单原子催化剂局部配位微环境的研究进展
Research Progress of Local Coordination Microenvironment of Single-Atom Catalysts
摘要: 单原子催化剂(SACs)由于兼具均相催化剂和非均相催化剂的优点，逐渐成为催化领域的热门材料。随着SACs的发展，对其局部配位环境的研究已经发展到原子水平。金属原子中心以及周围的配位原子构成的配位环境对其催化活性、选择性和稳定性起着重要的作用。本文论述了通过调节配位原子数目、配位原子类型、配位原子位置三种不同的策略实现了对SACs配位微环境的调控以及在有机催化、光催化以及电催化领域的应用。
Abstract: Singleatom catalysts (SACs) are gradually becoming popular materials in the field of catalysis due to the advantages of both homogeneous and hetero-geneous catalysts. With the development of SACs, the study of their local coordination environment has been developed to the atomic level. The coordination environment consisting of the metal atom center and the surrounding coordination atoms plays an important role in their catalytic activity, selectivity and stability. In this paper, three different strategies for modulating the coordination microenvironment of SACs, including adjustment of the number of coordination atoms, the type of coordination atoms, and the position of coordination atoms, and their applications in organic cataly-sis, photocatalysis and electrocatalysis are discussed.
文章引用：王丽. 单原子催化剂局部配位微环境的研究进展[J]. 材料科学, 2023, 13(2): 59-67. https://doi.org/10.12677/MS.2023.132008

参考文献

[1] Ma, D.D. and Zhu, Q.L. (2020) MOF-Based Atomically Dispersed Metal Catalysts: Recent Progress towards Novel Atomic Configurations and Electrocatalytic Applications. Coordination Chemistry Reviews, 422, 213483-21352. [Google Scholar] [CrossRef] 
[2] Zhao, S.N., Song, X.Z., Song, S.Y., et al. (2017) Highly Efficient Heterogeneous Catalytic Materials Derived from Metal-Organic Framework Supports/Precursors. Coordination Chemis-try Reviews, 337, 80-96. [Google Scholar] [CrossRef] 
[3] Lin, Y., Liu, P., Velasco, E., et al. (2019) Fabricating Single-Atom Catalysts from Chelating Metal in Open Frameworks. Advanced Materials, 31, 1808193-1808202. [Google Scholar] [CrossRef] [PubMed]
[4] Liu, L. and Corma, A. (2018) Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles. Chemical Reviews, 118, 4981-5079. [Google Scholar] [CrossRef] [PubMed]
[5] Huang, H., Shen, K., Chen, F., et al. (2020) Metal-Organic Frameworks as a Good Platform for the Fabrication of Single-Atom Catalysts. Acs Catalysis, 10, 6579-6586. [Google Scholar] [CrossRef] 
[6] Li, X., Rong, H., Zhang, J., et al. (2020) Modulating the Local Coor-dination Environment of Single-Atom Catalysts for Enhanced Catalytic Performance. Nano Research, 13, 1842-1855. [Google Scholar] [CrossRef] 
[7] Fei, H., Dong, J., Chen, D., et al. (2019) Single Atom Electrocat-alysts Supported on Graphene or Graphene-Like Carbons. Chemical Society Reviews, 48, 5207-5241. [Google Scholar] [CrossRef] 
[8] Gong, Y.N., Jiao, L., Qian, Y., et al. (2020) Regulating the Coordination Environment of MOF-Templated Single- Atom Nickel Electrocatalysts for Boosting CO2 Reduction. Angewandte Chemie-International Edition, 59, 2705-2709. [Google Scholar] [CrossRef] [PubMed]
[9] Geng, Z., Cao, Y., Chen, W., et al. (2019) Regulating the Coordina-tion Environment of Co Single Atoms for Achieving Efficient Electrocatalytic Activity in CO2 Reduction. Applied Catal-ysis B-Environmental, 240, 234-240. [Google Scholar] [CrossRef] 
[10] Zhu, Y., Peng, W., Li, Y., et al. (2019) Modulating the Electronic Structure of Single-Atom Catalysts on 2D Nanomaterials for Enhanced Electrocatalytic Performance. Small Methods, 3, 1800438-1800466. [Google Scholar] [CrossRef] 
[11] Liang, J., Yu, Q., Yang, X., et al. (2018) A Systematic Theoretical Study on FeOx-Supported Single-Atom Catalysts: M1/FeOx for CO Oxidation. Nano Research, 11, 1599-1611. [Google Scholar] [CrossRef] 
[12] Wang, Y., Chen, Z., Shen, R., et al. (2016) Pd-Dispersed CuS Hetero-Nanoplates for Selective Hydrogenation of Phenylacetylene. Nano Research, 9, 1209-1219. [Google Scholar] [CrossRef] 
