膨胀石墨基复合材料在电化学中的应用
Application of Expanded Graphite Matrix Composites in Electrochemistry
DOI: 10.12677/OJNS.2023.112027, PDF,   
作者: 陈 哲:武汉工程大学化学与环境工程学院,湖北 武汉
关键词: 膨胀石墨复合材料电化学Expanded Graphite Composite Materials Electrochemistry
摘要: 膨胀石墨(EG)是由天然鳞片石墨制得的一种疏松多孔的蠕虫状新型碳材料,具有多孔结构、大比表面积、高表面能、良好的导电性和机械柔韧性等优点,有着广泛的用途。为了进一步提高原始多孔材料的性能,常常会将多孔材料与其他材料相结合,构建的复合材料能表现更优异的性能。在这篇综述中,着重介绍了基于膨胀石墨与金属纳米粒子、金属氧化物、金属硫化物、金属氢氧化物、导电聚合物以及金属有机骨架等构建的复合材料在电化学传感、电催化、电化学储能等方面的应用。
Abstract: Expanded graphite (EG) is a new type of loose and porous worm-like carbon material made from natural flake graphite. It has many advantages, such as porous structure, large specific surface area, high surface energy, good conductivity and mechanical flexibility, and has a wide range of applications. In order to further improve the performance of original porous materials, porous materials are often combined with other materials, and the composite materials constructed can perform better performance. In this review, the application of composite materials based on expanded graphite and metal nanoparticles, metal oxides, metal sulfides, metal hydroxides, conductive polymers, and metal-organic frameworks in electrochemical sensing, electrocatalysis, and electrochemical energy storage is emphatically introduced.
文章引用:陈哲. 膨胀石墨基复合材料在电化学中的应用[J]. 自然科学, 2023, 11(2): 227-235. https://doi.org/10.12677/OJNS.2023.112027

参考文献

[1] Matsunaga, T., Takagi, S., Shimoda, K., et al. (2019) Comprehensive Elucidation of Crystal Structures of Lithium Intercalated Graphite. Carbon, 142, 513-517. [Google Scholar] [CrossRef
[2] Jara, A.D., Betemariam, A., Woldetinsae, G. and Kim, J.Y. (2019) Purification, Application and Current Market Trend of Natural Graphite: A Review. International Journal of Mining Science and Technology, 29, 671-689. [Google Scholar] [CrossRef
[3] Çalın, Ö., Kurt, A. and Çelik, Y. (2020) Influence of Expan-sion Conditions and Precursor Flake Size on Porous Structure of Expanded Graphite. Fullerenes, Nanotubes and Carbon Nanostructures, 28, 611-620. [Google Scholar] [CrossRef
[4] Liu, T., Zhang, R., Zhang, X., et al. (2017) One-Step Room-Temperature Preparation of Expanded Graphite. Carbon, 119, 544-547. [Google Scholar] [CrossRef
[5] Dai, C., Gu, C., Liu, B., et al. (2019) Preparation of Low-Temperature Expandable Graphite as a Novel Steam Plugging Agent in Heavy Oil Reservoirs. Journal of Molecular Liquids, 293, Article ID: 111535. [Google Scholar] [CrossRef
[6] Darabut, A.M., Lobko, Y., Yakovlev, Y., et al. (2022) In-fluence of Thermal Treatment on the Structure and Electrical Conductivity of Thermally Expanded Graphite. Ad-vanced Powder Technology, 33, Article ID: 103884. [Google Scholar] [CrossRef
[7] Terence, M.C., Silva, E.E. and Carrió, J.A.G. (2014) Elec-trochemically Exfoliated Graphene. Journal of Nano Research, 29, 29-33. [Google Scholar] [CrossRef
[8] Wu, L., Li, W., Li, P., et al. (2014) Powder, Paper and Foam of Few-Layer Graphene Prepared in High Yield by Electrochemical Intercalation Exfoliation of Expanded Graphite. Small, 10, 1421-1429. [Google Scholar] [CrossRef] [PubMed]
[9] Xiang, X., Feng, S., Chen, J., et al. (2019) Gold Nanoparti-cles/Electrochemically Expanded Graphite Composite: A Bifunctional Platform toward Glucose Sensing and SERS Applications. Journal of Electroanalytical Chemistry, 851, Article ID: 113471. [Google Scholar] [CrossRef
