|
[1]
|
Yang, J. and Jin, R.C. (2019) New Advances in Atomically Precise Silver Nanoclusters. ACS Materials Letters, 1, 482-489. [Google Scholar] [CrossRef]
|
|
[2]
|
Jin, R.C. (2015) Atomically Precise Metal Nanoclusters: Stable Sizes and Optical Properties. Nanoscale, 7, 1549-1565. [Google Scholar] [CrossRef]
|
|
[3]
|
Zeng, C.J., Chen, Y.X., Kirschbaum, K., et al. (2015) Structural Pat-terns at All Scales in A Nonmetallic Chiral Au133(SR)52 Nanoparticle. Science Advances, 1, e1500045. [Google Scholar] [CrossRef] [PubMed]
|
|
[4]
|
Liu, C., Ren, X.Q., Lin, F., et al. (2019) Structure of the Au23−xAgx(S-Adm)15 Nanocluster and Its Application for Photocatalytic Degradation of Organic Pollutants. Angewandte Chemie International Edition, 58, 11335-11339. [Google Scholar] [CrossRef] [PubMed]
|
|
[5]
|
Shang, L., Xu, J. and Nienhaus, G.U. (2019) Recent Advances in Synthesizing Metal Nanocluster-Based Nanocomposites for Application in Sensing, Imaging and Catalysis. Nano Today, 28, Article ID: 100767. [Google Scholar] [CrossRef]
|
|
[6]
|
Yang, J.J., Wang, F.L., Yuan, H.Q., et al. (2019) Recent Ad-vances in Ultra-Small Fluorescent Au Nanoclusters toward Oncological Research. Nanoscale, 11, 17967-17980. [Google Scholar] [CrossRef]
|
|
[7]
|
Tian, F., Chen, J., Chen, F.X., et al. (2021) Boosting Hydrogen Evolu-tion over Ni6(SCH2Ph)12 Nanocluster Modified TiO2 via Pseudo-Z-Scheme Interfacial Charge Transfer. Applied Cataly-sis B: Environmental, 292, Article ID: 120158. [Google Scholar] [CrossRef]
|
|
[8]
|
Liu, C., Li, T., Abroshan, H., et al. (2018) Chiral Ag23 Nanocluster with Open Shell Electronic Structure and Helical Face-centered Cubic Framework. Nature Communications, 9, Article No. 744. [Google Scholar] [CrossRef] [PubMed]
|
|
[9]
|
Joshi, C.P., Bootharaju, M.S., Alhilaly, M.J., et al. (2015) [Ag25(SR)18]−: The “Golden” Silver Nanoparticle. Journal of the American Chemical Society, 137, 11578-11581. [Google Scholar] [CrossRef] [PubMed]
|
|
[10]
|
Abdulhalim, L.G., Bootharaju, M.S., Tang, Q., et al. (2015) Ag29(BDT)12(TPP)4: A Tetravalent Nanocluster. Journal of the American Chemical Society, 137, 11970-11975. [Google Scholar] [CrossRef] [PubMed]
|
|
[11]
|
Tian, F. and Chen, R. (2019) Pd-Mediated Synthesis of Ag33 Chiral Nanocluster with Core-Shell Structure in T Point Group. Journal of the American Chemical Society, 141, 7107-7114. [Google Scholar] [CrossRef] [PubMed]
|
|
[12]
|
Harkness, K.M., Tang, Y., Dass, A., et al. (2012) Ag44(SR)304−: A Sil-ver-Thiolate Superatom Complex. Nanoscale, 4, 4269-4274. [Google Scholar] [CrossRef] [PubMed]
|
|
[13]
|
Chakraborty, I., Kurashige, W., Kanehira, K., et al. (2013) Ag44(SeR)30: A Hollow Cage Silver Cluster with Selenolate Protection. Journal of Physical Chemistry Letters, 4, 3351-3355. [Google Scholar] [CrossRef] [PubMed]
|
|
[14]
|
Bootharaju, M.S., Lee, S., Deng, G., et al. (2021) Ag44(EBT)26(TPP)4 Nanoclusters with Tailored Molecular and Electronic Structure. An-gewandte Chemie International Edition, 60, 9038-9044. [Google Scholar] [CrossRef] [PubMed]
|
|
[15]
|
Kang, X., Li, Y.W., Zhu, M.Z., et al. (2020) Atomically Precise Alloy Nanoclusters: Syntheses, Structures, and Properties. Chemical Society Reviews, 49, 6443-6514. [Google Scholar] [CrossRef]
|
|
[16]
|
Yan, J.Z., Su, H.F., Yang, H.Y., et al. (2016) Asymmetric Synthesis of Chiral Bimetallic [Ag28Cu12(SR)24]4− Nanoclusters via Ion Pairing. Journal of the American Chemical Society, 138, 12751-12754. [Google Scholar] [CrossRef] [PubMed]
