氮掺杂石墨烯负载铁镍双金属磷化物及其电催化水分解性能研究
Research of Iron-Nickel Bimetal Phosphide Embedded on Nitrogen Doped Grapheme for Electrocatalytic Water Splitting
DOI: 10.12677/JAPC.2023.122010, PDF,   
作者: 宁志超, 赵佳硕, 石 晶, 李 波：河南工业大学化学化工学院，河南 郑州
关键词: 氮掺杂石墨烯；电催化；磷化物；Nitrogen-Doped Graphene； Electrocatalysis； Phosphide
摘要: 析氢反应和析氧反应是电化学水分解和金属–空气电池等可再生能源技术的基础反应。各种过渡金属(Co、Fe、Ni等)基催化剂由于具有良好的电催化活性而被大量探索，以作为贵金属潜在的替代品。本研究成功制备出负载于NGO上的双功能电催化剂((FexNi1-x)2P/NGO)。在1 M KOH中，达到10 mA/cm2的电流密度，OER过电位需228 mV，HER过电位需160 mV。(FexNi1-x)2P/NGO作为电解池的阴极和阳极时，1.66 V的电压就能达到10 mA/cm2的电流密度，并表现出优异的稳定性。该研究简化了镍铁磷化物的合成过程，并且片状NGO减少了纳米粒子的团聚，提供了大量的活性位点。
Abstract: Hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) are the basis of renewable energy technologies such as electrochemical water splitting and metal-air batteries. The electrocatalysts composed of various transition metals (Co, Fe, Ni, etc.) have been explored extensively as potential substitutes for precious metals due to their good electrocatalytic activity. In this article, bi-functional electrocatalyst ((FexNi1-x)2P/NGO) supported by Fe2P and Ni2P was successfully prepared in a tube furnace by annealing at high temperature. In 1 M KOH, the catalyst as prepared under the optimal conditions reached the current density of 10 mA/cm2. The OER overpotential required 228 mV and HER overpotential required 160 mV. When (FexNi1-x)2P/NGO is used as the cathode and anode of the electrolytic cell, the current density of 10 mA/cm2 can be reached at a voltage of 1.66 V, and shows excellent stability. This work simplifies the synthesis of nickel-iron phosphide, and the flake NGO reduces the agglomeration of nanoparticles, providing a large number of active sites.
文章引用：宁志超, 赵佳硕, 石晶, 李波. 氮掺杂石墨烯负载铁镍双金属磷化物及其电催化水分解性能研究[J]. 物理化学进展, 2023, 12(2): 76-85. https://doi.org/10.12677/JAPC.2023.122010

参考文献

[1] Zhang, Q., Han, W., Xu, Z., Li, Y., Chen, L., Bai, Z., Yang, L. and Wang, X. (2020) Hollow Waxberry-Like Cobalt-Nickel Oxide/S,N-Codoped Carbon Nanospheres as a Trifunctional Electrocatalyst for OER, ORR, and HER. RSC Advances, 10, 27788-27793. [Google Scholar] [CrossRef] 
[2] Wang, J., Fan, Y., Qi, S., Li, W. and Zhao, M. (2020) Bifunctional HER/OER or OER/ORR Catalytic Activity of Two-Dimensional TM3(HITP)2 with TM = Fe-Zn. The Journal of Physical Chemistry C, 124, 9350-9359. [Google Scholar] [CrossRef] 
[3] Banerjee, S., Debata, S., Madhuri, R. and Sharma, P.K. (2018) Electrocatalytic Behavior of Transition Metal (Ni, Fe, Cr) Doped Metal Oxide Nanocomposites for Oxygen Evolution Reaction. Applied Surface Science, 449, 660-668. [Google Scholar] [CrossRef] 
[4] Wang, H., Zhang, K.H.L., Hofmann, J.P., de la Peña O’Shea, V.A. and Oropeza, F.E. (2021) The Electronic Structure of Transition Metal Oxides for Oxygen Evolution Reaction. Journal of Materials Chemistry A, 9, 19465-19488. [Google Scholar] [CrossRef] 
[5] Yamada, I., Takamatsu, A., Asai, K., Ohzuku, H., Shirakawa, T., Uchimura, T., Kawaguchi, S., Tsukasaki, H., Mori, S., Wada, K., Ikeno, H. and Yagi, S. (2018) Synergistically Enhanced Oxygen Evolution Reaction Catalysis for Multielement Transition-Metal Oxides. ACS Applied Energy Materials, 1, 3711-3721. [Google Scholar] [CrossRef] 
