Pt/CeO2催化剂催化丙酮气相加氢性能
Catalyzing Acetone Hydrogenation Performance by Pt/CeO2 Catalyst
DOI: 10.12677/HJCET.2023.131005, PDF,    科研立项经费支持
作者: 韩承俊, 鲍天颐, 陈昌智, 汪庭玉：山东第一医科大学化学与制药工程学院，山东 泰安
关键词: 氢气解离；丙酮吸附；加氢；异丙醇；催化性能；H2 Dissociation； Acetone Adsorption； Hydrogenation； Isopropanol； Catalytic Performance
摘要: 本文通过对Pt/CeO2催化剂还原处理，形成足够的Pt-CeO2界面，考察了其对丙酮气相加氢制备异丙醇的性能。实验证实，Pt或CeO2位点均不能催化此反应，虽然Pt能解离氢气，CeO2能吸附丙酮。但是Pt/CeO2能够同时具备活化氢气和吸附丙酮的性能，所以催化性能大幅提高。
Abstract: Sufficient Pt-CeO2 interface is formed after H2-reduction treatment of Pt/CeO2 catalyst, and its catalytic performance of acetone hydrogenation is investigated. The sole Pt or CeO2 site couldn’t catalyze acetone hydrogenation successfully, although Pt could activate H2 and CeO2 adsorb acetone. However, Pt/CeO2 could catalyze acetone hydrogenation effectively due to its excellent H2 activation and acetone adsorption ability.
文章引用：韩承俊, 鲍天颐, 陈昌智, 汪庭玉. Pt/CeO2催化剂催化丙酮气相加氢性能[J]. 化学工程与技术, 2023, 13(1): 35-42. https://doi.org/10.12677/HJCET.2023.131005

参考文献

[1] Alt, C. (2006) Ullmann’s Encyclopedia of Industrial Chemistry. Wiley, New York, 2345-2351.
[2] Xu, M., Cai, J., Guo, J., et al. (2017) Technical and Economic Feasibility of the Isopropanol-Acetone-Hydrogen Chemical Heat Pump Based on a Lab-Scale Prototype. Energy, 139, 1030-1039. [Google Scholar] [CrossRef] 
[3] Jiang, G., Cumberland, T., Zang, J., et al. (2021) A Novel Design of High-Temperature Polymer Electrolyte Membrane Acetone Fuel Cell. Sensors and Actuators, B: Chemical, 329, Article ID: 129006. [Google Scholar] [CrossRef] 
[4] Kratzel, A., Todt, D., Philip, V., et al. (2020) Efficient Inac-tivation of SARS-CoV-2 by WHO-Recommended Hand Rub Formulations and Alcohols. [Google Scholar] [CrossRef] 
[5] Bing, R.G., Straub, C.T., Sullis, D.B., et al. (2022) Plant Biomass Fermentation by the Extreme Thermophile Caldicellulosiruptorbescii for Coproduction of Green Hydrogen and Acetone: Technoeconomic Analysis. Bioresource Technology, 348, Article ID: 126780. [Google Scholar] [CrossRef] [PubMed]
[6] Shirochenko, K.S., Safronov, A.D., Akhmetov, I.V. and Gubaydullin, I.M. (2019) Mathematical Modeling of a Fractionation Unit in the Production of Phenol and Acetone by Cumene Method. Journal of Physics: Conference Series, 1096, Article ID: 012191. [Google Scholar] [CrossRef] 
[7] Xu, Y., Chuang, K.T. and Sanger, A.R. (2002) Design of a Process for Production of Isopropyl Alcohol by Hydration of Propylene in a Catalytic Distillation Column. Chemical Engineering Research and Design, 80, 686-694. [Google Scholar] [CrossRef] 
[8] Özkar, S. and Finke, R.G. (2005) Iridium (0) Nanocluster, Acid-Assisted Catalysis of Neat Acetone Hydrogenation at Room Temperature: Exceptional Activity, Catalyst Lifetime, and Selectivity at Complete Conversion, Journal of the American Chemical Society, 127, 4800-4808. [Google Scholar] [CrossRef] [PubMed]
[9] Shutkina, O.V., Ponomareva, O.A., Kots, P.A. and Ivanova, I.I. (2013) Selective Hydrogenation of Acetone in the Presence of Benzene. Catalysis Today, 218, 30-34. [Google Scholar] [CrossRef] 
[10] Cunningham, J., Hickey, J.N. and Wang, Z. (1996) Activities and Selectivities of Copper/Metal-Oxide Catalysts at Temperatures Relevant to Chemical Heat-Pumps Based on Isopropanol/Acetone Interconversions. International Journal of Energy Research, 20, 763-766. [Google Scholar] [CrossRef] 
[11] Gandia, L.M., Di-az, A. and Montes, M. (1995) Selectivity in the High-Temperature Hydrogenation of Acetone with Silica-Supported Nickel and Cobalt Catalysts. Journal of Catalysis, 157, 461-471. [Google Scholar] [CrossRef] 