|
|
[17]
|
Anumula, R., Xiao, P., Cui, C., et al. (2020) A Small Bimetallic Ag3Cu2 Nanocluster with Dual Emissions within and Against Kasha’s Rule. Nanoscale, 12, 7864-7869. [Google Scholar] [CrossRef]
|
|
[18]
|
Xia, N., Xing, J.P., Peng, D., et al. (2022) Assembly-Induced Spin Transfer and Distance-Dependent Spin Coupling in Atomically Precise AgCu Nanoclusters. Nature Communications, 13, 5934-5943. [Google Scholar] [CrossRef] [PubMed]
|
|
[19]
|
Bao, Y.Z., Wu, X.H., Gao, H.J., et al. (2020) The Geometric and Electronic Structures of a Ag13Cu10(SAdm)12X3 Nanocluster. Dalton Transactions, 49, 17164-17168. [Google Scholar] [CrossRef]
|
|
[20]
|
Yang, H.Y., Lei, J., Wu, B.H., et al. (2013) Crystal Structure of A Lu-minescent Thiolated Ag Nanocluster with an Octahedral Ag64+ Core. Chemical Communications, 49, 300-302. [Google Scholar] [CrossRef]
|
|
[21]
|
Tian, F. and Chen, R. (2020) Ag18(μ8-S)(p-TBBT)16(PPh3)8: Symmetry Breaking Induced by the Core to Tenerate Chirality. Chemical Communications, 56, 2719-2722. [Google Scholar] [CrossRef]
|
|
[22]
|
Du, W.J., Jin, S., Xiong, L., et al. (2017) Ag50(Dppm)6(SR)30 and Its Homologue AuxAg50–x(Dppm)6(SR)30 Alloy Nanocluster: Seeded Growth, Structure Determination, and Differences in Properties. Journal of the American Chemical Society, 139, 1618-1624. [Google Scholar] [CrossRef] [PubMed]
|
|
[23]
|
Li, J.L., Li, H., Yu, H.Z., et al. (2020) A Novel Geometric Structure of a Nanocluster with an Irregular Kernel: Ag30Cu14(TPP)4(SR)28. Dalton Transactions, 49, 7684-7687. [Google Scholar] [CrossRef]
|
|
[24]
|
Ma, X.H., Si, Y.B., Luo, L.L., et al. (2022) Directional Doping and Cocrystallizing an Open-Shell Ag39 Superatom via Precursor Engineering. ACS Nano, 16, 5507-5514. [Google Scholar] [CrossRef] [PubMed]
|
|
[25]
|
Kang, X., Abroshan, H., Wang, S.X., et al. (2019) Free Valence Electron Centralization Strategy for Preparing Ultrastable Nanoclusters and Their Catalytic Application. Inorganic Chem-istry, 58, 11000-11009. [Google Scholar] [CrossRef] [PubMed]
|
|
[26]
|
Ren, L.T., Yuan, P., Su, H.F., et al. (2017) Bulky Surface Ligands Promote Surface Reactivities of [Ag141X12(S- Adm)40]3+ (X = Cl, Br, I) Nanoclusters: Models for Multi-ple-Twinned Nanoparticles. Journal of the American Chemical Society, 139, 13288-13291. [Google Scholar] [CrossRef] [PubMed]
|
|
[27]
|
Yang, S., Chai, J.S., Chong, H.B., et al. (2018) Sulfonate, Sulfide and Thiolate Ligands into an Ultrasmall Nanocluster: [Ag40.13Cu13.87S19(tBuS)20(tBuSO3)12]. Chemical Communications, 54, 4314-4316. [Google Scholar] [CrossRef]
|
|
[28]
|
Zou, X.J., Li, Y.F., Jin, S., et al. (2020) Doping Copper Atoms into the Nanocluster Kernel: Total Structure Determination of Cu30Ag61(SAdm)38S3(BPh4). Journal of Physical Chemistry Letters, 11, 2272-2276. [Google Scholar] [CrossRef] [PubMed]
|
|
[29]
|
Lin, Z.Z., Zhang, T., Fang, C., et al. (2023) A Bimetallic Ag15Cu12(S-c-C6H11)18(CH3COO)3 Nanocluster Featuring an Irregular Ag12 Kernel. Dalton Transactions, 52, 971-976. [Google Scholar] [CrossRef]
|
|
[30]
|
Chai, J., Yang, S., Chen, T., et al. (2021) Chiral Inversion and Conser-vation of Clusters: A Case Study of Racemic Ag32Cu12 Nanocluster. Inorganic Chemistry, 60, 9050-9056. [Google Scholar] [CrossRef] [PubMed]
|
|
[31]
|
