PEDOT:PSS在电致变色器件中的应用研究进展
Research Progress of PEDOT:PSS Application in Electrochromic Devices
摘要: 电致变色是一种在氧化还原过程中发生可逆颜色变化的电化学现象。在施加正负电压时，电致变色器件(ECDs)表现电化学活性物质的可逆的颜色转换。目前，ECD被广泛用作智能窗、防眩目后视镜、传感器和可穿戴设备。聚(3,4-乙撑二氧噻吩)：聚苯乙烯磺酸盐(PEDOT:PSS)是一种应用广泛的导电聚合物，可应用于电致变色、光伏设备的透明导电电极。除此之外，PEDOT:PSS还具有电致变色性能，可作为电致变色器件的电致变色材料。本文综述了PEDOT:PSS在电致变色器件中的应用研究的最新进展，并介绍了PEDOT:PSS在ECD中的应用及这些ECD性能提高的方法和机理。
Abstract: Electrochromism is an electrochemical phenomenon in which reversible color changes occur during redox processes. When positive and negative voltages are applied, electrochromic devices (ECDs) exhibit reversible color transitions of electrochemically active substances. Currently, ECDs are widely used as smart windows, anti-glare mirrors, sensors, and wearable devices. Poly(3,4- ethylenedioxythio phene):Polystyrene sulfonate (PEDOT:PSS) is a widely used conductive polymer for transparent conductive electrodes in electrochromic and photovoltaic equipment. In addition, PEDOT:PSS also has electrochromic properties, which can be used as an electrochromic material for electrochromic devices. This article reviews the latest progress in the application of PEDOT:PSS in electrochromic devices, and introduces the application of PEDOT:PSS in ECDs and the methods and mechanisms for improving the performance of these ECDs.
文章引用：谢源源, 许文博, 鲁志威. PEDOT:PSS在电致变色器件中的应用研究进展[J]. 物理化学进展, 2023, 12(2): 43-51. https://doi.org/10.12677/JAPC.2023.122006

参考文献

[1] Monk, P., Mortimer, R. and Rosseinsky, D. (2007) Electrochromism and Electrochromic Devices. Cambridge University Press, New York, 1-7. [Google Scholar] [CrossRef] 
[2] Gu, H.X., Guo, C.S., Zhang, S.H., et al. (2018) Highly Efficient, Near-Infrared and Visible-Light Modulated Electrochromic Devices Based on Polyoxometalates and W18O49 Nanowires. ACS Nano, 12, 559-567. [Google Scholar] [CrossRef] [PubMed]
[3] Fang, H.J., Zheng, P.Y., Ma, R., et al. (2018) Multifunctional Hydrogel Enables Extremely Simplified Electrochromic Devices for Smart Windows and Ionic Writing Boards. Materials Horizons, 5, 1000-1007. [Google Scholar] [CrossRef] 
[4] Jia, H.X., Cao, X. and Jin, P.S. (2020) Advances in Inorganic All-Solid-State Electrochromic Materials and Devices. Journal of Inorganic Materials, 35, 511-524. [Google Scholar] [CrossRef] 
[5] Wang, J.L., Lu, Y.R., Li, H.H., et al. (2017) Large Area Co-Assembly of Nanowires for Flexible Transparent Smart Windows. Journal of the American Chemical Society, 139, 9921-9926. [Google Scholar] [CrossRef] [PubMed]
[6] Chen, X.D., Rogers, J.A., Lacour Stéphanie, P., et al. (2019) Materials Chemistry in Flexible Electronics. Chemical Society Reviews, 48, 1431-1433. [Google Scholar] [CrossRef] 
[7] Wei, W., Man, W., Ma, J.M., et al. (2018) Electrochromic Metal Oxides: Recent Progress and Prospect. Advanced Electronic Materials, 4, Article ID: 1800185. [Google Scholar] [CrossRef] 
[8] Mortimer, R. and Roger, J. (2011) Electrochromic Materials. Annual Review of Materials Research, 41, 241-268. [Google Scholar] [CrossRef] 
[9] 庄碧莹, 汪浩, 张倩倩, 等. 电致变色材料的研究与应用进展[J]. 北京工业大学学报, 2020, 46(10): 1091-1102.
