MOF/COF复合材料合成与应用研究进展
Research Progress on Synthesis and Application of MOF/COF Composites
DOI: 10.12677/MS.2023.133013, PDF,  被引量   
作者: 揭广岸, 朱百慧, 职晓焱, 冯 嫣, 宋敬璇, 董方园, 傅仰河*：浙江师范大学含氟新材料研究所，先进催化材料教育部重点实验室，浙江 金华
关键词: 金属有机骨架；共价有机骨架；复合材料；合成策略；应用； Metal Organic Frameworks； Covalent Organic Frameworks； Composites； Synthesis Strategies； Applications
摘要: 金属有机骨架材料(MOF)和共价有机骨架材料(COF)因结构易调控、具有较大的比表面积和高孔隙率等优点逐渐成为材料研究领域的热点。但MOF和COF自身仍存在不足，将不同类型的MOF和COF材料进行有效复合，不仅可以保持各自的优势，还可以解决各自存在的不足，在各种应用中表现出优异的潜力。因此，基于MOF/COF的复合材料得到了越来越多的关注和快速发展。本文主要论述了MOF/COF复合材料的合成方法及其在吸附和分离、光催化、传感和储能领域的应用。
Abstract: Metal organic frameworks (MOF) and covalent organic frameworks (COF) have gradually become hot spots in the field of materials research due to the advantages of easy structural adjustment, large specific surface area and high porosity. However, MOF and COF still have their own shortcomings, and the effective compounding of different types of MOF and COF materials can not only maintain their re-spective advantages, but also solve their respective shortcomings. The composites have shown ex-cellent potential in various applications. Therefore, MOF/COF composites have received more and more attention and rapid development. In this paper, the synthetic strategies of MOF/COF compo-sites and their applications in adsorption and separation, photocatalysis, sensing and energy stor-age are discussed.
文章引用：揭广岸, 朱百慧, 职晓焱, 冯嫣, 宋敬璇, 董方园, 傅仰河. MOF/COF复合材料合成与应用研究进展[J]. 材料科学, 2023, 13(3): 103-110. https://doi.org/10.12677/MS.2023.133013

参考文献

[1] Wu, Q., Luan, H. and Xiao, F. (2022) Theoretical Design for Zeolite Synthesis. Science China—Chemistry, 65, 1683-1690. [Google Scholar] [CrossRef] 
[2] Tian, Y. and Zhu, G. (2020) Porous Aromatic Frameworks (PAFs). Chemical Reviews, 120, 8934-8986. [Google Scholar] [CrossRef] [PubMed]
[3] Chen, J., Abazari, R., Adegoke, K.A., et al. (2022) Met-al-Organic Frameworks and Derived Materials as Photocatalysts for Water Splitting and Carbon Dioxide Reduction. Co-ordination Chemistry Reviews, 469, Article ID: 214664. [Google Scholar] [CrossRef] 
[4] Geng, K., He, T., Liu, R., et al. (2020) Covalent Organic Frame-works: Design, Synthesis, and Functions. Chemical Reviews, 120, 8814-8933. [Google Scholar] [CrossRef] [PubMed]
[5] Ebadi Amooghin, A., Sanaeepur, H., Luque, R., et al. (2022) Fluorinated Metal-Organic Frameworks for Gas Separation. Chemical Society Reviews, 51, 7427-7508. [Google Scholar] [CrossRef] 
[6] Wang, Y., Lv, H., Grape, E.S., et al. (2021) A Tunable Multivariate Metal-Organic Framework as a Platform for Designing Photocatalysts. Journal of the American Chemical Society, 143, 6333-6338. [Google Scholar] [CrossRef] [PubMed]
[7] Li, J., Jing, X., Li, Q., et al. (2020) Bulk COFs and COF Nanosheets for Electrochemical Energy Storage and Conversion. Chemical Society Reviews, 49, 3565-3604. [Google Scholar] [CrossRef] 
[8] Ma, X., Kang, J., Wu, Y., et al. (2022) Recent Advances in Met-al/Covalent Organic Framework-Based Materials for Photoelectrochemical Sensing Applications. Trac-Trends in Analyt-ical Chemistry, 157, Article ID: 116793. [Google Scholar] [CrossRef] 
[9] Song, Y., Sun, Q., Aguila, B., et al. (2019) Opportunities of Cova-lent Organic Frameworks for Advanced Applications. Advanced Science, 6, Article ID: 1801410. [Google Scholar] [CrossRef] [PubMed]
