DMF辅助溶剂热法合成ZnOHF微/纳米结构
DMF-Assisted Solvothermal Synthesis of ZnOHF Micro/Nanostructures
DOI: 10.12677/JAPC.2023.122003, PDF,    国家自然科学基金支持
作者: 刘科麟, 王丹琪, 熊天宇, 丁津津*, 王 淼*：南通大学化学与化工学院，江苏 南通
关键词: ZnOHF；DMF；溶剂热法；微米管；光催化活性；ZnOHF； DMF； Solvothermal Method； Microtubes； Photocatalytic Activity
摘要: 本文以NH4BF4为氟源，在N,N-二甲基甲酰胺(DMF)辅助下，合成了不同形貌的ZnOHF微/纳米结构(纳米棒、微米管和纳米片)，其中DMF既是溶剂，也是配体调节产物结构。本论文探究了DMF和H2O的比例在合成不同形貌的ZnOHF微/纳米结构过程中的作用。在紫外灯辐照下，测定了不同形貌的ZnOHF对罗丹明B溶液的光催化活性，结果表明在12.5 mL DMF/12.5mL H2O溶剂中，得到的微米管状ZnOHF的光催化性质最好。
Abstract: Employing NH4BF4 as fluoride, different morphological ZnOHF micro/nanostructures (nanorods, microtubes and nanosheets) have been synthesized with the aid of N,N-dimethylformamide (DMF). DMF is used both as solvent and structures functional agent in tuning the crystal phase and morphologies of the products. The ratio of DMF/H2O plays important roles in the formation of different morphological products. Under the irradiation of Uv-light, the photocatalytic activities of different morphological ZnOHF micro/nanostructures are investigated by the degradation of Rhodamine B solution. Resultantly, the ZnOHF microtubes exhibited the best photocatalytic properties which were synthesized in the presence of 12.5 mL DMF/12.5mL H2O.
文章引用：刘科麟, 王丹琪, 熊天宇, 丁津津, 王淼. DMF辅助溶剂热法合成ZnOHF微/纳米结构[J]. 物理化学进展, 2023, 12(2): 21-26. https://doi.org/10.12677/JAPC.2023.122003

参考文献

[1] 田辉. 羟基氟化物MOHF (M = Zn, Cu)的合成、表征及高压研究[D]: [硕士学位论文]. 长春: 吉林大学, 2018.
[2] Wang, M., Shen, X.L., Jiang, G.Q. and Shi, Y.J. (2012) Synthesis, Characterization and Photocatalytic Properties of Hierarchical Fan-Shaped ZnOHF and ZnO Microcrystals. Materials Letters, 87, 54-57. [Google Scholar] [CrossRef] 
[3] Wang, M., Sun, T.M., Tang, Y.F. and Jiang, G.Q. (2015) Template-Free Synthesis and Photocatalytic Properties of Flower-Like ZnOHF Nanostructures. Materials Letters, 160, 150-153. [Google Scholar] [CrossRef] 
[4] Zhu, B., Liu, Y.A., Zhao, H., et al. (2021) ZnOHF/N-Doped Carbon Hybrids as a Novel Anode Material for Enhanced Lithium Storage. Journal of Alloys and Compounds, 889, Article ID: 161705. [Google Scholar] [CrossRef] 
[5] Yao, X.Y., Zhao, J.B., Jin, Z.D., et al. (2021) Flower-Like Hydroxyfluoride-Sensing Platform toward NO2 Detection. ACS Applied Materials & Interfaces, 13, 26278-26287. [Google Scholar] [CrossRef] [PubMed]
[6] Li, Y.W., He, D.X., Luo, Y.X., et al. (2021) Hyperbranched Hierarchical Nanoarchitectures of ZnOHF: Synthesis, Characterization, Growth Mechanism and Their Gas Sensing Property. Applied Physics A, 127, Article No. 291. [Google Scholar] [CrossRef] 
[7] Kyusung, K., Li, C.Y., Choi, P.G., et al. (2022) Facile Synthesis of Zinc Hydroxyfluoridenanobelt and Effect of Hexamethylenetetramine for Growth Direction. Journal of Asian Ceramic Societies, 10, 697-702. [Google Scholar] [CrossRef] 
[8] Wang, M., Jin, Z.C., Liu, M.J., et al. (2017) Nanoplate-Assembled Hierarchical Cake-Like ZnO Microstructures: Solvothermal Synthesis, Characterization and Photocatalytic Properties. RSC Advances, 7, 32528-32535. [Google Scholar] [CrossRef] 
[9] Wang, M., Sun, T.M., Shi, Y.J., et al. (2014) 3D Hierarchical ZnOHF Nanostructures: Synthesis, Characterization and Photocatalytic Properties. CrystEngComm, 16, 10624-10630. [Google Scholar] [CrossRef] 
[10] Guo, Y.Y., Mo, Y.X., Wang, M., et al. (2021) Green and Facile Synthesis of Hierarchical ZnOHF Microspheres for Rapid and Selective Adsorption of Cationic Dyes. Journal of Molecular Liquids, 329, Article ID: 115529. [Google Scholar] [CrossRef]