[10] Yu, Q., Wei, L., Yang, X., et al. (2022) Electrochemical Synthesis of Graphene Oxide from Graphite Flakes Exfoliated at Room Temperature. Applied Surface Science, 598, Article ID: 153788. [Google Scholar] [CrossRef
[11] Gavilán-Arriazu, E.M., Pinto, O.A., López de Mishima, B.A., et al. (2018) The Kinetic Origin of the Daumas-Hérold Model for the Li-Ion/Graphite Intercalation System. Electrochemistry Communications, 93, 133-137. [Google Scholar] [CrossRef
[12] Lan, R., Su, W. and Li, J. (2019) Preparation and Catalytic Performance of Expanded Graphite for Oxidation of Organic Pollutant. Catalysts, 9, 280. [Google Scholar] [CrossRef
[13] Hou, B., Sun, H.-J., Peng, T.-J., et al. (2020) Rapid Preparation of Expanded Graphite at Low Temperature. New Carbon Materials, 35, 262-268. [Google Scholar] [CrossRef
[14] Li, X., Lei, Y., Qin, L., et al. (2021) Mildly-Expanded Graphite with Adjustable Interlayer Distance as High-Performance Anode for Potassium-Ion Batteries. Carbon, 172, 200-206. [Google Scholar] [CrossRef
[15] Zhao, J., Dumont, J.H., Martinez, U., et al. (2020) Graphite Intercalation Compounds Derived by Green Chemistry as Oxygen Reduction Reaction Catalysts. ACS Applied Materials & Interfaces, 12, 42678-42685. [Google Scholar] [CrossRef] [PubMed]
[16] Pham, T.V., Nguyen, T.T., Nguyen, D.T., et al. (2019) The Preparation and Characterization of Expanded Graphite via Microwave Irradiation and Conventional Heating for the Purification of Oil Contaminated Water. Journal of Nanoscience and Nanotechnology, 19, 1122-1125. [Google Scholar] [CrossRef] [PubMed]
[17] Deng, R., Chu, F., Yu, H., et al. (2022) Electrochemical Perfor-mance of Expanded Graphite Prepared from Anthracite via a Microwave Method. Fuel Processing Technology, 227, Article ID: 107100. [Google Scholar] [CrossRef
[18] Wu, K.-H., Cheng, K.-F., Wang, J.-C., et al. (2017) Prep-aration of Magnetic Expanded Graphite with Microwave Absorption and Infrared Stealth Characteristics. Materials Express, 7, 500-508. [Google Scholar] [CrossRef
[19] Liu, Z.-X., Zhang, X.-W., Zhang, W.-J., et al. (2019) Microwave-Assisted Fabrication of Slight-Expanded Graphite under Normal Temperature. Materials Science and Technology, 36, 251-254. [Google Scholar] [CrossRef
[20] Emery, N., Hérold, C. and Lagrange, P. (2008) The Synthesis of Binary Metal-Graphite Intercalation Compounds Using Molten Lithium Alloys. Carbon, 46, 72-75. [Google Scholar] [CrossRef
[21] Zhao, Q., Hao, X., Su, S., et al. (2019) Expanded-Graphite Embedded in Lithium Metal as Dendrite-Free Anode of Lithium Metal Batteries. Journal of Materials Chemistry A, 7, 15871-15879. [Google Scholar] [CrossRef
[22] Li, Q., Odoom-Wubah, T., Fu, X., et al. (2020) Photoinduced Pt-Decorated Expanded Graphite toward Low-Temperature Benzene Catalytic Combustion. Industrial & Engineering Chemistry Research, 59, 11453-11461. [Google Scholar] [CrossRef
[23] Mafa, P.J., Mamba, B.B. and Kuvarega, A.T. (2020) Photoe-lectrocatalytic Evaluation of EG-CeO2 Photoanode on Degradation of 2,4-Dichlorophenol. Solar Energy Materials and Solar Cells, 208, Article ID: 110416. [Google Scholar] [CrossRef
[24] Huang, W., Zhang, Y., Li, Y., et al. (2020) Morpholo-gy-Controlled Electrochemical Sensing of Environmental Cd(2+) and Pb(2+) Ions on Expanded Graphite Supported CeO2 Nanomaterials. Analytica Chimica Acta, 1126, 63-71. [Google Scholar] [CrossRef] [PubMed]
