金川铜镍硫化物矿床磁黄铁矿标型矿物学特征及其地质意义
Typomorphic Mineralogical Characteristics of Pyrrhotite in Jinchuan Copper Nickel Sulfide Deposit and Its Geological Significance
DOI: 10.12677/AG.2022.126076, PDF,  被引量   
作者: 赵 翔, 赖健清:中南大学有色金属成矿预测与地质环境监测教育部重点实验室,湖南 长沙;中南大学地球科学与信息物理学院,湖南 长沙;艾启兴, 王韵棋:金川集团股份有限公司,甘肃 金昌
关键词: 金川矿床磁黄铁矿标型特征岩浆通道系统Jinchuan Deposit Pyrrhotite Typomorphic Characteristics Magma Conduit System
摘要: 金川矿床作为世界第三大铜镍硫化物矿床具有重要的研究价值。前人在矿物学的研究主要集中在橄榄石、辉石等硅酸盐矿物上,而对成矿物质本身的硫化物矿物研究较少。本文采用X射线衍射、电子探针分析等方法,对不同构造类型矿石中磁黄铁矿的结构状态与化学成分作了研究。结果表明,浸染状、海绵陨铁状矿石中磁黄铁矿产出特征和矿物组合较为相似,其中前者以高温六方相为主,主要为高温岩浆经历缓慢降温结晶形成,后者则为高温六方相和低温单斜相的交生体,经历了岩浆的快速降温结晶过程;而块状矿石中磁黄铁矿产出特征和矿物组合与上述类型矿石差异较大,主要为高温岩浆经历快速降温结晶形成。根据块状硫化物矿石所在位置以及在该区分布特征,推断岩浆通道入口最有可能分布于II矿区东部的中间位置。
Abstract: Jinchuan deposit is the third largest copper nickel sulfide deposit in the world, which is of great research value. Previous mineralogy studies on Jinchuan deposit mainly focused on silicate min-erals such as olivine and pyroxene, but less on sulfide minerals. In this paper, the structural state and chemical composition of pyrrhotite of ores with different structural types have been studied by X-ray diffraction and electron microprobe analysis. The results show that the occurrence characteristics and mineral assemblages of pyrrhotite in disseminated and sideronitic sulfide ores are relatively similar. The pyrrhotite in these ores is mainly high-temperature hexagonal phase and contains a very small amount of low-temperature monoclinic pyrrhotite. And they are mainly formed by slow cooling crystallization of high-temperature magma, but it has experienced rapid cooling crystallization locally. The occurrence characteristics and mineral assemblages of pyrrhotite in massive ores are quite different from those of the above types of ores, which is mainly formed by rapid cooling crystallization of high-temperature magma. According to the location and the distribution characteristics of massive sulfide ore in this area, it is inferred that the entrance of magmatic channel is most likely to be located in the middle of the east of mining area II.
文章引用:赵翔, 赖健清, 艾启兴, 王韵棋. 金川铜镍硫化物矿床磁黄铁矿标型矿物学特征及其地质意义[J]. 地球科学前沿, 2022, 12(6): 776-783. https://doi.org/10.12677/AG.2022.126076

参考文献

[1] 汤中立. 中国岩浆硫化物矿床的主要成矿机制[J]. 地质学报, 1996(3): 237-243.
[2] Naldrett, A.J. (1999) World-Class Ni-Cu-PGE Deposits: Key Factors in Their Genesis. Mineralium Deposita, 34, 227-240. [Google Scholar] [CrossRef
[3] Song, X., Wang, Y. and Chen, L. (2011) Magmatic Ni-Cu-(PGE) Deposits in Magma Plumbing Systems: Features, Formation and Exploration. Geoscience Frontiers, 2, 375-384. [Google Scholar] [CrossRef
[4] Liu, M., Zhou, M., Su, S., et al. (2021) Contrasting Geochemistry of Apatite from Peridotites and Sulfide Ores of the Jinchuan Ni-Cu Sulfide Deposit, NW China. Economic Geology, 116, 1073-1092. [Google Scholar] [CrossRef
[5] 索文德, 康健, 艾启兴, 等. 甘肃金川Ⅱ号岩体橄榄石成因探讨[J]. 矿物学报, 2022, 42(3): 376-386.
[6] 王振江. 中国金川Ni-Cu(PGE)硫化物矿床深部成矿过程的实验研究[D]: [博士学位论文]. 武汉: 中国地质大学, 2020.
