-Oxidation Catalysts. Physical Chemistry Chemical Physics, 2, 4812-4817.
[Google Scholar] [CrossRef
[5] Jiao, W., He, Y., Li, J., Wang, J., Tatsumi, T. and Fan, W. (2015) Ti-Rich TS-1: A Highly Active Catalyst for Epoxidation of Methallyl Chloride to 2-Methyl Epichlorohydrin. Applied Catalysis A: General, 491, 78-85.
[Google Scholar] [CrossRef
[6] Pozzo, L., Fornasari, G. and Monti, T. (2002) TS-1 Catalytic Mechanism in Cyclohexanone Oxime Production. Catalysis Communications, 3, 369-375.
[Google Scholar] [CrossRef
[7] Li, Z., Chen, R., Xing, W., Jin, W. and Xu, N. (2010) Continuous Acetone Ammoximation over TS-1 in a Tubular Membrane Reactor. Industrial & Engineering Chemistry Research, 49, 6309-6316.
[Google Scholar] [CrossRef
[8] Reddy, J.S. and Jacobs, P.A. (1996) Selective Oxidation of Secondary Amines over Titanium Silicalite Molecular Sieves, TS-1 and TS-2. Catalysis Letters, 37, 213-216.
[Google Scholar] [CrossRef
[9] Gontier, S. and Tuel, A. (1994) Oxidation of Aniline over TS-1, the Titanium Substituted Silicalite-1. Applied Catalysis A: General, 118, 173-186.
[Google Scholar] [CrossRef
[10] Leonowicz, M.E., Lawton, J.A., Lawton, S.L. and Rubin, M.K. (1994) MCM-22: A Molecular Sieve with Two Independent Multidimensional Channel Systems. Science, 264, 1910-1913.
[Google Scholar] [CrossRef] [PubMed]
[11] Lawton, S.L., Leonowicz, M.E., Partridge, R.D., Chu, P. and Rubin, M.K. (1998) Twelve-Ring Pockets on the External Surface of MCM-22 Crystals. Microporous and Mesoporous Materials, 23, 109-117.
[Google Scholar] [CrossRef
[12] Yin, J., Xu, H., Wang, B., Tian, W., Yin, J., Jiang, J. and Wu, P. (2020) Highly Selective 1-Pentene Epoxidation over Ti-MWW with Modified Micro-Environment of Ti Active Sites. Catalysis Science & Technology, 10, 6050-6064.
[Google Scholar] [CrossRef
[13] Wu, P., Nuntasri, D., Liu, Y., Wu, H., Jiang, Y., Fan, W., He, M. and Tatsumi, T. (2006) Selective Liquid-Phase Oxidation of Cyclopentene over MWW Type Titanosilicate. Catalysis Today, 117, 199-205.
[Google Scholar] [CrossRef
[14] Tang, K., Hou, W., Wang, X., Xu, W., Lu, X., Ma, R., Fu, Y. and Zhu, W. (2021) Enhanced Catalytic Performance of Trimethylsilylated Ti-MWW Zeolites for the Liquid-Phase Epoxidation of Propylene with H2O2. Microporous and Mesoporous Materials, 328, 111492-111501.
[Google Scholar] [CrossRef
[15] Huo, Y., Zhang, Y., Xu, W., Tang, K., Lu, X., Ma, R., Fu, Y. and Zhu, W. (2020) Acid-Modulated Synthesis of Ti-MWW Zeolites with Rich Framework Ti Species for Efficient Epoxidation. Industrial & Engineering Chemistry Research, 59, 19929-19937.
[Google Scholar] [CrossRef
[16] Ding, J., Xu, L., Yu, Y., Wu, H., Huang, S., Yang, Y. and Wu, J. (2013) Clean Synthesis of Acetaldehyde Oxime through Ammoximation on Titanosilicate Catalysts. Catalysis Science & Technology, 3, 2587-2595.
[Google Scholar] [CrossRef
[17] Ding, J. and Wu, P. (2014) Selective Synthesis of Dimethyl Ketone Oxime through Ammoximation over Ti-MOR Catalyst. Applied Catalysis A: General, 488, 86-95.
[Google Scholar] [CrossRef
[18] Gao, G., Cheng, S., An, Y., Si, X., Fu, X., Liu, Y., Zhang, H., Wu, P. and He, M.Y. (2010) Oxidative Desulfurization of Aromatic Sulfur Compounds over Titanosilicates. ChemCatChem, 2, 459-466.
