MFT成核剂对聚氨酯硬泡泡孔结构及物理性能的影响
Effect of MFT Nucleating Agent on Cell Structure and Physical Properties of Polyurethane Rigid Foam Cells
DOI: 10.12677/OJNS.2023.111007, PDF,   
作者: 李 彬:美的厨卫电器制造有限公司,安徽 芜湖
关键词: 聚氨酯泡沫成核剂泡孔导热系数Polyurethane Foam Nucleating Agent Cell Thermal Conductivity
摘要: 通过添加MFT成核剂,制备出泡孔均匀细腻的聚氨酯硬泡,降低泡沫固相导热系数和辐射导热系数,当MFT成核剂添加3份时,泡沫孔径可降低三分之一,导热系数下降5.5%,与LBA发泡体系保温效果相当。
Abstract: By adding MFT nucleating agent, polyurethane rigid foam with uniform and fine pores was prepared, and the thermal conductivity and radiative thermal conductivity of the foam were reduced. When 3 parts of MFT nucleating agent were added, the pore size of the foam was reduced by one-third and the thermal conductivity decreased by 5.5%, which was equivalent to the thermal insulation effect of LBA foaming system.
文章引用:李彬. MFT成核剂对聚氨酯硬泡泡孔结构及物理性能的影响[J]. 自然科学, 2023, 11(1): 54-59. https://doi.org/10.12677/OJNS.2023.111007

参考文献

[1] 米欣, 张杰, 田新宝, 等. 3M添加剂在聚氨酯发泡上的应用研究[J]. 家电科技, 2014(2): 56-57.
[2] 李锋华, 蒋兴华. 聚合物基泡体复合材料的传热性能及机理[J]. 合成材料老化与应用, 2002(4): 30-34.
[3] Zhang, H., Fang, W.Z., Li, Y.M., et al. (2017) Experimental Study of the Thermal Conductivity of Polyurethane Foams. Applied Thermal Engineering, 115, 528-538. [Google Scholar] [CrossRef
[4] Hee, K.S., Lim, H., Chul, S.J., et al. (2008) Effect of Blowing Agent Type in Rigid Polyurethane Foam. Journal of Macro-molecular Science, Part A: Pure and Applied Chemistry, 45, 323-327. [Google Scholar] [CrossRef
[5] Pietrak, K. and Wiśniewski, T.S. (2015) A Review of Models for Effective Thermal Conductivity of Composite Materials. Journal of Power Technologies, 95, 14-24.
[6] Antunes, M., Velasco, J.I., Solórzano, E., et al. (2010) Heat Transfer in Polyolefin Foams. In: Heat Transfer in Multi-Phase Materials, Springer, Berlin, 131-161. [Google Scholar] [CrossRef
[7] Jarfelt, U. and Ramnäs, O. (2006) Thermal Conductivity of Pol-yurethane Foam-Best Performance. In: 10th International Symposium on District Heating and Cooling, Chalmers University of Technology, Goteborg, 12.
[8] Wu, J.W., Sung, W.F. and Chu, H.S. (1999) Thermal Conductivity of Polyurethane Foams. International Journal of Heat and Mass Transfer, 42, 2211-2217. [Google Scholar] [CrossRef
[9] Choi, S.W., Jung, J.M., Yoo, H.M., et al. (2018) Anal-ysis of Thermal Properties and Heat Transfer Mechanisms for Polyurethane Foams Blown with Water. Journal of Thermal Analysis and Calorimetry, 132, 1253-1262. [Google Scholar] [CrossRef
[10] Song, H.Y., Cheng, X.X. and Chu, L. (2014) Effect of Den-sity and Ambient Temperature on Coefficient of Thermal Conductivity of Heat-Insulated EPS and PU Materials for Food Packaging. Applied Mechanics and Materials, 469, 152-155. [Google Scholar] [CrossRef
[11] Harikrishnan, G. and Khakhar, D.V. (2007) Effect of Monomer Temperature on Foaming and Properties of Flexible Polyurethane Foams. Journal of Applied Polymer Science, 105, 3439-3443. [Google Scholar] [CrossRef
[12] Chen, Y., Das, R. and Battley, M. (2015) Effects of Cell Size and Cell Wall Thickness Variations on the Stiffness of Closed-Cell Foams. International Journal of Solids and Structures, 52, 150-164. [Google Scholar] [CrossRef
[13] Tseng, C., Yamaguchi, M. and Ohmori, T. (1997) Thermal Conductivity of Polyurethane Foams from Room Temperature to 20 K. Cryogenics, 37, 305-312. [Google Scholar] [CrossRef
[14] 杨加栋, 张晓灵, 吴文通, 等. 零ODP值发泡剂对硬质聚氨酯泡沫的泡孔结构和导热系数的影响[J]. 聚氨酯工业, 2015, 30(1): 9-13.
[15] 郑冬芳, 吴克安, 钱跃言, 等. 《蒙特利尔议定书》HFCs修正提案浅析[J]. 浙江化工, 2016(1): 1-5.
[16] 李彬, 汤春花. 第四代发泡剂LBA泡沫老化趋势探讨[J]. 化学工程与技术, 2019, 9(1): 15-19. [Google Scholar] [CrossRef
[17] Reichenauer, G., Heinemann, U. and Ebert, H.P. (2007) Relationship between Pore Size and the Gas Pressure Dependence of the Gaseous Thermal Conductivity. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 300, 204-210. [Google Scholar] [CrossRef
[18] 潘榕伟, 秦桑路, 林云. 新一代高效节能环保家电发泡剂技术的开发与应用[J]. 电器, 2012(z1): 83-86.
[19] 王耀, 尹良敏. 新型发泡剂LBA在冰箱发泡应用中的研究[J]. 广州化工, 2015, 43(23): 134-136.
[20] 魏路, 信延垒, 于楠, 等. 电热水器用LBA型硬泡组合聚醚的研究[J]. 聚氨酯工业, 2017, 32(5): 52-55.