VOCs催化剂的研究进展
Research Progress of Catalysts for VOCs
DOI: 10.12677/AAC.2023.133033, PDF,    科研立项经费支持
作者: 张文静, 刘毓炜, 朱薇丽, 吴 明, 丁建东:南通大学化学化工学院,江苏 南通;刘敬印, 刘立忠*:南通大学化学化工学院,江苏 南通;南通大学–云汇科技环境科学联合研发中心,江苏 南通
关键词: VOCs催化氧化催化剂影响因素<VOCs Catalytic Oxidation Catalyst Influencing Factors
摘要: 挥发性有机物(VOCs)是影响我国大气环境质量的主要气态污染物,已经成为我国“十四五”期间空气污染物重点指标之一。催化氧化法是当前处理挥发性有机物的主流技术之一,其核心是催化剂。对此,本文主要针对目前已报道VOCs催化剂进行综述,介绍了各类催化剂对常见VOCs的催化研究现状,并对催化剂的催化性能、反应机理等方面进行了概括,分析了催化剂的制备方法、前体类型、水蒸气浓度等对催化活性的影响。
Abstract: Volatile organic compounds (VOCs) are the main gaseous pollutants that affect the quality of China’s atmospheric environment, and have become one of the key indicators of air pollutants during the “14th Five-Year Plan” period in my country. Catalytic oxidation is one of the mainstream technologies for dealing with volatile organic compounds, and its core is a catalyst. In this regard, this paper mainly reviews the VOCs catalysts that have been reported so far, introduces the current research status of various catalysts on common VOCs, and makes an overview of the catalytic performance and reaction mechanism of the catalysts, the effect of precursor type, water vapor concentration, etc. on the catalytic activity.
文章引用:张文静, 刘毓炜, 朱薇丽, 吴明, 丁建东, 刘敬印, 刘立忠. VOCs催化剂的研究进展[J]. 分析化学进展, 2023, 13(3): 289-303. https://doi.org/10.12677/AAC.2023.133033

参考文献

[1] Li, M., Zhang, Q., Zheng, B., et al. (2019) Persistent Growth of Anthropogenic Non-Methane Volatile Organic Compound (NMVOC) Emissions in China during 1990-2017: Drivers, Speciation and Ozone Formation Potential. Atmospheric Chemistry and Physics, 19, 8897-8913.
[Google Scholar] [CrossRef
[2] Wu, K., Yang, X., Chen, D., et al. (2020) Estimation of Biogenic VOC Emissions and Their Corresponding Impact on Ozone and Secondary Organic Aerosol Formation in China. Atmospheric Research, 231, Article ID: 104656.
[Google Scholar] [CrossRef
[3] Woellner, M., Hausdorf, S., Klein, N., et al. (2018) Adsorption and Detection of Hazardous Trace Gases by Metal- Organic Frameworks. Advanced Materials, 30, Article ID: 1704679.
[Google Scholar] [CrossRef] [PubMed]
[4] Zhao, X., Xu, D., Wang, Y., et al. (2021) Electric Field Assisted Benzene Oxidation over Pt-Ce-Zr Nano-Catalysts at Low Temperature. Journal of Hazardous Materials, 407, Article ID: 124349.
[Google Scholar] [CrossRef] [PubMed]
[5] Wen, M., Li, G., Liu, H., et al. (2019) Metal-Organic Framework-Based Nanomaterials for Adsorption and Photocatalytic Degradation of Gaseous Pollutants: Recent Progress and Challenges. Environmental Science: Nano, 6, 1006-1025.
[Google Scholar] [CrossRef
[6] Li, Z., Yang, D.P., Chen, Y., et al. (2020) Waste Eggshells to Valuable Co3O4/CaCO3 Materials as Efficient Catalysts for VOCs Oxidation. Molecular Catalysis, 483, Article ID: 110766.
[Google Scholar] [CrossRef
[7] Zhang, K., Ding, H., Pan, W., et al. (2022) Research Progress of a Composite Metal Oxide Catalyst for VOC Degradation. Environmental Science & Technology, 56, 9220-9236.
[Google Scholar] [CrossRef] [PubMed]
[8] Li, Y., Chang, H., Yan, H., Tian, S.L. and Jessop, P.G. (2020) Reversible Absorption of Volatile Organic Compounds by Switchable-Hydrophilicity Solvents: A Case Study of Toluene with N, N-Dimethylcyclohexylamine. Acs Omega, 6, 253-264.
[Google Scholar] [CrossRef] [PubMed]
[9] Li, J., Liao, H., Sun, Y., et al. (2021) Fabrication of MWCNTs/PDMS Mixed Matrix Membranes for Recovery of Volatile Aromatic Compounds from Brewed Black Tea. Separation and Purification Technology, 259, Article ID: 118101.
[Google Scholar] [CrossRef
[10] Yu, L., Wang, L., Xu, W., et al. (2018) Adsorption of VOCs on Reduced Graphene Oxide. Journal of Environmental Sciences, 67, 171-178.
[Google Scholar] [CrossRef] [PubMed]
[11] Tan, L., Wang, J., Cai, B., et al. (2022) Nitrogen-Rich Layered Carbon for Adsorption of Typical Volatile Organic Compounds and Low-Temperature Thermal Regeneration. Journal of Hazardous Materials, 424, Article ID: 127348.
[Google Scholar] [CrossRef] [PubMed]
[12] Yang, C., Miao, G., Pi, Y., et al. (2019) Abatement of Various Types of VOCs by Adsorption/Catalytic Oxidation: A Review. Chemical Engineering Journal, 370, 1128-1153.
