RFe12基稀土永磁材料的研究进展
Recent Advances in RFe12-Based Permanent Magnets
DOI: 10.12677/MS.2022.124028, PDF,    科研立项经费支持
作者: 郭家瑞, 王亚娜, 宋文鹏, 郑立允, 黄光伟*:河北工程大学材料科学与工程学院,河北 邯郸;河北省稀土永磁材料与应用工程研究中心,河北 邯郸
关键词: 永磁材料ThMn12块体磁性能Permanent Magnets ThMn12 Bulk Magnetic Properties
摘要: 为了实现社会的可持续发展,响应“双碳”目标的号召,助力“双碳”目标的达成,迫切需要具有低CO2或无CO2排放的绿色技术。永磁材料作为绿色技术的关键材料被广泛应用于风力发电、轨道交通、人工智能等技术领域。为了提高这些技术在应用过程中的电力转换效率,需要一种比NdFeB永磁材料性能更优异的永磁材料。具有ThMn12晶体结构的RFe12 (R为稀土元素,一般为Sm)基化合物即是有潜力满足当前绿色技术发展的永磁材料。本文将对RFe12基稀土永磁材料的相稳定性、磁性能,RFe12基薄膜、粉体及块体磁体的研究进展进行综述。最后,结合目前RFe12基稀土永磁材料的研究现状,提出一种适合于块体RFe12基稀土永磁材料制备的技术手段并对其进行探讨。
Abstract: In order to realize sustainable development of the society, respond to the call of the “dual carbon” goal and help achieve the “dual carbon” goal, green technologies with low or no CO2 emissions are urgently needed. As the key material of green technologies, permanent magnetic materials are widely used in wind power generation, rail transit, artificial intelligence and other technical fields. In order to enhance the power conversion efficiency of these technologies in the application process, a new type of permanent magnetic material with better performance than NdFeB permanent magnetic material is urgently needed. RFe12 (R stands for rare earth elements, usually Sm) based compound with ThMn12 crystal structure is a permanent magnetic material that has the potential to meet the development of current green technologies. In this review, the phase stability and magnetic properties of RFe12-based rare earth permanent magnetic materials, as well as the research progress of RFe12-based thin films, powders and bulk magnets are reviewed. Finally, according to the current research status of RFe12-based rare earth permanent magnetic material, a novel technology suitable for the preparation of bulk RFe12-based rare earth permanent magnet material is proposed and discussed.
文章引用:郭家瑞, 王亚娜, 宋文鹏, 郑立允, 黄光伟. RFe12基稀土永磁材料的研究进展[J]. 材料科学, 2022, 12(4): 269-282. https://doi.org/10.12677/MS.2022.124028

参考文献

[1] Gutfleisch, O., Willar, M.A., Brück, E., Chen, C.H., Sankar, S.G. and Liu, J.P. (2011) Magnetic Materials and Devices for the 21st Century: Stronger, Lighter, and More Energy Efficient. Advanced Materials, 23, 821-842. [Google Scholar] [CrossRef] [PubMed]
[2] Trench, A. and Sykes, J.P. (2020) Rare Earth Permanent Magnets and Their Place in the Future Economy. Engineering, 6, 115-118. [Google Scholar] [CrossRef
[3] Coey, J.M.D. (2020) Perspective and Prospects for Rare Earth Permanent Magnets. Engineering, 6, 119-131. [Google Scholar] [CrossRef
[4] Sagawa, M., Fujimura, S., Togawa, N., Yamamoto, H. and Matsuura, Y. (1984) New Material for Permanent Magnets on a Base of Nd and Fe. Journal of Applied Physics, 55, 2083-2087. [Google Scholar] [CrossRef
[5] Tozman, P., Sepehri-Amin, H. and Hono, K. (2021) Prospects for the Development of SmFe12-Based Permanent Magnets with a ThMn12-Type Phase. Scripta Materialia, 194, Article ID: 113686. [Google Scholar] [CrossRef
