一种以{W12O42}多酸为构筑单元形成的纯无机三维pcu网络
A Pure Inorganic Three-Dimensional pcu Network Formed by {W12O42} POM as Building Unit
DOI: 10.12677/AAC.2022.122017, PDF,   
作者: 王 潮, 王 宇, 蒋战果:浙江师范大学,浙江 金华
关键词: 多金属氧酸盐框架Polyoxometalate Framework
摘要: 基于过渡金属连接的纯无机多酸框架结构具有稳定性高、协同性好等优点,在催化等领域具有潜在的应用。本文以Paradodecatungstate-B阴离子[H2W12O42]10−为构筑单元通过水热合成法在80℃下原位合成了一例新的三维纯无机多酸框架,并通过单晶X射线衍射分析(SC-XRD)、粉末X射线衍射、傅立叶变换红外光谱(FTIR)表征了其结构。
Abstract: The pure inorganic POM framework structure based on transition metal connection has the advantages of high stability and good synergy, and has potential applications in catalysis and other fields. In this paper, a new three-dimensional pure inorganic POM framework was synthesized in situ at 80˚C by hydrothermal method with Paradodecatungstate-B anion [H2W12O42]10− as the building block, and its structure was characterized by single crystal X-ray diffraction (SC-XRD), powder X-ray diffraction and Fourier transform infrared spectroscopy (FTIR).
文章引用:王潮, 王宇, 蒋战果. 一种以{W12O42}多酸为构筑单元形成的纯无机三维pcu网络[J]. 分析化学进展, 2022, 12(2): 132-140. https://doi.org/10.12677/AAC.2022.122017

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