[6] Ke, W., Zhang, Y., Imbault, A.L. and Li, Y. (2021) Metal-Organic Framework Derived Iron-Nickel Sulfide Nanorods for Oxygen Evolution Reaction. International Journal of Hydrogen Energy, 46, 20941-20949. [Google Scholar] [CrossRef] 
[7] Thangasamy, P., Oh, S., Nam, S., Randriamahazaka, H. and Oh, I.K. (2020) Ferrocene-Incorporated Cobalt Sulfide Nanoarchitecture for Superior Oxygen Evolution Reaction. Small, 16, e2001665. [Google Scholar] [CrossRef] [PubMed]
[8] Wang, H., Yang, J., Yang, L., Zhang, G., Liu, C., Tang, H., Zhao, Q. and Pan, F. (2018) FeCoNi Sulphide-Derived Nanodots as Electrocatalysts for Efficient Oxygen Evolution Reaction. Functional Materials Letters, 11, Article ID: 1850058. [Google Scholar] [CrossRef] 
[9] Li, Z., Dou, X., Zhao, Y. and Wu, C. (2016) Enhanced Oxygen Evolution Reaction of Metallic Nickel Phosphide Nanosheets by Surface Modification. Inorganic Chemistry Frontiers, 3, 1021-1027. [Google Scholar] [CrossRef] 
[10] Song, C., Liu, Y., Wang, Y., Tang, S., Li, W., Li, Q., Zeng, J., Chen, L., Peng, H. and Lei, Y. (2021) Highly Efficient Oxygen Evolution and Stable Water Splitting by Coupling NiFe LDH with Metal Phosphides. Science China Materials, 64, 1662-1670. [Google Scholar] [CrossRef] 
[11] Zhou, L.N., Yu, L., Liu, C. and Li, Y.J. (2020) Electrocatalytic Activity Sites for the Oxygen Evolution Reaction on Binary Cobalt and Nickel Phosphides. RSC Advances, 10, 39909-39915. [Google Scholar] [CrossRef] 
[12] Asen, P. and Esfandiar, A. (2021) Facile Synthesis of Highly Efficient Bifunctional Electrocatalyst by Vanadium Oxysulfide Spheres on Cobalt-Cobalt Sulfonitride Nanosheets for Oxygen and Hydrogen Evolution Reaction. Electrochimica Acta, 391, Article ID: 138948. [Google Scholar] [CrossRef] 
[13] Zhang, T., Zhang, B., Peng, Q., Zhou, J. and Sun, Z. (2021) Mo2B2 MBene-Supported Single-Atom Catalysts as Bifunctional HER/OER and OER/ORR Electrocatalysts. Journal of Materials Chemistry A, 9, 433-441. [Google Scholar] [CrossRef] 
[14] Zhao, R., Ni, B., Wu, L., Sun, P. and Chen, T. (2022) Carbon-Based Iron-Cobalt Phosphate FeCoP/C as an Effective ORR/OER/HER Trifunctional Electrocatalyst. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 635, Article ID: 128118. [Google Scholar] [CrossRef] 
[15] Liang, H.W., Wei, W., Wu, Z.S., Feng, X. and Mullen, K. (2013) Mesoporous Metal-Nitrogen-Doped Carbon Electrocatalysts for Highly Efficient Oxygen Reduction Reaction. Journal of the American Chemical Society, 135, 16002-16005. [Google Scholar] [CrossRef] [PubMed]
[16] Liu, W., Hou, Y., Lin, Z., Yang, S., Yu, C., Lei, C., Wu, X., He, D., Jia, Q., Zheng, G., Zhang, X. and Lei, L. (2018) Porous Cobalt Oxynitride Nanosheets for Efficient Electrocatalytic Water Oxidation. ChemSusChem, 11, 1479-1485. [Google Scholar] [CrossRef] [PubMed]
[17] Wahab, M.A., Joseph, J., Atanda, L., Sultana, U.K., Beltramini, J.N., Ostrikov, K., Will, G., O’Mullane, A.P. and Abdala, A. (2020) Nanoconfined Synthesis of Nitrogen-Rich Metal-Free Mesoporous Carbon Nitride Electrocatalyst for the Oxygen Evolution Reaction. ACS Applied Energy Materials, 3, 1439-1447. [Google Scholar] [CrossRef] 
[18] 刘影. 新型杂合纳米结构的可控合成及其电催化性能研究[D]: [博士学位论文]. 南京: 南京师范大学, 2020.