[6] Takahashi, Y., Sepehri-Amin, H. and Ohkubo, T. (2021) Recent Advances in SmFe12-Based Permanent Magnets. Science and Technology of Advanced Materials, 22, 449-460. [Google Scholar] [CrossRef] [PubMed]
[7] Hadjipanayis, G.C., Gabay, A.M., Schönhöbel, A.M., Martín-Cid, A., Barandiaran, J.M. and Niarchos, D. (2020) ThMn12- Type Alloys for Permanent Magnets. Engineering, 6, 141-147. [Google Scholar] [CrossRef
[8] Ohashi, K., Tawara, Y., Osugi, R. and Shimao, M. (1988) Magnetic Properties of Fe-Rich Rare-Earth Intermetallic Compounds with a ThMn12 Structure. Journal of Applied Physics, 64, 5714-5716. [Google Scholar] [CrossRef
[9] Hu, B.P., Li, H.S., Gavigan, J.P. and Coey, J.M.D. (1989) Intrinsic Magnetic Properties of the Iron-Rich ThMn12- Structure Alloys R (Fe11Ti); R= Y, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm and Lu. Journal of Physics: Condensed Matter, 1, 755. [Google Scholar] [CrossRef
[10] Buschow, K.H.J. (1991) Permanent Magnet Materials Based on Tetragonal Rare Earth Compounds of the Type RFe12−xMx. Journal of Magnetism and Magnetic Materials, 100, 79-89. [Google Scholar] [CrossRef
[11] Körner, W., Krugel, G. and Elsässer, C. (2016) Theoretical Screening of Intermetallic ThMn12-Type Phases for New Hard-Magnetic Compounds with Low Rare Earth Content. Scientific Reports, 6, Article No. 24686. [Google Scholar] [CrossRef] [PubMed]
[12] Tereshina, I.S., Kostyuchenko, N.V., Tereshina-Chitrova, E.A., Skourski, Y., Doerr, M., Pelevin, I.A. and Drulis, H. (2018) ThMn12-Type Phases for Magnets with Low Rare-Earth Content: Crystal-Field Analysis of the Full Magnetization Process. Scientific Reports, 8, Article No. 3595. [Google Scholar] [CrossRef] [PubMed]
[13] Sakuma, N., Suzuki, S., Kuno, T., Urushibata, K., Kobayashi, K., Yano, M. and Manabe, A. (2016) Influence of Zr Substitution on the Stabilization of ThMn12-Type (Nd1−αZrα)(Fe0.75Co0.25)11.25Ti0.75N1.2−1.4 (α= 0−0.3) Compounds. AIP Advances, 6, Article ID: 056023. [Google Scholar] [CrossRef
[14] Isnard, O. and Kinast, E.J. (2020) Neutron Diffraction Investigation of the DyFe11Ti Magnetic Structure and Its Spin Reorientations. Engineering, 6, 154-158. [Google Scholar] [CrossRef
[15] Suzuki, H., Nambu, A. and Okamoto, M. (2019) X-Ray Magnetic Circular Dichroism and Neutron Diffraction Measurements of the Magnetic Moment of Titanium in Sm (Fe0.8Co0.2)11Ti. Physical Review B, 100, Article ID: 144443. [Google Scholar] [CrossRef
[16] Fuquan, B., Wang, J.L., Tegus, O., Dagula, W., Tang, N., Yang, F. M. and Buschow, K.H.J. (2005) Phase Formation and Magnetic Properties of YFe12−xNbx (x= 0.70–0.90) Compounds. Journal of Magnetism and Magnetic Materials, 290-291, 1192-1194. [Google Scholar] [CrossRef
[17] Artigas, M., Piquer, C., Rubin, J. and Bartolomé, J. (1999) Preparation of the New Compounds RE (Ta≈0.5,Fe≈ 11.5)(RE= Tb, Dy, Ho, Er, Lu). Journal of Magnetism and Magnetic Materials, 196-197, 653-654. [Google Scholar] [CrossRef