[13] Wang, Q., Ina, T., Chen, W.T., et al. (2020) Evolution of Zn(II) Single Atom Catalyst Sites during the Pyrolysis-Induced Transformation of ZIF-8 to N-Doped Carbons. Science Bulletin, 65, 1743-1751. [Google Scholar] [CrossRef] [PubMed]
[14] Pan, Y., Chen, Y., Wu, K., et al. (2019) Regulating the Coordina-tion Structure of Single-Atom Fe-NxCy Catalytic Sites for Benzene Oxidation. Nature Communications, 10, 4290-4301. [Google Scholar] [CrossRef] [PubMed]
[15] Xu, M., Li, D., Sun, K., et al. (2021) Interfacial Microenviron-ment Modulation Boosting Electron Transfer between Metal Nanoparticles and MOFs for Enhanced Photocatalysis. An-gewandte Chemie-International Edition, 60, 16372- 16376. [Google Scholar] [CrossRef] [PubMed]
[16] Zhu, Y., Yang, X., Peng, C., et al. (2021) Carbon-Supported Single-Atom Catalysts: Carbon-Supported Single Metal Site Cata-lysts for Electrochemical CO2 Reduction to CO and Beyond. Small, 17, 2005148-2005172. [Google Scholar] [CrossRef] [PubMed]
[17] Najam, T., Shah, S.S.A., Ding, W., et al. (2019) Role of P-doping in Antipoisoning: Efficient MOF-Derived 3D Hierarchical Architectures for the Oxygen Reduction Reaction. The Journal of Physical Chemistry C, 123, 16796-16803. [Google Scholar] [CrossRef] 
[18] Shah, S.S.A., Najam, T., Javed, M.S., et al. (2021) Novel Mn-/Co-Nx Moieties Captured in N-Doped Carbon Nanotubes for Enhanced Oxygen Reduction Activity and Stability in Acidic and Alkaline Media. ACS Applied Materials & Interfaces, 13, 23191-23200. [Google Scholar] [CrossRef] [PubMed]
[19] Shah, S.S.A., Najam, T., Bashir, M.S., et al. (2022) Single-Atom Catalysts for Next-Generation Rechargeable Batteries and Fuel Cells. Energy Storage Materials, 45, 301-322. [Google Scholar] [CrossRef] 
[20] Xu, Z., Deng, W. and Wang, X. (2021) 3D Hierarchical Car-bon-Rich Micro-/Nanomaterials for Energy Storage and Catalysis. Electrochemical Energy Reviews, 4, 269-335. [Google Scholar] [CrossRef] 
[21] Jiang, J.S., Wei, H.L., Tan, A.D., et al. (2021) Fabricating High-Loading Fe-N4 Single-Atom Catalysts for Oxygen Reduction Reaction by Carbon-Assisted Pyrolysis of Metal Complexes. Chinese Journal of Catalysis, 42, 753-761. [Google Scholar] [CrossRef] 
[22] Yan, X., Jia, Y. and Yao, X. (2021) Defective Structures in Metal Compounds for Energy-Related Electrocatalysis. Small Structures, 2, Article ID: 2000067. [Google Scholar] [CrossRef] 
[23] Xie, C., Lin, L., Huang, L., et al. (2021) Zn-Nx Sites on N-Doped Carbon for Aerobic Oxidative Cleavage and Esterification of C(CO)-C Bonds. Nature Communications, 12, 4823-4835. [Google Scholar] [CrossRef] [PubMed]
[24] Peng, L., Wang, C., Wang, Q., et al. (2021) Rationally Designed Ni-Ni3S2 Interfaces for Efficient Overall Water Electrolysis. Advanced Energy and Sustainability Research, 2, 2100078-2100085. [Google Scholar] [CrossRef] 
[25] Zhang, H., Liu, Y., Chen, T., et al. (2019) Un-veiling the Activity Origin of Electrocatalytic Oxygen Evolution over Isolated Ni Atoms Supported on a N-Doped Car-bon Matrix. Advanced Materials, 31, 1904548-1904555. [Google Scholar] [CrossRef] [PubMed]
[26] Tomboc, G. M., Kim, T., Jung, S., et al. (2022) Modulating the Lo-cal Coordination Environment of Single-Atom Catalysts for Enhanced Catalytic Performance in Hydrogen/Oxygen Evo-lution Reaction. Small, 18, Article ID: 2105680. [Google Scholar] [CrossRef] [PubMed]
[27] Wan, J., Zhao, Z., Shang, H., et al. (2020) In Situ Phosphatizing of Triphenylphosphine Encapsulated within Metal- Organic Frameworks to Design Atomic Co1-P1N3 Interfacial Structure for Promoting Catalytic Performance. Journal of the American Chemical Society, 142, 8431-8439. [Google Scholar] [CrossRef] [PubMed]
