氧化铋基电解质的性能及研究进展
Properties and Research Progress of Bismuth Oxide Based Electrolytes
DOI: 10.12677/APP.2022.126039, PDF,    科研立项经费支持
作者: 禄靖雯, 谢婉莹, 陈潞潼, 李冰雪, 任宇冰, 张梦珂, 孙启瑞：郑州师范学院物理与电子工程学院，河南 郑州；张 洁*：郑州师范学院物理与电子工程学院，河南 郑州；郑州大学物理学院(微电子学院)，河南 郑州；郑州威科姆科技股份有限公司，河南 郑州
关键词: 固体氧化物燃料电池；氧化铋；掺杂改性；Solid Oxide Fuel Cells； Bismuth Oxide； Doping Modification
摘要: 中低温固体氧化物燃料电池(SOFC)是未来燃料电池发展的重要方向，而适用于中低温的固体电解质是中低温SOFC的关键材料。Bi2O3基电解质在低温区(600℃以下)具有优异的电学性能，因此是理想的中低温电解质材料。本文从Bi2O3基电解质的导电原理和不同价态离子掺杂的角度综述了Bi2O3基固体电解质的发展现状。δ相的Bi2O3基电解质具有最高的电导率，但其稳定的温度范围很窄，因此获得在低温下(600℃以下)稳定的δ相是Bi2O3基电解质发展需要克服的关键技术难题，目前主要通过掺杂的方法来实现稳定的δ-Bi2O3，从而得到具有良好电学性能的Bi2O3基电解质。
Abstract: The medium and low temperature solid oxide fuel cell (SOFC) is an important direction for the future development of fuel cells, and the solid electrolyte suitable for medium and low temperature is the key material for medium and low temperature SOFC. Bi2O3-based electrolytes have excellent electrical properties in the low temperature region (below 600˚C), so they are ideal medium-low temperature electrolyte materials. In this paper, the development status of Bi2O3-based solid electrolytes is reviewed from the perspective of the conductivity principle of Bi2O3-based electrolytes and the doping of ions with different valence states. The δ-phase Bi2O3-based electrolyte has the highest conductivity, but its stable temperature range is very narrow. Therefore, obtaining the δ-phase stable at low temperature (below 600˚C) is a key technical problem that needs to be overcome in the development of Bi2O3-based electrolyte. At present, it is mainly achieved d-Bi2O3 by doping so as to obtain Bi2O3 based electrolyte with good electrical properties.
文章引用：禄靖雯, 谢婉莹, 陈潞潼, 李冰雪, 任宇冰, 张梦珂, 孙启瑞, 张洁. 氧化铋基电解质的性能及研究进展[J]. 应用物理, 2022, 12(6): 337-342. https://doi.org/10.12677/APP.2022.126039

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