[10] Yuan, S., Feng, L., Wang, K., et al. (2018) Stable Metal-Organic Frameworks: Design, Synthesis, and Applications. Advanced Materials, 30, Article ID: 1704303. [Google Scholar] [CrossRef] [PubMed]
[11] Chen, X., Geng, K., Liu, R., et al. (2020) Covalent Organic Frame-works: Chemical Approaches to Designer Structures and Built-In Functions. Angewandte Chemie-International Edition, 59, 5050-5091. [Google Scholar] [CrossRef] [PubMed]
[12] Ding, M., Cai, X. and Jiang, H. (2019) Improving MOF Stability: Approaches and Applications. Chemical Science, 10, 10209-10230. [Google Scholar] [CrossRef] 
[13] Deng, Y., Wang, Y., Xiao, X., et al. (2022) Progress in Hybridization of Covalent Organic Frameworks and Metal-Organic Frameworks. Small, 18, Article ID: 2202928. [Google Scholar] [CrossRef] [PubMed]
[14] Li, Y., Karimi, M., Gong, Y., et al. (2021) Integration of Met-al-Organic Frameworks and Covalent Organic Frameworks: Design, Synthesis, and Applications. Matter, 4, 2230-2265. [Google Scholar] [CrossRef] 
[15] Chen, Z., Li, X., Yang, C., et al. (2021) Hybrid Porous Crystalline Materials from Metal Organic Frameworks and Covalent Organic Frameworks. Advanced Science, 8, Article ID: 2101883. [Google Scholar] [CrossRef] [PubMed]
[16] Zhang, F., Sheng, J., Yang, Z., et al. (2018) Rational De-sign of MOF/COF Hybrid Materials for Photocatalytic H2 Evolution in the Presence of Sacrificial Electron Donors. An-gewandte Chemie-International Edition, 57, 12106-12110. [Google Scholar] [CrossRef] [PubMed]
[17] Liu, X., Hu, M., Wang, M., et al. (2019) Novel Nanoarchitecture of Co-MOF-on-TPN-COF Hybrid: Ultralowly Sensitive Bioplatform of Electrochemical Aptasensor toward Ampicillin. Biosensors & Bioelectronics, 123, 59-68. [Google Scholar] [CrossRef] [PubMed]
[18] Sun, W., Tang, X., Yang, Q., et al. (2019) Coordination-Induced Interlinked Covalent- and Metal-Organic-Framework Hybrids for Enhanced Lithium Storage. Advanced Materials, 31, Article ID: 1903176. [Google Scholar] [CrossRef] [PubMed]
[19] Li, F., Wang, D., Xing, Q., et al. (2019) Design and Syntheses of MOF/COF Hybrid Materials via Postsynthetic Covalent Modification: An Efficient Strategy to Boost the Visi-ble-Light-Driven Photocatalytic Performance. Applied Catalysis B-Environmental, 243, 621-628. [Google Scholar] [CrossRef] 
[20] Cai, M., Li, Y., Liu, Q., et al. (2019) One-Step Construction of Hydrophobic MOFs@COFs Core-Shell Composites for Heterogeneous Selective Catalysis. Advanced Science, 6, Article ID: 1802365. [Google Scholar] [CrossRef] [PubMed]
[21] Chen, Y., Yang, D., Shi, B., et al. (2020) In Situ Con-struction of Hydrazone-Linked COF-Based Core-Shell Hetero-Frameworks for Enhanced Photocatalytic Hydrogen Evo-lution. Journal of Materials Chemistry A, 8, 7724-7732. [Google Scholar] [CrossRef] 
[22] Lu, G., Huang, X., Li, Y., et al. (2020) Covalently Integrated Core-Shell MOF@COF Hybrids as Efficient Visible- Light-Driven Photocatalysts for Selective Oxidation of Alcohols. Journal of Energy Chemistry, 43, 8-15. [Google Scholar] [CrossRef] 