[28] Han, Y., Wang, Y., Xu, R., et al. (2018) Electronic Structure Engineering to Boost Oxygen Reduction Activity by Controlling the Coordination of the Central Metal. Energy & Environmental Sci-ence, 11, 2348-2352. [Google Scholar] [CrossRef] 
[29] Zhang, J., Zhao, Y., Chen, C., et al. (2019) Tuning the Coordination Environment in Single-Atom Catalysts to Achieve Highly Efficient Oxygen Reduction Reactions. Journal of the Ameri-can Chemical Society, 141, 20118-20126. [Google Scholar] [CrossRef] [PubMed]
[30] Jiang, Z., Sun, W., Shang, H., et al. (2019) Atomic Interface Effect of a Single Atom Copper Catalyst for Enhanced Oxygen Reduction Reactions. Energy & Environmental Science, 12, 3508-3514. [Google Scholar] [CrossRef] 
[31] Ma, Y., Chi, B., Liu, W., et al. (2019) Tailoring of the Proximity of Platinum Single Atoms on CeO2 Using Phosphorus Boosts the Hydrogenation Activity. Acs Catalysis, 9, 8404-8412. [Google Scholar] [CrossRef] 
[32] Chen, Y., Ji, S., Zhao, S., et al. (2022) Enhanced Oxy-gen Reduction with Single-Atomic-Site Iron Catalysts for a Zinc- Air Battery and Hydrogen-Air Fuel Cell. Nature Communications, 9, 5422-2018. [Google Scholar] [CrossRef] [PubMed]
[33] Zhang, X., Lin, H., Zhang, J., et al. (2021) Decreasing the Coor-dinated N Atoms in a Single-Atom Cu Catalyst to Achieve Selective Transfer Hydrogenation of Alkynes. Chemical Sci-ence, 12, 14599-14605. [Google Scholar] [CrossRef] 
[34] Zhang, X., Lu, G.P., Wang, K., et al. (2022) Lignin-Derived Zn Single Atom/N-Codoped Porous Carbon for Alpha-Alkylation of Aromatic Ketones with Alcohols via Borrowing Hydrogen Strategy. Nano Research, 15, 1874-1881. [Google Scholar] [CrossRef] 
[35] Chen, Y., Gao, R., Ji, S., et al. (2022) Atomic-Level Modulation of Electronic Density at Cobalt Single-Atom Sites Derived from Metal-Organic Frameworks: Enhanced Oxygen Reduc-tion Performance. Angewandte Chemie-International Edition, 60, 3212-2021. [Google Scholar] [CrossRef] [PubMed]
[36] Jin, H., Li, P., Cui, P., et al. (2022) Unprecedentedly High Activity and Selectivity for Hydrogenation of Nitroarenes with Single Atomic Co1-N3P1 Sites. Nature Communications, 13, 723-732. [Google Scholar] [CrossRef] [PubMed]
[37] Liu, W., Cao, L., Cheng, W., et al. (2017) Single-Site Active Cobalt-Based Photocatalyst with a Long Carrier Lifetime for Spontaneous Overall Water Splitting. Angewandte Chemie-International Edition, 129, 9440-9445. [Google Scholar] [CrossRef] 
[38] Huang, P., Huang, J., Pantovich, S.A., et al. (2018) Selective CO2 Reduction Catalyzed by Single Cobalt Sites on Carbon Nitride under Visible-Light Irradiation. Journal of the American Chemical Society, 140, 16042-16047. [Google Scholar] [CrossRef] [PubMed]
[39] Ma, M., Huang, Z., Doronkin, D.E., et al. (2022) Ultrahigh Surface Density of Co-N2C Single-Atom-Sites for Boosting Photocatalytic CO2 Reduction to Methanol. Applied Catalysis B: En-vironmental, 300, 120695-120736. [Google Scholar] [CrossRef] 
[40] Yuan, K., Luetzenkirchen-Hecht, D., Li, L., et al. (2020) Boost-ing Oxygen Reduction of Single Iron Active Sites via Geometric and Electronic Engineering: Nitrogen and Phosphorus Dual Coordination. Journal of the American Chemical Society, 142, 2404-2412. [Google Scholar] [CrossRef] [PubMed]
[41] Shah, S.S.A., Najam, T., Yang, J., et al. (2022) Modulating the Micro-environment Structure of Single Zn Atom: ZnN4 P/C Active Site for Boosted Oxygen Reduction Reaction. Chinese Journal of Catalysis, 43, 2193-2201. [Google Scholar] [CrossRef] 
[42] Yu, J., Li, J., Xu, C.Y., et al. (2022) Modulating the d-Band Centers by Coordination Environment Regulation of Single-Atom Ni on Porous Carbon Fibers for Overall Water Split-ting. Nano Energy, 98, Article ID: 107622. [Google Scholar] [CrossRef] 

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