[10] Tang, X., Chen, G., Li, Z., et al. (2020) Structure Evolution of Electrochromic Devices from “Face-to-Face” to “Shoulder-by-Shoulder”. Journal of Materials Chemistry C, 8, 11042-11051. [Google Scholar] [CrossRef] 
[11] Peng, R., Wan, Z., Song, W., et al. (2019) Improving Performance of Non-Fullerene Organic Solar Cells over 13% by Employing Silver Nanowires Doped PEDOT:PSS Composite Interface. ACS Applied Materials & Interfaces, 11, 42447-42454. [Google Scholar] [CrossRef] [PubMed]
[12] Verma, A., Singh, D.P., Bakhshi, A.K., et al. (2003) Influence of Aging and Composition of the Precursor Sol on the Properties of CeO2-TiO2 Thin Films for Electrochromic Applications. Journal of Non-Crystalline Solids, 351, 2501-2512. [Google Scholar] [CrossRef] 
[13] Rekha, S., Joseph, T., Sengottaiyan, M., et al. (2017) ITO-Free Solution-Processed Flexible Electrochromic Devices Based on PEDOT:PSS as Transparent Conducting Electrode. ACS Applied Materials & Interfaces, 9, 19427-19435. [Google Scholar] [CrossRef] [PubMed]
[14] 邸永跃, 施肖锋, 高维濂, 贾梦伟, 张婕. 基于银纳米线透明电极制备柔性电致变色器件[J]. 液晶与显示, 2022, 37(6): 694-702.
[15] 崔颖, 马俊. PEDOT:PSS薄膜导电性能优化的研究进展[J]. 胶体与聚合物, 2022, 40(3): 149-152.
[16] Deepa, M., Srivastava, A.K., Sood, K.N., et al. (2008) Nanostructured Tungsten Oxide-Poly(3,4-Ethylenedioxythiophene, Poly(styrenesulfonate) Hybrid Films: Synthesis, Electrochromic Response, and Durability Characteristics. Journal of the Electrochemical Society, 155, D703-D710. [Google Scholar] [CrossRef] 
[17] Kalagi, S.S., Dalavi, D.S., Mali, S.S., et al. (2012) Study of Novel WO3-PEDOT:PSS Bilayered Thin Film for Electrochromic Applications. Nanoscience and Nanotechnology Letters, 4, 1145-1154. [Google Scholar] [CrossRef] 
[18] Boyadjiev, S.I., Manduca, B., Szucs, J., et al. (2016) WO3 Nanopaticles and PEDOT:PSS/WO3 Composite Thin Films Studied for Photocatalytic and Electrochromic Applications. Journal of Physics: Conference Series, 700, Article ID: 012019. [Google Scholar] [CrossRef] 
[19] Futsch, R., Mjejri, I., Rakotozafy, H., et al. (2020) PEDOT:PSS-V2O5 Hybrid for Color Adjustment in Electrochromic Systems. Frontiers in Materials, 7, 78. [Google Scholar] [CrossRef] 
[20] Mjejri, I. and Rougier, A. (2020) PEDOT:PSS/Fe2O3 as Hybrid Composite Film for Tuning Color in Electrochromism. Materials Today: Proceedings, 33, 2470-2473. [Google Scholar] [CrossRef] 
[21] Levasseur, D., Mjejri, I., Rolland, T., et al. (2019) Color Tuning by Oxide Addition in PEDOT:PSS-Based Electrochromic Devices. Polymers, 11, 179. [Google Scholar] [CrossRef] [PubMed]
[22] Lu, J., Song, H., Li, S., et al. (2015) A Poly(3,4-ethylenedioxythiophene, poly(styrene sulfonic acid)/Titanium Oxide Nanocomposite Film Synthesized by Sol-Gel Assisted Electropolymerization for Electrochromic Application. Thin Solid Films, 584, 353-358. [Google Scholar] [CrossRef] 
[23] Jiang, H.Y., Wu, W., Chang, Z.G., et al. (2021) In Situ Polymerization of PEDOT:PSS Films-Based on EMI-TFSI and the Analysis of Electrochromic Performance. e-Polymers, 21, 722-733. [Google Scholar] [CrossRef] 
[24] Fabretto, M., Hall, C., Vaithianathan, T., et al. (2008) The Mechanism of Conductivity Enhancement in Poly(3,4- ethylenedioxythiophene)-poly(styrenesulfonic) Acid Using Linear-Diol Additives: Its Effect on Electrochromic Performance. Thin Solid Films, 516, 7828-7835. [Google Scholar] [CrossRef] 