[18] Simon, D., Wuest, H., Koehler, T., Senyshyn, A., Ehrenberg, H. and Gutfleisch, O. (2019) The Quaternary System Sm-Fe-Mo-Al and the Effect of Al Substitution on Magnetic and Structural Properties of Its ThMn12 Phase. Journal of Alloys and Compounds, 770, 301-307. [Google Scholar] [CrossRef
[19] Jurczyk, M. (1990) Magnetic Behaviour of YFe10.8−xCoxT1.2 Systems (T≡W and Re). Journal of the Less Common Metals, 166, 335-341. [Google Scholar] [CrossRef
[20] Sorescu, M., Valeanu, M., Tomuta, D. and Barb, D. (1998) Investigation of the RFe10M2 (R= U; Sm; Y and M= Si; V; Mn) System by Magnetic and Mössbauer Studies. Solid State Communications, 105, 195-199. [Google Scholar] [CrossRef
[21] Matsumoto, M., Hawai, T. and Ono, K. (2020) (Sm,Zr)Fe12−xMx (M= Zr, Ti, Co) for Permanent-Magnet Applications: Ab Initio Material Design Integrated with Ex-perimental Characterization. Physical Review Applied, 13, Article ID: 064028. [Google Scholar] [CrossRef
[22] Sepehri-Amin, H., Ohkubo, T., Shima, T. and Hono, K. (2012) Grain Boundary and Interface Chemistry of an Nd–Fe–B-Based Sintered Magnet. Acta Materialia, 60, 819-830. [Google Scholar] [CrossRef
[23] Neiva, A.C., Missell, F.P., Grieb, B., Henig, E.T. and Petzow, G. (1991) Phase Equilibria around SmFe11Ti at 1000 °C. Journal of the Less Common Metals, 170, 293-299. [Google Scholar] [CrossRef
[24] Brown, D., Ma, B.M. and Chen, Z. (2002) Developments in the Processing and Properties of NdFeB-Type Permanent Magnets. Journal of Magnetism and Magnetic Materials, 248, 432-440. [Google Scholar] [CrossRef
[25] Lee, R.W. (1985) Hot-Pressed Neodymium-Iron-Boron Magnets. Applied Physics Letters, 46, 790-791. [Google Scholar] [CrossRef
[26] Mishra, R.K. (1987). Microstructure of Hot-Pressed and Die-Upset NdFeB Magnets. Journal of Applied Physics, 62, 967-971.[CrossRef
[27] Davies, B.E., Mottram, R.S. and Harris, I.R. (2001) Recent Developments in the Sintering of NdFeB. Materials Chemistry and Physics, 67, 272-281. [Google Scholar] [CrossRef
[28] Chen, Z.H. (2011) Global Rare Earth Resources and Scenarios of Future Rare Earth Industry. Journal of Rare Earths, 29, 1-6. [Google Scholar] [CrossRef
[29] Nakamura, H. (2018) The Current and Future Status of Rare Earth Permanent Magnets. Scripta Materialia, 154, 273-276. [Google Scholar] [CrossRef
[30] Suzuki, S., Kuno, T., Urushibata, K., Kobayashi, K., Sakuma, N., Washio, K. and Manabe, A. (2016) A New Magnet Material with ThMn12 Structure: (Nd1−xZrx)(Fe1−yCoy)11+zTi1−zNα (α=0.6–1.3). Journal of Magnetism and Magnetic Materials, 401, 259-268. [Google Scholar] [CrossRef
[31] Kou, X.C., Zhao, T.S., Grössinger, R., Kirchmayr, H.R., Li, X. and De Boer, F.R. (1993) Magnetic Phase Transitions, Magnetocrystalline Anisotropy, and Crystal-Field Interactions in the RFe11Ti Series (where R= Y, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Or Tm). Physical Review B, 47, 3231-3242. [Google Scholar] [CrossRef
[32] Fujii, H. and Sun, H. (1995) Interstitially Modified Intermetallics of Rare Earth and 3D Elements. Handbook of Magnetic Materials, 9, 303-404. [Google Scholar] [CrossRef