[25] Chen, X., Zhang, Y., Li, C., et al. (2020) Nanointerfaces of Expanded Graphite and Fe2O3 Nanomaterials for Electrochemical Monitoring of Multiple Organic Pollutants. Elec-trochimica Acta, 329, Article ID: 135118. [Google Scholar] [CrossRef
[26] Ndiaye, N.M., Sylla, N.F., Ngom, B.D., et al. (2019) High-Performance Asymmetric Supercapacitor Based on Vanadium Dioxide/Activated Expanded Graphite Com-posite and Carbon-Vanadium Oxynitride Nanostructures. Electrochimica Acta, 316, 19-32. [Google Scholar] [CrossRef
[27] Zheng, G., Zhang, Y., Nie, T., et al. (2019) Expanded Graphite Decorated with PdO@C Nanoparticles for Individual and Simultaneous Sensing of Multiple Phenols. Sensors and Actuators B: Chemical, 291, 362-368. [Google Scholar] [CrossRef
[28] Lv, T.A., Min, H., Shu, H., et al. (2020) LiMnPO4 Nanoplates with Optimal Crystal Orientation in Situ Anchored on the Expanded Graphite for High-Rate and Long-Life Lithium Ion Batteries. Electrochimica Acta, 359, Article ID: 136945. [Google Scholar] [CrossRef
[29] Hou, X., Wang, Y., Hu, R., et al. (2019) Catalytic Effect of EG and MoS2 on Hydrolysis Hydrogen Generation Behavior of High-Energy Ball-Milled Mg 10wt.%Ni Alloys in NaCl Solution—A Powerful Strategy for Superior Hydrogen Generation Performance. International Journal of Energy Research, 43, 8426-8438. [Google Scholar] [CrossRef
[30] He, J., Chen, S., Yang, S., et al. (2020) Fabrication of MoS2 Loaded on Expanded Graphite Matrix for High-Efficiency pH-Universal Hydrogen Evolution Reaction. Journal of Alloys and Compounds, 828, Article ID: 154370. [Google Scholar] [CrossRef
[31] Qu, R., Tang, S., Li, Y., et al. (2019) Outstanding Per-formances of Ni2CoS4/Expanded Graphite with Ultrafine Ni2CoS4 Particles for Supercapacitor Applications. Journal of Materials Science: Materials in Electronics, 30, 5052-5064. [Google Scholar] [CrossRef
[32] Yuan, J., Tang, S., Zhu, Z., et al. (2017) Facile Synthesis of High-Performance Ni(OH)2/Expanded Graphite Electrodes for Asymmetric Supercapacitors. Journal of Materials Science: Materials in Electronics, 28, 18022-18030. [Google Scholar] [CrossRef
[33] Zhang, X., Ikram, M., Liu, Z., et al. (2019) Expanded Graphite/NiAl Layered Double Hydroxide Nanowires for Ultra-Sensitive, Ultra-Low Detection Limits and Selective NOx Gas Detection at Room Temperature. RSC Advances, 9, 8768-8777. [Google Scholar] [CrossRef
[34] Guo, J., Li, X., Sun, Y., et al. (2018) In-Situ Confined Formation of NiFe Layered Double Hydroxide Quantum Dots in Expanded Graphite for Active Electrocatalytic Oxygen Evolu-tion. Journal of Solid State Chemistry, 262, 181-185. [Google Scholar] [CrossRef
[35] Wang, J., Fu, D., Ren, B., et al. (2019) Design and Fabrication of Polypyrrole/Expanded Graphite 3D Interlayer Nanohybrids towards High Capacitive Performance. RSC Ad-vances, 9, 23109-23118. [Google Scholar] [CrossRef
[36] Xiong, C., Lin, X., Liu, H., et al. (2019) Fabrication of 3D Ex-panded Graphite-Based (MnO2 Nanowalls and PANI Nanofibers) Hybrid as Bifunctional Material for High-Performance Supercapacitor and Sensor. Journal of the Electrochemical Society, 166, A3965-A3971. [Google Scholar] [CrossRef
[37] Ma, L., Zhang, X., Ikram, M., et al. (2020) Controllable Synthesis of an Intercalated ZIF-67/EG Structure for the Detection of Ultratrace Cd2+, Cu2+, Hg2+ and Pb2+ Ions. Chemical En-gineering Journal, 395, Article ID: 125216. [Google Scholar] [CrossRef