Connell, T.U., Sandanayake, S., et al. (2013) Hal-ide-Ion-Templated Ag8Cu6 Rhombic Dodecahedrons: Synthesis, Structure and Reactivity of [Ag8Cu6(C≡CtBu)12X]BF4 (X = Cl, Br). Dalton Transactions, 42, 4903-4907. [Google Scholar] [CrossRef] [PubMed]
|
|
[32]
|
Ma, X.S., Xiong, L., Qin, L.B., et al. (2021) A Homoleptic Al-kynyl-Protected [Ag9Cu6(tBuC≡C)12]+ Superatom with Free Electrons: Synthesis, Structure Analysis, and Different Properties Compared with the Au7Ag8 Cluster in the M15+ Series. Chemical Science, 12, 12819-12826. [Google Scholar] [CrossRef]
|
|
[33]
|
Qin, L.B., Sun, F., Ma, X., et al. (2021) Homoleptic Alkynyl-Protected Ag15 Nanocluster with Atomic Precision: Structural Analysis and Electrocatalytic Performance toward CO2 Reduction. Angewandte Chemie International Edition, 60, 26136-26141. [Google Scholar] [CrossRef] [PubMed]
|
|
[34]
|
Deng, G.C., Lee, K., Deng, H.W., et al. (2022) Alkynyl-Protected Ag12Cu4 Cluster with Aggregation-Induced Emission En-hancement. The Journal of Physical Chemistry C, 126, 20577-20583. [Google Scholar] [CrossRef]
|
|
[35]
|
Deng, G.C., Kim, J.M., Bootharaju, M.S., et al. (2023) Body-Centered-Cubic-Kernelled Ag15Cu6 Nanocluster with Alkynyl Protection: Synthesis, Total Structure, and CO2 Electroreduction. Journal of the American Chemical Society, 145, 3401-3407. [Google Scholar] [CrossRef] [PubMed]
|
|
[36]
|
Sun, X.L., Tang, X.K., Gao, Y.L., et al. (2023) An Atomically Precise Ag18Cu8 Nanocluster with Rich Alkynyl-Metal Coordination Structures and Unique SbF6− Assembling Modes. Na-noscale, 15, 2316-2322. [Google Scholar] [CrossRef]
|
|
[37]
|
Gao, Y.L., Sun, X.L., Tang, X.K., et al. (2023) An Alkynyl-Protected Ag13−xCu6+x Nanocluster for Catalytic Hydrogenation. Dalton Transactions, 52, 52-57. [Google Scholar] [CrossRef]
|
|
[38]
|
Deng, G.C., Lee, K., Deng, H.W., et al. (2023) Alkynyl-Protected Chi-ral Bimetallic Ag22Cu7 Superatom with Multiple Chirality Origins. Angewandte Chemie International Edition, 62, e202217483. [Google Scholar] [CrossRef] [PubMed]
|
|
[39]
|
Kaiyu, M., Shen, H., Kazuyuki, K., et al. (2021) The [Ag25Cu4H8Br6(C≡CPh)12(PPh3)12]3+ : Ag13H8 Silver Hydride Core Protected by [CuAg3(C≡CPh)3(PPh3)3]+ Motifs. Dalton Transactions, 50, 5659-5665. [Google Scholar] [CrossRef]
|
|
[40]
|
Yuan, S.F., Guan, Z.J. and Wang, Q.M. (2022) Identification of the Active Species in Bimetallic Cluster Catalyzed Hydrogenation. Journal of the American Chemical Society, 144, 11405-11412. [Google Scholar] [CrossRef] [PubMed]
|
|
[41]
|
Yang, P., Xu, A.D., Xia, J., et al. (2014) Facile Synthesis of Highly Catalytic Activity Ni-Co-Pd-P Composite for Reduction of the P-Nitrophenol. Applied Catalysis A: General, 470, 89-96. [Google Scholar] [CrossRef]
|
|
[42]
|
Tang, A., Long, M. and He, Z. (2014) Electrodeposi-tion of Sb2Se3 on TiO2 Nanotube Arrays for Catalytic Reduction of P-Nitrophenol. Electrochimica Acta, 146, 346-352. [Google Scholar] [CrossRef]
|
|
[43]
|
Hasan, Z., Cho, D., Chon, C., et al. (2016) Reduction of P-Nitrophenol by Magnetic Co-Carbon Composites Derived From Metal Organic Frameworks. Chemical Engineering Journal, 298, 183-190. [Google Scholar] [CrossRef]
|
|
[44]
|
Chen, H., Yang, M., Tao, S., et al. (2017) Oxygen Vacancy En-hanced Catalytic Activity of Reduced Co3O4 towards P-Nitrophenol Reduction. Applied Catalysis B: Environmental, 209, 648-656. [Google Scholar] [CrossRef]
|
|
[45]
|