[23] Liang, F., Wang, K., Lv, X., et al. (2020) Modular Total Synthe-sis in Reticular Chemistry. Journal of the American Chemical Society, 142, 3069-3076. [Google Scholar] [CrossRef] [PubMed]
[24] Firoozi, M., Rafiee, Z. and Dashtian, K. (2020) New MOF/COF Hybrid as a Robust Adsorbent for Simultaneous Removal of Auramine O and Rhodamine B Dyes. Acs Omega, 5, 9420-9428. [Google Scholar] [CrossRef] [PubMed]
[25] Das, S., Ben, T., Qiu, S., et al. (2020) Two-Dimensional COF-Three-Dimensional MOF Dual-Layer Membranes with Unprecedentedly High H2/CO2 Selectivity and Ultrahigh Gas Permeabilities. ACS Applied Materials & Interfaces, 12, 52899-52907. [Google Scholar] [CrossRef] [PubMed]
[26] Wang, Y., Yang, Q., Yi, F., et al. (2021) NH2-UiO-66 Coated with Two-Dimensional Covalent Organic Frameworks: High Stability and Photocatalytic Activity. ACS Applied Materials & Interfaces, 13, 29916-29925. [Google Scholar] [CrossRef] [PubMed]
[27] Niu, Q., Dong, S., Tian, J., et al. (2022) Rational Design of Novel COF/MOF S-Scheme Heterojunction Photocatalyst for Boosting CO2 Reduction at Gas-Solid Interface. ACS Applied Materials & Interfaces, 14, 24299-24308. [Google Scholar] [CrossRef] [PubMed]
[28] Chen, C., Xiong, Y., Zhong, X., et al. (2022) Enhancing Photocata-lytic Hydrogen Production via the Construction of Robust Multivariate Ti-MOF/COF Composites. Angewandte Chemie-International Edition, 61, Article ID: 2114071. [Google Scholar] [CrossRef] [PubMed]
[29] Wang, J., Wang, L., Wang, Y., et al. (2022) Covalently Connected Core-Shell NH2-UiO-66@Br-COFs Hybrid Materials for CO2 Capture and I2 Vapor Adsorption. Chemical Engineering Journal, 438, Article ID: 135555. [Google Scholar] [CrossRef] 
[30] Wang, J., Dai, Z., Wang, L., et al. (2023) A Z-Scheme Heterojunc-tion of Porphyrin-Based Core-Shell Zr-MOF@Pro- COF-Br Hybrid Materials for Efficient Visible-Light-Driven CO2 Reduction. Journal of Materials Chemistry A, 11, 2023-2030. [Google Scholar] [CrossRef] 
[31] Peng, Y., Zhao, M., Chen, B., et al. (2018) Hybridization of MOFs and COFs: A New Strategy for Construction of MOF@COF Core-Shell Hybrid Materials. Advanced Materials, 30, Article ID: 1705454. [Google Scholar] [CrossRef] [PubMed]
[32] Wadhawan, S., Jain, A., Nayyar, J., et al. (2020) Role of Nano-materials as Adsorbents in Heavy Metal Ion Removal from Waste Water: A Review. Journal of Water Process Engi-neering, 33, Article ID: 101038. [Google Scholar] [CrossRef] 
[33] Sholl, D. and Lively, R. (2016) Seven Chemical Separations to Change the World. Nature, 532, 435-437. [Google Scholar] [CrossRef] [PubMed]
[34] Li, W., Shi, W., Hu, Z., et al. (2020) Fabrication of Magnetic Fe3O4@metal Organic framework@covalent Organic Framework Composite and Its Selective Separation of Trace Copper. Applied Surface Science, 530, Article ID: 147254. [Google Scholar] [CrossRef] 
[35] Koros, W. and Zhang, C. (2017) Materials for Next-Generation Molecularly Selective Synthetic Membranes. Nature Materials, 16, 289-297. [Google Scholar] [CrossRef] [PubMed]
[36] Garzon-Tovar, L., Perez-Carvajal, J., Yazdi, A., et al. (2019) A MOF@COF Composite with Enhanced Uptake through Interfacial Pore Generation. Angewandte Chemie-International Edition, 58, 9512-9516. [Google Scholar] [CrossRef] [PubMed]