[12] Fauzia, V., Karmelia, R., Roza, L. and Hafizah, M.A.E. (2019) Gold Mesocauliflowers as Catalyst for the Hydrogenation of Acetone to Isopropanol. Materials Research Express, 6, Article ID: 084002. [Google Scholar] [CrossRef] 
[13] Balouch, A., Umar, A.A., Shah, A.A., Salleh, M.M. and Oyama, M. (2013) Efficient Heterogeneous Catalytic Hydrogenation of Acetone to Isopropanol on Semihollow and Porous Palladium Nanocatalyst. ACS Applied Materials & Interfaces, 5, 9843-9849. [Google Scholar] [CrossRef] [PubMed]
[14] Sen, B. and Vannice, M.A. (1988) Metal-Support Effects on Acetone Hydrogenation over Platinum Catalysts. Journal of Catalysis, 113, 52-71. [Google Scholar] [CrossRef] 
[15] Fuente, A.M., Pulgar, G., González, F., Pesquera, C. and Blanco, C. (2001) Activated Carbon Supported Pt Catalysts: Effect of Support Texture and Metal Precursor on Ac-tivity of Acetone Hydrogenation. Applied Catalysis A: General, 208, 35-46. [Google Scholar] [CrossRef] 
[16] Fu, Q., Li, W., Yao, Y., et al. (2010) Interface-Confined Ferrous Centers for Catalytic Oxidation. Science, 328, 1141-1144. [Google Scholar] [CrossRef] [PubMed]
[17] Zhao, G., Yang, F., Chen, Z., et al. (2017) Metal/Oxide Interfa-cial Effects on the Selective Oxidation of Primary Alcohols. Nature Communications, 8, Article No. 14039. [Google Scholar] [CrossRef] [PubMed]
[18] Liu, K., Zhao, Y., Wang, J., et al. (2020) Ag-CoO Nanocomposites for Gas-Phase Oxidation of Alcohols to Aldehydes and Ketones: Intensified O2 Activation at Ag-CoO Interfacial Sites. Catalysis Science & Technology, 10, 8445-8457. [Google Scholar] [CrossRef] 
[19] Chen, A., Yu, X., Zhou, Y., et al. (2019) Structure of the Catalyt-ically Active Copper-Ceria Interfacial Perimeter. Nature Catalysis, 2, 334-341. [Google Scholar] [CrossRef] 
[20] Zhang, T., Wang, W., Gu, F., et al. (2022) Enhancing the Low Temperature CO2 Methanation over Ni/La-CeO2 Catalyst: The Effects of Surface Oxygen Vacancy and Basic Site on the Catalytic Performance. Applied Catalysis B: Environmental, 312, Article ID: 121385. [Google Scholar] [CrossRef] 
[21] Rui, N., Wang, Z., Sun, K., et al. (2017) CO2 Hydrogenation to Methanol over Pd/In2O3: Effects of Pd and Oxygen Vacancy. Applied Catalysis B: Environmental, 218, 488-497. [Google Scholar] [CrossRef] 
[22] Xue, Y., Yao, R., Li, J., et al. (2017) Efficient Pt-FeOx/TiO2@SBA-15 Catalysts for Selective Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol. Catalysis Science & Technology, 7, 6112-6123. [Google Scholar] [CrossRef] 
[23] Ji, Y., Wu, Y., Zhao, G., et al. (2015) Porous Bimetallic Pt-Fe Nanocatalysts for Highly Efficient Hydrogenation of Acetone. Nano Research, 8, 2706-2713. [Google Scholar] [CrossRef] 
[24] Yang, Q., Gao, D., Li, C., et al. (2022) Deposition of Pt Clusters onto MOFs-Derived CeO2 by ALD for Selective Hydrogenation of Furfural. Fuel, 311, Article ID: 122584. [Google Scholar] [CrossRef] 
[25] Zhu, L., Lu, J., Chen, P., et al. (2012) A Comparative Study on Pt/CeO2 and Pt/ZrO2 Catalysts for Crotonaldehyde Hydrogenation. Journal of Molecular Catalysis A: Chemical, 361-362, 52-57. [Google Scholar] [CrossRef] 
[26] Shen, M., Zhao, G., Nie, Q., et al. (2021) Ni-Foam-Structured Ni-Al2O3 Ensemble as an Efficient Catalyst for Gas-Phase Acetone Hydrogenation to Isopro-panol. ACS Applied Materials & Interfaces, 13, 28334-28347. [Google Scholar] [CrossRef] [PubMed]