BiOBr基光催化剂的制备与应用
Preparation and Application of BiOBr Based Photocatalyst
摘要: 通过光催化来高效利用太阳能是解决环境问题和可持续发展未来的理想选择。BiOBr的半导体因其独特的窄带隙和层状结构,且具有优异的可见光吸收能力、低毒性和高光催化活性等优点,被广泛用作环境修复的光催化剂。正因为BiOBr的应用广泛且前景广阔,所以人们专注于对BiOBr的深入研究。本文综述了BiOBr基光催化剂在环境修复方面的最新发展及其制备与应用。重点介绍了控制产物形貌的合成策略,以及提高光催化活性的有效改性策略。其包括通过电荷分离增强本体相,增强空间电荷分离。本文还从污染物净化和二氧化碳减排两个方面综述了BiOBr基光催化剂在环境方面的应用。最后,讨论了BiOBr基材料在未来光催化研究中的挑战和机遇。
Abstract: The efficient utilization of solar energy through photocatalysis is an ideal choice for solving environmental problems and sustainable development in the future. BioBr semiconductors are widely used as photocatalysts for environmental remediation because of their unique narrow band gap and layered structure, excellent visible light absorption ability, low toxicity and high photocatalytic activity. Because of the wide application and broad prospect of BioBr, people focus on the in-depth study of BioBr. This paper reviews the latest development, preparation and application of BioBr based photocatalysts in environmental remediation. The synthesis strategies to control the morphology of the products and the effective modification strategies to improve the photocatalytic activity were introduced. It includes enhancing the bulk phase and space charge separation through charge separation. This paper also summarizes the application of BioBr based photocatalyst in environment from two aspects: pollutant purification and carbon dioxide emission reduction. Finally, the challenges and opportunities of BioBr based materials in future photocatalytic research are discussed.
文章引用:张涵, 孟凡明. BiOBr基光催化剂的制备与应用[J]. 纳米技术, 2022, 12(2): 71-87. https://doi.org/10.12677/NAT.2022.122010

参考文献

[1] Pálmai, M., Zahran, E.M., Angaramo, S., Bálint, S., Pászti, Z., Knecht, M.R. et al. (2017) Pd-Decorated m-BiVO4/BiOBr Ternary Composite with Dual Heterojunction for Enhanced Photocatalytic Activity. Journal of Materi-als Chemistry A, 5, 529-534. [Google Scholar] [CrossRef
[2] Huang, Y., Wu, Z., Zhang, N. and Xie, X. (2020) Artificial Nitrogen Fixation over Bismuth-Based Photocatalysts: Fundamentals and Future Perspectives. Jour-nal of Materials Chemistry A, 8, 4978-4995. [Google Scholar] [CrossRef
[3] Lin, L.L., Wang, X.G., Zhang, J. (2017) A Review on the Application of Photocatalytic Materials. Materials in Environmental Engineering, 469-476.
[4] Kim, S.R. and Jo, W.K. (2019) Boosted Photocatalytic Decomposition of Nocuous Organic Gases over Tricomposites of N-Doped Carbon Quantum Dots, ZnFe2O4, and BiOBr with Different Junctions. Journal of Hazardous Materials, 380, Article ID: 120866. [Google Scholar] [CrossRef] [PubMed]
[5] Zhang, S., Chen, X. and Song, L. (2018) Preparation of BiF3/BiOBr Heterojunctions from Microwave-Assisted Method and Photocatalytic Performances. Journal of Hazardous Materials, 367, 30-315. [Google Scholar] [CrossRef] [PubMed]
[6] Xue, X., Chen, R., Chen, H., et al. (2018) Oxygen Vacancy Engineering Promoted Photocatalytic Ammonia Synthesis on Ultrathin Two-Dimensional Bismuth Oxybromide Nanosheets. Nano Letters, 18, 37327-7377. [Google Scholar] [CrossRef] [PubMed]
[7] Cheng, H., Huang, B. and Dai, Y. (2014) Engineering BiOX (X = Cl, Br, I) Nanostructures for Highly Efficient Photocatalytic Applications. Nanoscale, 6, 2009-2026. [Google Scholar] [CrossRef] [PubMed]
[8] Di, J., Xia, J., Li, H., et al. (2017) Bismuth Oxyhalide Layered Materials for Energy and Environmental Applications. Nano Energy, 41, 172-192. [Google Scholar] [CrossRef
[9] Han, L., Guo, Y., Lin, Z., et al. (2020) 0D to 3D Controllable Nanostructures of BiOBr via a Facile and Fast Room-Temperature Strategy. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 603, Article ID: 125233. [Google Scholar] [CrossRef
[10] Wu, D., Yue, S., Wang, W., et al. (2016) Boron Doped BiOBr Nanosheets with Enhanced Photocatalytic Inactivation of Esche-richia coli. Applied Catalysis B Environmental, 192, 35-45. [Google Scholar] [CrossRef
[11] Wu, D., Wang, B., Wang, W., et al. (2015) Visible-Light-Driven BiOBr Nanosheets for Highly Facet-Dependent Photocata-lytic Inactivation of Escherichia Coli. Journal of Materials Chemistry A, 3, 15148-15155. [Google Scholar] [CrossRef
[12] Fan, Z., Zhao, Y., Zhai, W., et al. (2018) Facet-Dependent Performance of BiOBr for Photocatalytic Reduction of Cr(vi) Rsc Advances Communication. RSC Advances, 6, 2028-2031.