[37] Zhang, F., Wang, X., Liu, H., et al. (2019) Recent Advances and Ap-plications of Semiconductor Photocatalytic Technology. Applied Sciences-Basel, 9, 2489. [Google Scholar] [CrossRef] 
[38] Liu, J., Ma, N., Wu, W., et al. (2020) Recent Progress on Photocatalytic Heterostructures with Full Solar Spectral Responses. Chemical Engineering Journal, 393, Article ID: 124719. [Google Scholar] [CrossRef] 
[39] Li, Z., Guo, J., Wan, Y., et al. (2022) Combining Metal-Organic Frameworks (MOFs) and Covalent-Organic Frameworks (COFs): Emerging Opportunities for New Materials and Ap-plications. Nano Research, 15, 3514-3532. [Google Scholar] [CrossRef] 
[40] Gong, E., Ali, S., Hiragond, C.B., et al. (2022) Solar Fuels: Re-search and Development Strategies to Accelerate Photocatalytic CO2 Conversion into Hydrocarbon Fuels. Energy & En-vironmental Science, 15, 880-937. [Google Scholar] [CrossRef] 
[41] Wang, L., Mao, J., Huang, G., et al. (2022) Configuration of Het-ero-Framework via Integrating MOF and Triazine- Containing COF for Charge-Transfer Promotion in Photocatalytic CO2 Reduction. Chemical Engineering Journal, 446, Article ID: 137011. [Google Scholar] [CrossRef] 
[42] Tajik, S., Beitollahi, H., Nejad, F.G., et al. (2021) Recent Develop-ments in Polymer Nanocomposite-Based Electrochemical Sensors for Detecting Environmental Pollutants. Industrial & Engineering Chemistry Research, 60, 1112- 1136. [Google Scholar] [CrossRef] [PubMed]
[43] Chen, W., Liu, S., Fu, Y., et al. (2022) Recent Advances in Photoelectrocatalysis for Environmental Applications: Sensing, Pollutants Re-moval and Microbial Inactivation. Coordination Chemistry Reviews, 454, Article ID: 214341. [Google Scholar] [CrossRef] 
[44] Yuan, R., Li, H. and He, H. (2021) Recent Advances in Met-al/Covalent Organic Framework-Based Electrochemical Aptasensors for Biosensing Applications. Dalton Transactions, 50, 14091-14104. [Google Scholar] [CrossRef] 
[45] Zhou, N., Ma, Y., Hu, B., et al. (2019) Construction of Ce-MOF@COF Hybrid Nanostructure: Label-Free Aptasensor for the Ultrasensitive Detection of Oxytetracycline Resi-dues in Aqueous Solution Environments. Biosensors & Bioelectronics, 127, 92-100. [Google Scholar] [CrossRef] [PubMed]
[46] Cui, X., Dong, H., Chen, S., et al. (2021) Progress and Perspective of Metal- and Covalent-Organic Frameworks and their Derivatives for Lithium-Ion Batteries. Batteries & Supercaps, 4, 72-97. [Google Scholar] [CrossRef] 
[47] Wang, S., Guo, Y., Wang, F., et al. (2022) Research Progress on Metal and Covalent Organic Framework-Based Materials for High-Performance Supercapacitors. New Carbon Mate-rials, 37, 109-132. [Google Scholar] [CrossRef] 
[48] Cui, B. and Fu, G. (2022) Process of Metal-Organic Framework (MOF)/Covalent-Organic Framework (COF) Hybrids- Based Derivatives and Their Applications on Energy Transfer and Storage. Nanoscale, 14, 1679-1699. [Google Scholar] [CrossRef] 
[49] Peng, H., Raya, J., Richard, F., et al. (2020) Synthesis of Robust MOFs@COFs Porous Hybrid Materials via an Aza- Diels-Alder Reaction: Towards High-Performance Supercapacitor Materials. Angewandte Chemie-International Edition, 59, 19602-19609. [Google Scholar] [CrossRef] [PubMed]

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