[Google Scholar] [CrossRef
[19] Xie, W., Zheng, Y., Zhao, S., Yang, J., Liu, Y. and Wu, P. (2010) Selective Oxidation of Pyridine to Pyridine-N-Oxide with Hydrogen Peroxide over Ti-MWW Catalyst. Catalysis Today, 157, 114-118.
[Google Scholar] [CrossRef
[20] Levin, D., Cynwyd, B. and Chang, C.D., et al. (2000) Olefin Epoxidation Catalysts. United States Patent 6114551.
[21] Wu, P. and Tatsumi, T. (2002) Preparation of B-Free Ti-MWW through Reversible Structural Conversion. Chemical Communications, 10, 1026-1027.
[Google Scholar] [CrossRef] [PubMed]
[22] Yan, M., Jin, F., Ding, Y., Wu, G., Chen, R., Wang, L. and Yan, Y. (2019) Synthesis of Titanium-Incorporated MWW Zeolite by Sequential Deboronation and Atom-Planting Treatment of ERB-1 as an Epoxidation Catalyst. Industrial & Engineering Chemistry Research, 58, 4764-4773.
[Google Scholar] [CrossRef
[23] Wu, P., Tatsumi, T., Komatsu, T. and Yashima, T. (2001) A Novel Titanosilicate with MWW Structure. I. Hydrothermal Synthesis, Elimination of Extraframework Titanium, and Characterizations. The Journal of Physical Chemistry B, 105, 2897-2905.
[Google Scholar] [CrossRef
[24] Wu, P., Tatsumi, T., Komatsu, T. and Tatsuaki, Y. (2000) Hydrothermal Synthesis of a Novel Titanosilicate with MWW Topoloy. Chemistry Letters, 29, 774-775.
[Google Scholar] [CrossRef
[25] Wang, Y., Zhou, D., Yang, G., Miao, S., Liu, X. and Bao, X. (2004) A DFT Study on Isomorphously Substituted MCM-22 Zeolite. The Journal of Physical Chemistry A, 108, 6730-6734.
[Google Scholar] [CrossRef
[26] Zhou, D., Zhang, H., Zhang, J., Sun, X., Li, H., He, N. and Zhang, W. (2014) Density Functional Theory Investigations into the Structure and Spectroscopic Properties of the Ti4+ Species in Ti-MWW Zeolite. Microporous and Mesoporous Materials, 195, 216-226.
[Google Scholar] [CrossRef
[27] Wu, P., Miyaji, T., Liu, Y., He, M. and Tatsumi, T. (2005) Synthesis of Ti-MWW by a Dry-Gel Conversion Method. Catalysis Today, 99, 233-240.
[Google Scholar] [CrossRef
[28] Camblor, M.A., Corma, A. and Díaz-Cabañas, M.J. (1998) Synthesis and Structural Characterization of MWW Type Zeolite ITQ-1, the Pure Silica Analog of MCM-22 and SSZ-25. The Journal of Physical Chemistry B, 102, 44-51.
[Google Scholar] [CrossRef
[29] Liu, N., Liu, Y., Xie, W., Wang, L., He, M. and Wu, P. (2007) Hydrothermal Synthesis of Boron-Free Ti-MWW with Dual Structure-Directing Agents. Studies in Surface Science and Catalysis, 170, 464-469.
[Google Scholar] [CrossRef
[30] Lu, X., Zhou, W.J., Guan, Y., Liebens, A. and Wu, P. (2017) Enhancing Ethylene Epoxidation of a MWW-Type Titanosilicate/H2O2 Catalytic System by Fluorine Implanting. Catalysis Science & Technology, 7, 2624-2631.
[Google Scholar] [CrossRef
[31] Zhao, H., Yokoi, T., Kondo, J.N. and Tatsumi, T. (2015) Hydrophobicity Enhancement of Ti-MWW Catalyst and Its Improvement in Oxidation Activity. Applied Catalysis A: General, 503, 156-164.
[Google Scholar] [CrossRef
[32] Yu, Y., Tang, Z., Liu, W., Wang, J., Chen, Z., Shen, K., Wang, R., Liu, H., Huang, X. and Liu, Y. (2019) Enhanced Catalytic Oxidation Performance of K+-Modified Ti-MWW through Selective Breaking of Interfacial Hydrogen-Bonding Interactions of H2O2. Applied Catalysis A: General, 587, Article ID: 117270.
[Google Scholar] [CrossRef
[33] Wang, L., Wang, Y., Liu, Y., Wu, H., Li, X., He, M. and Wu, P. (2009) Alkoxysilylation of Ti-MWW Lamellar Precursors into Interlayer Pore-Expanded Titanosilicates. Journal of Materials Chemistry, 19, 8594-8602.
[Google Scholar] [CrossRef