[7] Mao, X., Li, L., Liu, Z., et al. (2019) Multiple Magma Conduits Model of the Jinchuan Ni-Cu-(PGE) Deposit, Northwestern China: Constraints from the Geochemistry of Platinum-Group Elements. Minerals, 9, Article No. 187. [Google Scholar] [CrossRef
[8] 郗爱华, 葛玉辉, 蔡元峰, 等. 红旗岭铜镍硫化物矿床磁性矿物学研究及矿床成因意义[J]. 自然科学进展, 2006, 16(9): 1109-1115.
[9] 曹亚文. 金川铜镍硫化物矿床矿物形成演化研究[D]: [博士学位论文]. 北京: 中国地质科学院, 1995.
[10] 丁瑞颖. 甘肃金川镍铜铂岩浆硫化物矿床II矿区矿物特征研究[D]: [硕士学位论文]. 西安: 长安大学, 2012.
[11] 芮会超, 焦建刚, 靳树芳. 金川铜镍硫化物矿床磁黄铁矿矿物学特征及成因意义[J]. 矿床地质, 2017, 36(2): 501- 514.
[12] Wang, H. and Salveson, I. (2005) A Review on the Mineral Chemistry of the Non-Stoichiometric Iron Sulphide, Fe1−x S (0 ≤ x ≤ 0.125): Polymorphs, Phase Relations and Transitions, Electronic and Magnetic Structures. Phase Transitions, 78, 547-567. [Google Scholar] [CrossRef
[13] Becker, M., de Villiers, J. and Bradshaw, D. (2010) The Mineralogy and Crystallography of Pyrrhotite from Selected Nickel and PGE Ore Deposits. Economic Geology, 105, 1025-1037. [Google Scholar] [CrossRef
[14] 汤中立, 李文渊. 金川铜镍硫化物(含铂)矿床成矿模式及地质对比[M]. 北京: 地质出版社, 1995.
[15] 汤中立, 闫海卿, 焦建刚, 等. 中国岩浆硫化物矿床新分类与小岩体成矿作用[J]. 矿床地质, 2006(1): 1-9.
[16] 曾认宇. 金川铜镍硫化物矿床岩浆通道系统及岩浆演化研究[D]: [硕士学位论文]. 长沙: 中南大学, 2014.
[17] Song, X.Y., Keays, R.R., Zhou, M.F., et al. (2009) Siderophile and Chalcophile Elemental Constraints on the Origin of the Jinchuan Ni-Cu-(PGE) Sulfide Deposit, NW China. Geochimica et Cosmochimica Acta, 73, 404-424. [Google Scholar] [CrossRef
[18] 郭维民, 陆建军, 章荣清, 等. 安徽铜陵冬瓜山矿床中磁黄铁矿矿石结构特征及其成因意义[J]. 矿床地质, 2010, 29(3): 405-414.
[19] 杨爽, 杜杨松, 曹毅, 等. 安徽铜陵冬瓜山层控矽卡岩铜矿床形成过程——来自磁黄铁矿的证据[J]. 现代地质, 2012, 26(1): 54-60.
[20] Arnold, R.G. (1962) Equilibrium Relations between Pyrrhotite and Pyrite from 325˚ to 743˚C. Economic Geology, 57, 72-90. [Google Scholar] [CrossRef
[21] Kissin, S.A. and Scott, S.D. (1982) Phase relations involving pyrrhotite below 350 degrees C. Economic Geology, 77, 1739-1754. [Google Scholar] [CrossRef
[22] 丁奎首, 秦克章, 许英霞, 等. 东天山主要铜镍矿床中磁黄铁矿的矿物标型特征及其成矿意义[J]. 矿床地质, 2007(1): 109-119.
[23] Gu, L. and Vokes, F.M. (1996) Intergrowths of Hexagonal and Monoclinic Pyrrhotites in Some Sulphide Ores from Norway. Mineralogical Magazine, 60, 303-316. [Google Scholar] [CrossRef
[24] Evans-Lamswood, D., Butt, D., Jackson, R., et al. (2000) Physical Controls Associated with the Distribution of Sulfidesin the Voisey’s Bay Ni-Cu-Co Deposit, Labrador. Economic Geology, 95, 749-769. [Google Scholar] [CrossRef
[25] 闫海卿, 王强, 胡彦强, 等. 金川铜镍硫化物岩浆矿床前锋岩浆与岩浆通道[J]. 中国地质, 2013, 40(3): 807-819.