[33] Fujii, H., Miyazaki, Y., Tatami, K., Sun, H., Morii, Y., Aka-yama, M. and Funahashi, S. (1995) Magnetic and Structural Properties of NdFe8Co3Ti Nitride with ThMn12-Type Structure. Journal of Magnetism and Magnetic Materials, 140-144, 1089-1090. [Google Scholar] [CrossRef
[34] Wang, X.Z., Chevalier, B., Berlureau, T., Etourneau, J., Coey, J.M.D. and Cadogan, J.M. (1988) Iron-Rich Pseudobinary Alloys with the ThMn12 Structure Obtained by Melt Spinning: Gd (FenAl12−n), N= 6, 8, 10. Journal of the Less Common Metals, 138, 235-240. [Google Scholar] [CrossRef
[35] Buschow, K.H.J. (1988) Structure and Properties of Some Novel Ternary Fe-Rich Rare-Earth Intermetallics. Journal of Applied Physics, 63, 3130-3135. [Google Scholar] [CrossRef
[36] Hirayama, Y., Takahashi, Y.K., Hirosawa, S. and Hono, K. (2017) Intrinsic Hard Magnetic Properties of Sm(Fe1−xCox)12 Compound with the ThMn12 Structure. Scripta Materialia, 138, 62-65. [Google Scholar] [CrossRef
[37] Ogawa, D., Yoshioka, T., Xu, X.D., Takahashi, Y.K., Tsuchiura, H., Ohkubo, T. and Hono, K. (2020) Magnetic Anisotropy Constants of ThMn12-Type Sm (Fe1–xCox)12 Compounds and Their Temperature Dependence. Journal of Magnetism and Magnetic Materials, 497, Article ID: 165965. [Google Scholar] [CrossRef
[38] Jiang, C.B. and An, S.Z. (2013) Recent Progress in High Temperature Permanent Magnetic Materials. Rare Metals, 32, 431-440. [Google Scholar] [CrossRef
[39] Hirayama, Y., Takahashi, Y.K., Hirosawa, S. and Hono, K. (2015) NdFe12Nx Hard-Magnetic Compound with High Magnetization and Anisotropy Field. Scripta Materialia, 95, 70-72. [Google Scholar] [CrossRef
[40] Sato, T., Ohsuna, T., Yano, M., Kato, A. and Kaneko, Y. (2017) Permanent Magnetic Properties of NdFe12Nx Sputtered Films Epitaxially Grown on V Buffer Layer. Journal of Applied Physics, 122, Article ID: 053903. [Google Scholar] [CrossRef
[41] Tozman, P., Takahashi, Y.K., Sepehri-Amin, H., Ogawa, D., Hirosawa, S. and Hono, K. (2019) The Effect of Zr Substitution on Saturation Magnetization in (Sm1-xZrx)(Fe0.8Co0.2)12 Compound with the ThMn12 Structure. Acta Materialia, 178, 114-121. [Google Scholar] [CrossRef
[42] Fecht, H.J., Hellstern, E., Fu, Z. and Johnson, W.L. (1990) Nanocrystalline Metals Prepared by High-Energy Ball Milling. Metallurgical Transactions A, 21, Article No. 2333. [Google Scholar] [CrossRef
[43] Takacs, L. (2002) Self-Sustaining Reactions Induced by Ball Milling. Progress in Materials Science, 47, 355-414. [Google Scholar] [CrossRef
[44] Zhang, Q., Song, W., Huang, G., Lou, L., Hou, F., Guo, D., et al. (2016) Crystallization Process and Kinetics of SmCo/Fe and SmCo/FeCo Partially Crystallized Amorphous alloys. Journal of Non-Crystalline Solids, 432, 361-365. [Google Scholar] [CrossRef
[45] Weeber, A.W. and Bakker, H. (1988). Amorphization by Ball Milling. A Review. Physica B: Condensed Matter, 153, 93-135.[CrossRef
[46] Rong, C. and Shen, B. (2018) Nanocrystalline and Nanocomposite Permanent Magnets by Melt Spinning Technique. Chinese Physics B, 27, Article ID: 117502. [Google Scholar] [CrossRef