[19] Huo, J., Chen, Y., Liu, Y., Guo, J., Lu, L., Li, W., Wang, Y. and Liu, H. (2019) Bifunctional Iron Nickel Phosphide Nanocatalysts Supported on Porous Carbon for Highly Efficient Overall Water Splitting. Sustainable Materials and Technologies, 22, e00117. [Google Scholar] [CrossRef] 
[20] Zhang, X., Li, J., Sun, Y., Li, Z., Liu, P., Liu, Q., Tang, L. and Guo, J. (2018) N-Doped Reduced Graphene Oxide Supported Mixed Ni2P CoP Realize Efficient Overall Water Electrolysis. Electrochimica Acta, 282, 626-633. [Google Scholar] [CrossRef] 
[21] Chen, L., Wu, P., Yang, S., Qian, K., Sun, W., Wei, W., Xu, Y. and Xie, J. (2019) Fabrication of CNTs Encapsulated Nickel-Nickel Phosphide Nanoparticles on Graphene for Remarkable Hydrogen Evolution Reaction Performance. Journal of Electroanalytical Chemistry, 846, Article ID: 113142. [Google Scholar] [CrossRef] 
[22] Qian, M., Cui, S., Jiang, D., Zhang, L. and Du, P. (2017) Highly Efficient and Stable Water-Oxidation Electrocatalysis with a Very Low Overpotential Using FeNiP Substitutional-Solid-Solution Nanoplate Arrays. Advanced Materials, 29, Article ID: 1704075. [Google Scholar] [CrossRef] [PubMed]
[23] He, P., Yu, X.Y. and Lou, X.W. (2017) Carbon-Incorporated Nickel-Cobalt Mixed Metal Phosphide Nanoboxes with Enhanced Electrocatalytic Activity for Oxygen Evolution. Angewandte Chemie International Edition in English, 56, 3897-3900. [Google Scholar] [CrossRef] [PubMed]
[24] Man, H.W., Tsang, C.S., Li, M.M., Mo, J., Huang, B., Lee, L.Y.S., Leung, Y.C., Wong, K.Y. and Tsang, S.C.E. (2018) Tailored Transition Metal-Doped Nickel Phosphide Nanoparticles for the Electrochemical Oxygen Evolution Reaction (OER). Chemical Communications (Cambridge), 54, 8630-8633. [Google Scholar] [CrossRef] 
[25] Liang, X., Zheng, B., Chen, L., Zhang, J., Zhuang, Z. and Chen, B. (2017) MOF-Derived Formation of Ni2P-CoP Bimetallic Phosphides with Strong Interfacial Effect toward Electrocatalytic Water Splitting. ACS Applied Materials & Interfaces, 9, 23222-23229. [Google Scholar] [CrossRef] [PubMed]
[26] Sheng, J.P., Wang, L.Q., Deng, L., Zhang, M., He, H.C., Zeng, K., Tang, F.Y. and Liu, Y.N. (2018) MOF-Templated Fabrication of Hollow Co4N@N-Doped Carbon Porous Nanocages with Superior Catalytic Activity. ACS Applied Materials & Interfaces, 10, 7191-7200. [Google Scholar] [CrossRef] [PubMed]
[27] Xia, C., Jiang, Q., Zhao, C., Hedhili, M.N. and Alshareef, H.N. (2016) Selenide-Based Electrocatalysts and Scaffolds for Water Oxidation Applications. Advanced Materials, 28, 77-85. [Google Scholar] [CrossRef] [PubMed]
[28] Stern, L.-A., Feng, L., Song, F. and Hu, X. (2015) Ni2P as a Janus Catalyst for Water Splitting: The Oxygen Evolution Activity of Ni2P Nanoparticles. Energy & Environmental Science, 8, 2347-2351. [Google Scholar] [CrossRef]