含铜配合物CuL合成及湿敏性能研究
Synthesis and Humidity Sensitive Properties of Copper Containing Complex CuL
DOI: 10.12677/OJNS.2022.103045, PDF,    科研立项经费支持
作者: 张清倩*, 赵行柏, 胡王可汗, 吴婷婷, 康鼎基, 石建钊, 阎天惠, 龚霄芸, 胡芮冰, 冯学英, 殷艳艳#：南开大学滨海学院环境科学与工程系，天津
关键词: 铜；配合物；氢键；湿敏；Copper； Complex； Hydrogen Bond； Humidity Sensitivity
摘要: 本文通过氨三乙酸和乙酸铜为原料成功合成了一例含铜配合物材料(CuL)，单晶衍射表明该材料为零维的单核结构。CuL分子内存在大量羧基氧原子与结晶水分子，通过氢键作用构成三维超分子网络结构。湿敏性能研究发现该配合物材料具有较好的湿度敏感特性，在湿敏传感器方面具有潜在的应用价值。
Abstract: In this paper, a copper containing complex material (CuL) was successfully synthesized from ami-notriacetic acid and copper acetate. Single crystal diffraction showed that the material had a zero dimensional mononuclear structure. There are a large number of carboxyl oxygen atoms and crystalline water molecules in CuL molecule, which form a three-dimensional supramolecular network structure through hydrogen bonding. It is found that the complex material has good humidity sensitivity and has potential application value in humidity sensor.
文章引用：张清倩, 赵行柏, 胡王可汗, 吴婷婷, 康鼎基, 石建钊, 阎天惠, 龚霄芸, 胡芮冰, 冯学英, 殷艳艳. 含铜配合物CuL合成及湿敏性能研究[J]. 自然科学, 2022, 10(3): 373-378. https://doi.org/10.12677/OJNS.2022.103045

参考文献

[1] Farahani, H., Wagiran, R. and Hamidon, M.N. (2014) Humidity Sensors Principle, Mechanism, and Fabrication Technologies: A Comprehensive Review. Sensors, 14, 7881-7939. [Google Scholar] [CrossRef] [PubMed]
[2] Chen, Z. and Lu, C. (2005) Humidity Sensors: A Review of Materials and Mechanisms. Sensor Letters, 3, 274-295. [Google Scholar] [CrossRef] 
[3] Li, Y., Xiao, A.S., Zou, B., Zhang, H.X., Yan, K.L. and Lin, Y. (2018) Advances of Metal-Organic Frameworks for Gas Sensing. Polyhedron, 154, 83-97. [Google Scholar] [CrossRef] 
[4] Yin, Y.Y., Shi, W., Cheng, P., et al. (2012) Temperature-Directed Structural Recurrence in Low-Symmetric Co(II) Complexes and Nanocrystals. Chemical Communications, 48, 705-707. [Google Scholar] [CrossRef] 
[5] Kitagawa, S., Kitaura, R. and Noro, S. (2004) Functional Porous Coordination Polymers. Angewandte Chemie International Edition, 43, 2334-2375. [Google Scholar] [CrossRef] [PubMed]
[6] 吴事剑, 王荷英, 李晗, 等. MIL系列MOFs材料的合成及应用研究进展[J]. 广东化工, 2012, 39(15): 3-4.
[7] Yin, Y.Y., Xing, Y., Li, M.W., et al. (2018) A 3D Pillared-Layer Cadmium (II) Metal-Organic Framework for Chemiresistive Humidity Sensing with High Performance. Inorganic Chemistry Communications, 97, 49-55. [Google Scholar] [CrossRef] 
[8] Zhang, Y., Chen, Y., Zhang, Y., Cong, H., Fu, B., Wen, S. and Ruan, S. (2013) A Novel Humidity Sensor Based on NH2-MIL-125(Ti) Metal Organic Framework with High Responsiveness. Journal of Nanoparticle Research, 15, Article No. 2014. [Google Scholar] [CrossRef] 
[9] Achmann, S., Hagen, G., Kita, J., Malkowsky, I.M., Kiener, C. and Moos, R. (2009) Metal-Organic Frameworks for Sensing Applications in the Gas Phase. Sensors, 9, 1574-1589. [Google Scholar] [CrossRef] [PubMed]
[10] Greenspan, L. (1977) Humidity Fixed Points of Binary Saturated Aqueous Solutions. Journal of Research of the National Bureau of Standards—A Physics and Chemistry, 81A, 89-96. [Google Scholar] [CrossRef]