Au纳米粒子修饰ZnO纳米棒阵列复合催化剂对葡萄糖的光催化转化性能研究
Au Nanoparticles Modified ZnO Nanorod Arrays for the Conversion of Glucose
DOI: 10.12677/MS.2022.125053, PDF,    科研立项经费支持
作者: 刘 嘉, 刘彦岑, 金 龙, 季 震, 王承志, 罗 沙*:东北林业大学材料科学与工程学院,黑龙江 哈尔滨
关键词: 氧化锌纳米棒阵列Au纳米粒子光催化葡萄糖Au Nanoparticles Modified ZnO Nanorod Ar-rays for the Conversion of Glucose
摘要: 本文采用柠檬酸钠还原法制备了Au纳米粒子,并将其组装到ZnO纳米棒阵列/玻璃片复合催化剂表面。利用透射电子显微镜(TEM)、元素mapping、光致发光光谱(PL)和紫外–可见漫反射光谱(DRS)研究了催化剂的结构及光学特征,同时考察了催化剂对葡萄糖的光催化转化性能。研究结果表明,Au纳米粒子均匀分布在ZnO纳米棒阵列表面,有效抑制催化剂光生载流子复合,同时减小催化剂的禁带宽度,拓宽光谱响应范围,提高光子利用率,使得催化剂对葡萄糖的光催化转化性能显著增强。
Abstract: Au nanoparticles were prepared by sodium citrate reduction method and assembled on the surface of ZnO nanorod arrays/glass composite catalysts. The structural and optical characteristics of the catalysts were studied by transmission electron microscopy (TEM), the elemental mapping, photoluminescence (PL) and ultraviolet-visible diffuse reflectance spectra (DRS). Furthermore, the photocatalytic conversion of glucose was investigated. The research results showed that the Au nanoparticles, which were evenly distributed on the surface of ZnO nanorod arrays, could inhibit the recombination of photogenerated carriers, decrease the band gap and broaden the spectral response range, thus improving the photon utilization and photocatalytic performance of the catalysts for the conversion of glucose.
文章引用:刘嘉, 刘彦岑, 金龙, 季震, 王承志, 罗沙. Au纳米粒子修饰ZnO纳米棒阵列复合催化剂对葡萄糖的光催化转化性能研究[J]. 材料科学, 2022, 12(5): 510-515. https://doi.org/10.12677/MS.2022.125053

参考文献

[1] 程明, 杨昌军, 张全权. 高效液相色谱法测定葡萄糖光催化氧化产物[J]. 化学与生物工程, 2019, 36(7): 65-68.
[2] Jin, X., Zhao, M. and Vora, M. (2016) Synergistic Effects of Bimetallic PtPd/TiO2 Nanocatalysts in Oxidation of Glucose to Glucaric Acid: Structure Dependent Activity and Selectivity. Industrial & Engineering Chemistry Research, 55, 2932-2945. [Google Scholar] [CrossRef
[3] Colmenares, J.C., Magdziarz, A. and Bielejewska, A. (2011) High-Value Chemicals Obtained from Selective Photo-Oxidation of Glucose in the Presence of Nanostructured Titanium Photocatalysts. Bioresource Technology, 102, 11254-11257. [Google Scholar] [CrossRef] [PubMed]
[4] Jaramillo-Páez, C.A., Navío, J.A. and Hidalgo, M.C. (2018) ZnO and Pt-ZnO Photocatalysts: Characterization and Photocatalytic Activity Assessing by Means of Three Substrates. Catalysisi Today, 313, 12-19. [Google Scholar] [CrossRef
[5] Xu, F., Yuan, Y.F. and Wu, D.P. (2013) Synthesis of ZnO/Ag/Graphene Composite and Its Enhanced Photocatalytic Efficiency. Materials Research Bulletin, 48, 2066-2070. [Google Scholar] [CrossRef
[6] Udawatte, N., Lee, M. and Kim, J. (2011) Well-Defined Au/ZnO Nanoparticle Composites Exhibiting Enhanced Photocatalytic Activities. Applied Materials & Interfaces, 3, 4531-4538. [Google Scholar] [CrossRef] [PubMed]
[7] Bellardita, M., García-Lόpez, E.I. and Marcì, G. (2016) Photocatalytic Formation of H2 and Value-Added Chemicals in Aqueous Glucose (Pt)-TiO2 Suspension. International Journal of Hydrogen Energy, 41, 5934-5947. [Google Scholar] [CrossRef
[8] 李天冲, 杨峥, 张舒怡. Au修饰ZnO纳米棒催化剂的制备及光催化性能研究[J]. 材料科学, 2021, 11(5): 684-690.
[9] Wang, H., Wang, C.C. and Chen, Q.F. (2017) Interface-Defect-Mediated Photocatalysis of Mesocrystalline ZnO Assembly Synthesized In-Situ via a Template-Free Hydrothermal Approach. Applied Surface Science, 412, 517-528. [Google Scholar] [CrossRef
[10] Kong, M., Li, Y.Z. and Chen, X. (2011) Tuning the Relative Concentration Ratio of Bulk Defects to Surface Defects in TiO2 Nanocrystals Leads to High Photocatalytic Efficiency. Journal of the American Chemical Society, 133, 16414-16417. [Google Scholar] [CrossRef] [PubMed]
[11] Baruah, B., Downer, L. and Agyeman, D. (2019) Fabric-Based Composite Materials Containing ZnO-NRs and ZnO-NRs-AuNPs and Their Application in Photocatalysis. Materials Chemistry and Physics, 231, 252-259. [Google Scholar] [CrossRef