[25] Kuo, C.W., Chang, J.C., Chang, J.K., et al. (2021) Electrosynthesis of Electrochromic Polymer Membranes Based on 3,6-di(2-thienyl)carbazole and Thiophene Derivatives. Membranes, 11, 125. [Google Scholar] [CrossRef] [PubMed]
[26] Lv, X.J., Bi, Q., Tameev, A., et al. (2020) A New Green-to-Transmissive Polymer with Electroactivepoly(3,4- ethylene-dioxythiophene, poly(styrene sulfonate)as an Interface Layer for Achieving High-Performance Electrochromic Device. Journal of Polymer Science, 58, 937-947. [Google Scholar] [CrossRef] 
[27] Li, X. and Li, C. (2014) Synthesis and Electrochromic Properties of Fluorescent PEDOT/PSS Composite. Applied Mechanics and Materials, 665, 300-306. [Google Scholar] [CrossRef] 
[28] Zhao, Q., Wang, J.K., Ai, X.H., et al. (2022) Three-Dimensional Knotting of W17O47@PEDOT:PSS Nanowires Enables High-Performance Flexible Cathode for Dual-Functional Electrochromic and Electrochemical Device. InfoMat, 4, e12298. [Google Scholar] [CrossRef] 
[29] Nah, Y.C., Choi, W.S., Kim, D.Y., et al. (2008) Preparation and Electrochromic Properties of Spin Self-Assembled Polyelectrolyte Multilayer Films Composed of PEDOT:PSS and PAH. Solar Energy Materials & Solar Cell, 92, 1547-1551. [Google Scholar] [CrossRef] 
[30] Pacios, R., Marcilla, R., Pozo-Gonzalo, C., et al. (2007) Combined Electrochromic and Plasmonic Optical Responses in Conducting Polymer/Metal Nanoparticle Films. Journal of Nanoscience and Nanotechnology, 7, 2938-2941. [Google Scholar] [CrossRef] [PubMed]
[31] Ma, C.A., Liu, H.L., Teng, C., et al. (2020) Wetting-Induced Fabrication of Graphene Hybrid with Conducting Polymers for High-Performance Flexible Transparent Electrodes. ACS Applied Materials & Interfaces, 12, 55372-55381. [Google Scholar] [CrossRef] [PubMed]
[32] Shinde, M.A. and Kim, H. (2019) Flexible Electrochromic Device with Simple Solution Processed Stable Silver Nanowire Based Transparent Conductive Electrodes. Synthetic Metals, 254, 97-105. [Google Scholar] [CrossRef] 
[33] Kim, K.W., Lee, S.B., Kim, S.H., et al. (2018) Spray-Coated Transparent Hybrid Electrodes for High Performance Electrochromic Devices on Plastic. Organic Electronics, 62, 151-156. [Google Scholar] [CrossRef] 
[34] Ginting, R.T., Ovhal, M.M., Kang, J.W., et al. (2018) A Novel Design of Hybrid Transparent Electrodes for High Performance and Ultra-Flexible Bifunctional Electrochromic-Supercapacitors. Nano Energy, 53, 650-657. [Google Scholar] [CrossRef] 
[35] De Keersmaecker, M., Lang, A.W., Osterholm, A.M., et al. (2018) All Polymer Solution Processed Electrochromic devices: A Future without Indium Tin Oxide? ACS Applied Materials & Interfaces, 10, 31568-31579. [Google Scholar] [CrossRef] [PubMed]
[36] Choi, D., Lee, M., Kim, H., et al. (2017) Fabrication of Transparent Conductive Tri-Composite Film for Electrochromic Application. Applied Surface Science, 425, 1006-1013. [Google Scholar] [CrossRef] 
[37] Sinha, S., Daniels, R., Yassin, O., et al. (2022) Electrochromic Fabric Displays from a Robust, Open-Air Fabrication Technique. Advanced Materials Technologies, 7, Article ID: 2100548. [Google Scholar] [CrossRef] 
[38] Lang, A.W., Li, Y.Y., De Keersmaecker, M., et al. (2018) Transparent Wood Smart Windows: Polymer Electrochromic Devices Based on Poly(3,4-ethylenedioxythiophene, poly(styrene sulfonate) Electrodes. ChemSusChem, 11, 854-863. [Google Scholar] [CrossRef] [PubMed]
[39] Malti, A., Brooke, R., Liu, X.J., et al. (2016) Freestanding Electrochromic Paper. Journal of Materials Chemistry C, 4, 9680-9686. [Google Scholar] [CrossRef]