[47] Coehoorn, R., De Mooij, D.B., Duchateau, J.P.W.B. and Buschow, K.H.J. (1988) Novel Permanent Magnetic Materials Made by Rapid Quenching. Le Journal De Physique Colloques, 49, C8-669-C8-670. [Google Scholar] [CrossRef
[48] Zhou, C., Sun, K., Pinkerton, F.E. and Kramer, M.J. (2015) Magnetic Hardening of Ce1+xFe11−yCoyTi with ThMn12 Structure by Melt Spinning. Journal of Applied Physics, 117, 17A741. [Google Scholar] [CrossRef
[49] Singleton, E.W., Strzeszewski, J. and Hadjipanayis, G.C. (1989) High Coercivity in Rapidly Quenched Sm(Fe,T)12- Type Magnets. Applied Physics Letters, 54, 1934-1936. [Google Scholar] [CrossRef
[50] Zhao, L., Li, C., Zhang, X., Bandaru, S., Su, K., Liu, X. and Yan, M. (2020) Effects of Sm Content on the Phase Structure, Microstructure and Magnetic Properties of the SmxZr0.2(Fe0.8Co0.2)11.5Ti0.5 (x=0.8–1.4) Alloys. Journal of Alloys and Compounds, 828, Article ID: 154428. [Google Scholar] [CrossRef
[51] Schultz, L., Schnitzke, K. and Wecker, J. (1990) High Coercivity in Mechanically Alloyed Sm-Fe-V Magnets with a ThMn12 Crystal Structure. Applied Physics Letters, 56, 868-870. [Google Scholar] [CrossRef
[52] Bessais, L. and Djega-Mariadassou, C. (2001) Structure and Magnetic Properties of Nanocrystalline Sm(Fe1−xCox)11Ti (x ≤ 2). Physical Review B, 63, Article ID: 054412.
[53] Gabay, A.M. and Hadjipanayis, G.C. (2017) Mechanochemical Synthesis of Magnetically Hard Anisotropic RFe10Si2 Powders with R Representing Combinations of Sm, Ce and Zr. Journal of Magnetism and Magnetic Materials, 422, 43-48. [Google Scholar] [CrossRef
[54] Gutfleisch, O. (2011) Magnetic Materials in Sustainable Energy. Presentation at EU JAPAN Experts Workshop on Critical Metals.
[55] Sugimoto, S. (2011) Current Status and Recent Topics of Rare-Earth Permanent Magnets. Journal of Physics D: Applied Physics, 44, Article ID: 064001. [Google Scholar] [CrossRef
[56] Ormerod, J. and Constantinides, S. (1997) Bonded Permanent Magnets: Current Status and Future Opportunities. Journal of Applied Physics, 81, 4816-4820. [Google Scholar] [CrossRef
[57] Dirba, I., Harashima, Y., Sepehri-Amin, H., Ohkubo, T., Miyake, T., Hirosawa, S. and Hono, K. (2020) Thermal Decomposition of ThMn12-Type Phase and Its Optimum Stabilizing Elements in SmFe12-Based Alloys. Journal of Alloys and Compounds, 813, Article ID: 152224. [Google Scholar] [CrossRef
[58] Dirba, I., Sepehri-Amin, H., Choi, I.J., Choi, J.H., Uh, H.S., Kim, T.H. and Hono, K. (2021) SmFe12-Based Hard Magnetic Alloys Prepared by Reduction-Diffusion Process. Journal of Alloys and Compounds, 861, Article ID: 157993. [Google Scholar] [CrossRef
[59] Otsuka, K., Kamata, M., Nomura, T., Iida, H. and Nakamura, H. (2021) Coercivities of Sm-Fe-M Sintered Magnets with ThMn12-Type Structure (M= Ti, V). Materials Transactions, 62, 887-891. [Google Scholar] [CrossRef
[60] Schönhöbel, A.M., Madugundo, R., Gabay, A.M., Barandiarán, J.M. and Hadjipanayis, G.C. (2019) the Sm-Fe-V Based 1: 12 Bulk Magnets. Journal of Alloys and Compounds, 791, 1122-1127. [Google Scholar] [CrossRef