Dasog, M., Hou, W.B. and Scott, R.W.J. (2011) Controlled Growth and Catalytic Activity of Gold Monolayer Protected Clusters in Presence of Borohydride Salts. Chemical Com-munications, 47, 8569-8571. [Google Scholar] [CrossRef] [PubMed]
|
|
[46]
|
Shivhare, A., Ambrose, S.J., Zhang, H., et al. (2012) Stable and Recycla-ble Au25 Clusters for the Reduction of 4-Nitrophenol. Chemical Communications, 49, 276-278. [Google Scholar] [CrossRef]
|
|
[47]
|
Yamamoto, H., Yano, H., Kouchi, H., et al. (2012) N,N-Dimethylformamide-Stabilized Gold Nanoclusters as a Catalyst for the Reduction of 4-Nitrophenol. Nanoscale, 4, 4148-4154. [Google Scholar] [CrossRef] [PubMed]
|
|
[48]
|
Kauffman, D.R., Alfonso, D., Matranga, C., et al. (2014) Probing Active Site Chemistry with Differently Charged Au25q Nanoclusters (q = −1, 0, +1). Chemical Science, 5, 3151-3157. [Google Scholar] [CrossRef]
|
|
[49]
|
Zhao, S., Austin, N., Li, M., et al. (2018) Influence of Atom-ic-Level Morphology on Catalysis: The Case of Sphere and Rod-Like Gold Nanoclusters for CO2 Electroreduction. ACS Catalysis, 8, 4996-5001. [Google Scholar] [CrossRef]
|
|
[50]
|
Li, S.T., Alfonso, D., Nagarajan, A.V., et al. (2020) Monopalladium Substitution in Gold Nanoclusters Enhances CO2 Electroreduction Activity and Selectivity. ACS Catalysis, 10, 12011-12016. [Google Scholar] [CrossRef]
|
|
[51]
|
Li, S.T., Nagarajan, A.V., Li, Y.W., et al. (2021) The Role of Ligands in Atomically Precise Nanocluster-Catalyzed CO2 Electrochemical Reduction. Nanoscale, 13, 2333-2337. [Google Scholar] [CrossRef]
|
|
[52]
|
Lin, X.Z., Ma, W.G., Sun, K.J., et al. (2021) [AuAg26(SR)18S]− Nanocluster: Open Shell Structure and High Faradaic Efficiency in Electrochemical Reduction of CO2 to CO. The Jour-nal of Physical Chemistry Letters, 12, 552-557. [Google Scholar] [CrossRef] [PubMed]
|
|
[53]
|
Li, S.T., Nagarajan, A.V., Alfonso, D.R., et al. (2021) Boosting CO2 Electrochemical Reduction with Atomically Precise Surface Modification on Gold Nanoclusters. Angewandte Chemie International Edition, 60, 6351-6356. [Google Scholar] [CrossRef] [PubMed]
|
|
[54]
|
Zheng, Y., Vasileff, A., Zhou, X.L., et al. (2019) Understanding the Roadmap for Electrochemical Reduction of CO2 to Multi-Carbon Oxygenates and Hydrocarbons on Copper-Based Cata-lysts. Journal of the American Chemical Society, 141, 7646-7659. [Google Scholar] [CrossRef] [PubMed]
|
|
[55]
|
Ma, W.C., He, X.Y., Wang, W., et al. (2021) Electrocatalytic Reduction of CO2 and CO to Multi-Carbon Compounds Over Cu-Based Catalysts. Chemical Society Reviews, 50, 12897-12914. [Google Scholar] [CrossRef]
|
|
[56]
|
Xie, H., Wang, T.Y., Liang, J.S., et al. (2018) Cu-Based Nanocatalysts for Electrochemical Reduction of CO2. Nano Today, 21, 41-54. [Google Scholar] [CrossRef]
|
|
[57]
|
Nguyen, T.D., Jones, Z.R., Goldsmith, B.R., et al. (2015) A Cu25 Nanocluster with Partial Cu(0) Character. Journal of the American Chemical Society, 137, 13319-13324. [Google Scholar] [CrossRef] [PubMed]
|
|
[58]
|
Ma, X.S., Sun, F., Qin, L.B., et al. (2022) Electrochemical CO2 Reduc-tion Catalyzed by Atomically Precise Alkynyl-Protected Au7Ag8, Ag9Cu6, and Au2Ag8Cu5 Nanoclusters: Probing the Effect of Multi-Metal Core on Selectivity. Chemical Science, 13, 10149-10158. [Google Scholar] [CrossRef]
|
|
[59]
|
Zha, J., Meng, X.F., Fan, W.T., et al. (2023) Surface Site-Specific Re-placement for Catalysis Selectivity Switching. ACS Applied Materials & Interfaces, 15, 3985-3992. [Google Scholar] [CrossRef] [PubMed]
|