[13] Han, A., Zhang, H., Chuah, G.K., et al. (2017) Influence of the Halide and Exposed Facets on the Vis-ible-Light Photoactivity of Bismuth Oxyhalides for Selective Aerobic Oxidation of Primary Amines. Applied Catalysis B: Environmental, 219, 269-275. [Google Scholar] [CrossRef
[14] Chang, L., Pu, Y., Shen, G., et al. (2020) Excellent Adsorption-Photocatalysis Synergistic Activity of 3D-3D Flower-Like BiOBr/Graphene Hydrogel Composite and the Removal of PBX. New Journal of Chemistry, 44, 2479-2488. [Google Scholar] [CrossRef
[15] Lv, X., Yan, D., Lam, L.Y., et al. (2020) Solvothermal Synthesis of Copper-Doped BiOBr Microflowers with Enhanced Adsorption and Visible-Light Driven Photocatalytic Degradation of Norfloxacin. Chemical Engineering Journal, 401, Article ID: 126012. [Google Scholar] [CrossRef
[16] Yang, Y., Geng, L., Guo, Y. and Guo, Y. (2017) Morphology Evolution and Excellent Visible-Light Photocatalytic Activity of BiOBr Hollow Microspheres. Journal of Chemical Technology & Biotechnology, 92, 1236-1247. [Google Scholar] [CrossRef
[17] Zhao, Y., Yu, T., Tan, X., et al. (2015) SDS-Assisted Solvothermal Synthe-sis of Rose-Like BiOBr Partially Enclosed by {111} Facets and Enhanced Visible-Light Photocatalytic Activity. Dalton Transactions, 44, 20475-20483. [Google Scholar] [CrossRef
[18] Zhang, L., et al. (2020) Facile Synthesis of Bi5O7Br/BiOBr 2D/3D Heterojunction as Efficient Visible-Light-Driven Photocatalyst for Pharmaceutical Organic Degradation. Separation & Purification Technology, 231, Article ID: 115917. [Google Scholar] [CrossRef
[19] Kan, L., Zhang, H., Tang, Y., et al. (2015) Photocatalytic Degradation and Electricity Generation in a Rotating Disk Photoelectro-chemical Cell over Hierarchical Structured BiOBr Film. Applied Catalysis B Environmental, 164, 82-91. [Google Scholar] [CrossRef
[20] Yu, X., Qiu, H., Wang, B., et al. (2020) A Ternary Photocatalyst of All-Solid-State Z-Scheme TiO2-Au-BiOBr for Efficiently Degrading Various Dyes. Journal of Alloys and Com-pounds, 839, Article ID: 155597. [Google Scholar] [CrossRef
[21] Wu, X., Zhang, K., Zhang, G., et al. (2017) Facile Preparation of BiOX (X = Cl, Br, I) Nanoparticles and Up-Conversion Phosphors/BiOBr Composites for Efficient Degradation of NO Gas: Oxygen Vacancy Effect and Near Infrared Light Responsive Mechanism. Chemical Engineering Journal: Lausanne, 325, 59-70. [Google Scholar] [CrossRef
[22] Zhang, W., Qin, Z., Fan, D. (2013) Visible-Light Photocatalytic Removal of NO in Air over BiOX (X = Cl, Br, I) Single-Crystal Nanoplates Prepared at Room Temperature. Industrial & Engineering Chemistry Research, 52, 6740-6746. [Google Scholar] [CrossRef
[23] Ai, Z., Ho, W., Lee, S. and Zhang, L. (2009) Efficient Photocatalytic Re-moval of NO in Indoor Air with Hierarchical Bismuth Oxybromide Nanoplate Microspheres under Visible Light. Envi-ronmental Science & Technology, 43, 4143-4150. [Google Scholar] [CrossRef] [PubMed]
[24] Cai, Y., Song, J., Liu, X., et al. (2018) Soft BiOBr@TiO2 Nanofibrous Membranes with Hierarchical Heterostructures as Efficient and Recyclable Visible-Light Photocatalysts. Environmental Science: Nano, 5, 2631-2640. [Google Scholar] [CrossRef
[25] Li, G., et al. (2013) BiOX (X = Cl, Br, I) Nanostructures: Manni-tol-Mediated Microwave Synthesis, Visible Light Photocatalytic Performance, and Cr(VI) Removal Capacity. Journal of Colloid and Interface Science, 409, 43-51. [Google Scholar] [CrossRef] [PubMed]
[26] Miao, Y., Lian, Z., Huo, Y., et al. (2018) Microwave-Assisted Ion-othermal Synthesis of Hierarchical Microcube-Like BiOBr with Enhanced Photocatalytic Activity. Chinese Journal of Catalysis, 39, 1411-1417. [Google Scholar] [CrossRef