[61] Yang, Y., Yang, J., Han, J., Wang, C., Liu, S. and Du, H. (2015) Research and Development of Interstitial Compounds. IEEE Transactions on Magnetics, 51, Article No. 2103806. [Google Scholar] [CrossRef
[62] Saito, T., Watanabe, F. and Nishio-Hamane, D. (2019) Magnetic Properties of SmFe12-Based Magnets Produced by Spark Plasma Sintering Method. Journal of Alloys and Compounds, 773, 1018-1022. [Google Scholar] [CrossRef
[63] Qian, H.D., Lim, J.T., Kim, J.W., Yang, Y., Cho, K.M., Park, J. and Choi, C.J. (2021) Phase Transformation and Magnetic Properties of Fully Dense Sm (Fe0.8Co0.2)11Ti Bulk Magnets. Scripta Materialia, 193, 17-21. [Google Scholar] [CrossRef
[64] Yue, M., Zhang, X. and Liu, J.P. (2017) Fabrication of Bulk Nanostructured Permanent Magnets with High Energy Density: Challenges and Approaches. Nanoscale, 9, 3674-3697. [Google Scholar] [CrossRef
[65] Sellmyer, D.J. (2002) Strong Magnets by Self-Assembly. Nature, 420, 374-375. [Google Scholar] [CrossRef] [PubMed]
[66] Yang, Y., Walton, A., Sheridan, R., Güth, K., Gauß, R., Gutfleisch, O. and Binnemans, K. (2017) REE Recovery from End-of-Life NdFeB Permanent Magnet Scrap: A Critical Review. Journal of Sustainable Metallurgy, 3, 122-149. [Google Scholar] [CrossRef
[67] 胡伯平. 稀土永磁产业现状及展望[J]. 稀土信息, 2018(11): 14-17.
[68] Zhang, J.M., Xu, K.W. and Ji, V. (2001) Strain-Energy-Driven Abnormal Grain Growth in Copper Films on Silicon Substrates. Journal of Crystal Growth, 226, 168-174. [Google Scholar] [CrossRef
[69] Ma, F., Xu, K.W. and Fan, D.W. (2006) Strain Energy Ani-sotropy in Germanium and Other Diamond-Cubic Polycrystalline Films. Thin Solid Films, 500, 164-168. [Google Scholar] [CrossRef
[70] Li, X., Lou, L., Song, W., Huang, G., Hou, F., Zhang, Q. and Zhang, X. (2017) Novel Bimorphological Anisotropic Bulk Nanocomposite Materials with High Energy Products. Advanced Materials, 29, Article ID: 1606430. [Google Scholar] [CrossRef] [PubMed]
[71] Li, T., Jiang, B., Lou, L., Hua, Y., Gao, J., Wang, J. and Li, X. (2020) Bulk SmCo3 Nanocrystalline Magnets with Magnetic Anisotropy. Journal of Magnetism and Magnetic Materials, 502, Article ID: 166552. [Google Scholar] [CrossRef
[72] Song, W., Li, X., Lou, L., Hua, Y., Zhang, Q., Huang, G. and Zhang, X. (2017) Anisotropic Bulk SmCo7 Nanocrystalline Magnets with High Energy Product. APL Materials, 5, Article ID: 116101. [Google Scholar] [CrossRef
[73] Huang, G., Li, X., Lou, L., Hua, Y., Zhu, G., Li, M. and Zhang, X. (2018) Engineering Bulk, Layered, Multicomponent Nanostructures with High Energy Density. Small, 14, Ar-ticle ID: 1800619. [Google Scholar] [CrossRef] [PubMed]
[74] Wang, Y., Song, W. and Huang, G. (2022) Micro-structure, Magnetic Properties, and Thermal Stability of Bulk Anisotropic SmCo7/α-Fe(Co)+Nd2Fe14B/α-Fe Multiphase Nanohybrid Magnets. Journal of Superconductivity and Novel Magnetism, 1-8. [Google Scholar] [CrossRef
[75] Zhang, X. (2020) Heterostructures: New Opportunities for Functional Materials. Materials Research Letters, 8, 49-59. [Google Scholar] [CrossRef