氮氟共掺杂多孔石墨烯构建无酶葡萄糖传感器
Construction of Enzyme-Free Glucose Sensor by Nitrogen-Fluorine Co-Doped Porous Graphene
DOI: 10.12677/HJCET.2023.132013, PDF,   
作者: 位 晴:武汉工程大学化学与环境工程学院,湖北 武汉
关键词: 多孔石墨烯无酶葡萄糖传感器电化学Porous Grapheme Enzyme-Free Glucose Sensor Electrochemistry
摘要: 本文在氮气气氛中,通过高温煅烧法制备了具有多孔结构的N掺杂石墨烯(N-PrGO)和N,F共掺杂石墨烯(N,F-PrGO),通过X射线衍射光电子能谱(XPS)、拉曼光谱测试(Raman)等对材料的结构组成进行表征,使用CHI 760E电化学工作站进行性能测试。实验结果表明,与N-PrGO相比,F,N-PrGO纳米复合材料显示出优异的传感性能,并且具有宽的线性范围。
Abstract: In this paper, N-doped graphene (N-PrGO) and N,F-co-doped graphene (N,F-PrGO) with porous structure were prepared by high-temperature calcination method in a nitrogen atmosphere, and their structural compositions were characterized by X-ray diffraction photoelectron spectroscopy (XPS) and Raman spectroscopy (Raman). The CHI 760E electrochemical workstation was used for performance testing. The experimental results show that compared with N-PrGO, F,N-PrGO nanocomposites show excellent sensing performance and wide linear range.
文章引用:位晴. 氮氟共掺杂多孔石墨烯构建无酶葡萄糖传感器[J]. 化学工程与技术, 2023, 13(2): 115-119. https://doi.org/10.12677/HJCET.2023.132013

参考文献

[1] Alberti, K.G.M.M. and Zimmet, P.Z. (1998) Definition, Diagnosis and Classification of Diabetes Mellitus and Its Complications. Part 1: Diagnosis and Classification of Diabetes Mellitus. Provisional Report of a WHO Consultation. Diabetic Medicine, 15, 539-553. [Google Scholar] [CrossRef
[2] Ping, J., Zhou, Y., Wu, Y., et al. (2015) Recent Advances in Aptasensors Based on Graphene and Graphene-Like Nano-materials. Biosensors and Bioelectronics, 64, 373-385. [Google Scholar] [CrossRef] [PubMed]
[3] 李佳根, 王杰, 付凤琴, 等. 无酶自组装葡萄糖生物传感器研究[J]. 化学研究与应用, 2021, 33(11): 2228-2233.
[4] 朱正卫, 王敬元. 金属化合物无酶葡萄糖传感器研究进展[J]. 广州化工, 2021, 49(20): 11-13.
[5] 李宁, 徐伟航, 张瑞瑞, 等. 氢氧化铜纳米线用于无酶葡萄糖传感器的研究[J]. 湖北科技学院学报(医学版), 2022, 36(5): 380-384.
[6] Tian, T., Dong, J. and Xu, J. (2016) Direct Electrodeposition of Highly Ordered Gold Nanotube Arrays for Use in Non-Enzymatic Amperometric Sensing of Glucose. Microchimica Acta, 183, 1925-1932. [Google Scholar] [CrossRef
[7] 朱旭, 李春兰, 刘琴, 等. 石墨烯/纳米金复合材料的无酶葡萄糖生物传感器制备[J]. 分析化学, 2011, 39(12): 1846-1851.
[8] Chen, X., He, X., Gao, J., et al. (2019) Three-Dimensional Porous Ni, N-Codoped C Networks for Highly Sensitive and Selective Non-Enzymatic Glucose Sensing. Sensors and Actuators B: Chemical, 299, Article ID: 126945. [Google Scholar] [CrossRef
[9] Kim, D.S., Moon, I.K., Yang, J.H., et al. (2020) Mesoporous ZnCo2O4 Nanowire Arrays with Oxygen Vacancies and N-Dopants for Significant Improvement of Non-Enzymatic Glucose Detection. Journal of Electroanalytical Chemistry, 878, Article ID: 114585. [Google Scholar] [CrossRef
[10] Mazaheri, M., Aashuri, H. and Simchi, A. (2017) Three-Dimensional Hybrid Graphene/Nickel Electrodes on Zinc Oxide Nanorod Arrays as Non-Enzymatic Glucose Biosensors. Sensors and Actuators B: Chemical, 251, 462-471. [Google Scholar] [CrossRef
[11] Li, S.-J., Hou, L.-L., Yuan, B.-Q., et al. (2016) Enzyme-Free Glucose Sensor Using a Glassy Carbon Electrode Modified with Reduced Graphene Oxide Decorated with Mixed Copper and Cobalt Oxides. Microchimica Acta, 183, 1813-1821. [Google Scholar] [CrossRef
[12] Zhang, Y. Y., Wan, Q.J. and Yang, N.J. (2019) Recent Ad-vances of Porous Graphene: Synthesis, Functionalization, and Electrochemical Applications. Small, 15, 1903780-1903817. [Google Scholar] [CrossRef] [PubMed]
[13] Mansour, R., Faranak, F. and Hasuck, K. (2019) A New Enzyme-Free Biosensor Based on Nitrogen-Doped Graphene with High Sensing Performance for Electrochemical Detection of Glucose at Biological pH Value. Sensors and Actuators B: Chemical, 282, 322-330. [Google Scholar] [CrossRef
[14] Peera, S.G., Sahu, A.K., Arunchander, A., et al. (2015) Ni-trogen and Fluorine Co-Doped Graphite Nanofibers as High Durable Oxygen Reduction Catalyst in Acidic Media for Polymer Electrolyte Fuel Cells. Carbon, 93, 130-142. [Google Scholar] [CrossRef