[27] Meng, C., Wang, B., Ji, M., et al. (2020) One-Step Mechan-ical Synthesis of Oxygen-Defect Modified Ultrathin Bi12O17Br2 Nanosheets for Boosting Photocatalytic Activity. Chem-istrySelect, 5, 11177-11184. [Google Scholar] [CrossRef
[28] Wang, Z., Chu, Z., Dong, C., Wang, Z., Yao, S., Gao, H., et al. (2020) Ultrathin BiOX (X = Cl, Br, I) Nanosheets with Exposed {001} Facets for Photocatalysis. ACS Applied Nano Materials, 3, 1981-1991. [Google Scholar] [CrossRef
[29] Wang, Y., Tang, S. and Dai, J.S. (2018) Kinematics and Gait Analy-sis of a Linkage-Jointed Wheel-Legged Robot. Journal of Mechanical Engineering, 54, 11-19. [Google Scholar] [CrossRef
[30] Shi, Z., Zhang, Y., Shen, X., et al. (2020) Fabrication of G-C3N4/BiOBr Heterojunctions on Carbon Fibers as Weaveable Photocatalyst for Degrading Tetracycline Hydrochloride under Visible Light. Chemical Engineering Journal, 386, Article ID: 124010. [Google Scholar] [CrossRef
[31] Guo, C., Gao, S., Lv, J., et al. (2017) Assessing the Photocatalytic Transformation of Norfloxacin by BiOBr/Iron Oxides Hybrid Photocatalyst: Kinetics, Intermediates, and Influencing Factors. Applied Catalysis B Environmental, 205, 68-77. [Google Scholar] [CrossRef
[32] Guo, F., Chen, J., Zhao, J., Chen, Z., Xia, D., Zhan, Z., et al. (2020) Z-Scheme Heterojunction G-C3N4@PDA/BiOBr with Bio-mimetic Polydopamine as Electron Transfer Mediators for Enhanced Visible-Light Driven Degradation of Sulfamethox-azole. Chemical Engineering Journal, 386, Article ID: 124014.
[33] Jcsab, C., Smlab, D., Hza, B., et al. (2020) Z-Scheme Heterojunction Nanocomposite Fabricated By Decorating Magnetic MnFe2O4 Nanoparticles on BiOBr Nanosheets for Enhanced Visible Light Photocatalytic Degradation of 2,4-Dichlorophenoxyacetic Acid and Rhodamine B. Separation and Purification Technology, 250, Article ID: 117186. [Google Scholar] [CrossRef
[34] Tao, J.A., Jiang, W., Jie, S.C., et al. (2020) In Situ Self-Growing 3D Hierarchical BiOBr/BiOIO3 Z-Scheme Heterojunction with Rich Oxygen Vacancies and Iodine Ions as Carriers Transfer Dual-Channels for Enhanced Photocatalytic Activity. Chemical Engineering Journal, 396, Article ID: 125258. [Google Scholar] [CrossRef
[35] Wang, Y., Wang, K., Wang, J., et al. (2020) Sb2WO6/BiOBr 2D Nanocomposite S-Scheme Photocatalyst for NO Removal, Journal of Materials Science & Technol-ogy, 56, 236-243. [Google Scholar] [CrossRef
[36] Yang, F., X Chu, Sun, J., et al. (2020) Efficient Singlet Oxygen Generation by Excitonic Energy Transfer on Ultrathin G-C3N4 for Selective Photocatalytic Oxidation of Methyl-Phenyl-Sulfide with O2. Chinese Chemical Letters, 31, 2784-2788. [Google Scholar] [CrossRef
[37] Kanagaraj, T. and Thiripuranthagan, S. (2017) Photocatalytic Ac-tivities of Novel SrTiO3-BiOBr Heterojunction Catalysts Towards the Degradation of Reactive Dyes. Applied Catalysis B: Environmental, 207, 218-232. [Google Scholar] [CrossRef
[38] Li, H., Deng, F., Zheng, Y., Hua, L., Qu, C. and Luo, X. (2019) Visible-Light-Driven Z-Scheme RGO/Bi2S3-BiOBr Heterojunctions with Tunable Exposed BiOBr (102) Facets for Effi-cient Synchronous Photocatalytic Degradation of 2-Nitrophenol and Cr(VI) Reduction. Environmental Science: Nano, 6, 3670-3683. [Google Scholar] [CrossRef
[39] Di, J., Chen, C., Zhu, C., et al. (2019) Bismuth Vacancy-Tuned Bis-muth Oxybromide Ultrathin Nanosheets toward Photocatalytic CO2 Reduction. ACS Applied Materials & Interfaces, 11, 30786-30792. [Google Scholar] [CrossRef] [PubMed]
[40] Wu, J., Xie, Y., Ling, Y., et al. (2020) One-Step Synthesis and Gd3+ Decoration of BiOBr Microspheres Consisting of Nanosheets toward Improving Photocatalytic Reduction of CO2 into Hydrocarbon Fuel. The Chemical Engineering Journal, 400, Article ID: 125944. [Google Scholar] [CrossRef