[Google Scholar] [CrossRef
[13] Zabihi, M., Khorasheh, F. and Shayegan, J. (2015) Studies on the Catalyst Preparation Methods and Kinetic Behavior of Supported Cobalt Catalysts for the Complete Oxidation of Cyclohexane. Reaction Kinetics, Mechanisms and Catalysis, 114, 611-628.
[Google Scholar] [CrossRef
[14] Aranzabal, A., Ayastuy-Arizti, J.L., González-Marcos, J.A. and González-Velasco, J.R. (2003) The Reaction Pathway and Kinetic Mechanism of the Catalytic Oxidation of Gaseous Lean TCE on Pd/Alumina Catalysts. Journal of Catalysis, 214, 130-135.
[Google Scholar] [CrossRef
[15] Banu, I., Manta, C.M., Bercaru, G. and Bozga, G. (2015) Combustion Kinetics of Cyclooctane and Its Binary Mixture with o-Xylene over a Pt/γ-Alumina Catalyst. Chemical Engineering Research and Design, 102, 399-406.
[Google Scholar] [CrossRef
[16] Tang, Z., Zhang, T., Luo, D., et al. (2022) Catalytic Combustion of Methane: From Mechanism and Materials Properties to Catalytic Performance. ACS Catalysis, 12, 13457-13474.
[Google Scholar] [CrossRef
[17] Dou, B.J., Li, S.M., Liu, D.L., et al. (2016) Catalytic Oxidation of Ethyl Acetate and Toluene over Cu-Ce-Zr Supported ZSM-5/TiO2 Catalysts. RSC Advances, 6, 53852-53859.
[Google Scholar] [CrossRef
[18] Kaichev, V.V., Teschner, D., Saraev, A.A., et al. (2016) Evolution of Self-Sustained Kinetic Oscillations in the Catalytic Oxidation of Propane over a Nickel Foil. Journal of Catalysis, 334, 23-33.
[Google Scholar] [CrossRef
[19] Kaichev, V.V., Gladky, A.Y., Prosvirin, I.P., et al. (2013) In Situ XPS Study of Self-Sustained Oscillations in Catalytic Oxidation of Propane over Nickel. Surface Science, 609, 113-118.
[Google Scholar] [CrossRef
[20] Li, C., Zhao, Y., Song, H. and Li, H. (2020) A Review on Recent Advances in Catalytic Combustion of Chlorinated Volatile Organic Compounds. Journal of Chemical Technology & Biotechnology, 95, 2069-2082.
[Google Scholar] [CrossRef
[21] Liu, X., Chen, L., Zhu, T. and Ning, R.L. (2019) Catalytic Oxidation of Chlorobenzene over Noble Metals (Pd, Pt, Ru, Rh) and the Distributions of Polychlorinated by-Products. Journal of Hazardous Materials, 363, 90-98.
[Google Scholar] [CrossRef] [PubMed]
[22] Oh, S.H., Mitchell, P.J. and Siewert, R.M. (1991) Methane Oxidation over Alumina-Supported Noble Metal Catalysts with and without Cerium Additives. Journal of Catalysis, 132, 287-301.
[Google Scholar] [CrossRef
[23] Lyubovsky, M., Smith, L.L., Castaldi, M., et al. (2003) Catalytic Combustion over Platinum Group Catalysts: Fuel-Lean versus Fuel-Rich Operation. Catalysis Today, 83, 71-84.
[Google Scholar] [CrossRef
[24] Giebeler, L., Kießling, D. and Wendt, G. (2007) LaMnO3 Perovskite Supported Noble Metal Catalysts for the Total Oxidation of Methane. Chemical Engineering & Technology, 30, 889-894.
[Google Scholar] [CrossRef
[25] Palacio, L.A., Silva, J.M., Ribeiro, F.R. and Ribeiro, M.F. (2008) Catalytic Oxidation of Volatile Organic Compounds with a New Precursor Type Copper Vanadate. Catalysis Today, 133-135, 502-508.
[Google Scholar] [CrossRef
[26] Lee, C., Shul, Y.G. and Einaga, H. (2017) Silver and Manganese Oxide Catalysts Supported on Mesoporous ZrO2 Nanofiber Mats for Catalytic Removal of Benzene and Diesel Soot. Catalysis Today, 281, 460-466.
[Google Scholar] [CrossRef
[27] Zhang, L., Jiang, Y., Chen, B.B., et al. (2020) Exceptional Activity for Formaldehyde Combustion Using Siliceous β Zeolite as a Catalyst Support. Catalysis Today, 339, 174-180.
[Google Scholar] [CrossRef
[28] Liu, B., Ji, J., Zhang, B., et al. (2022) Catalytic Ozonation of VOCs at Low Temperature: A Comprehensive Review. Journal of Hazardous Materials, 422, Article ID: 126847.
[Google Scholar] [CrossRef] [PubMed]
[29] Cabrol, A., Lejeune, A., Lebullenger, R., et al. (2021) Simulation and Optimization of the Removal of Toluene in Air by Ozonation with a Catalytic Open-Cell Foam. Chemical Engineering Research and Design, 168, 453-464.
[Google Scholar] [CrossRef
[30] Liu, C., Xian, H., Jiang, Z., et al. (2015) Insight into the Improvement Effect of the Ce Doping into the SnO2 Catalyst for the Catalytic Combustion of Methane. Applied Catalysis B: Environmental, 176-177, 542-552.
[Google Scholar] [CrossRef
[31] Yang, P., Yang, S., Shi, Z., Meng, Z.H. and Zhou, R.X. (2015) Deep Oxidation of Chlorinated VOCs over CeO2-Based Transition Metal Mixed Oxide Catalysts. Applied Catalysis B: Environmental, 162, 227-235.
[Google Scholar] [CrossRef
[32] Xie, H., Tan, X., Zhang, G., et al. (2020) Porous Co-Based Spinel Oxide Prepared by Soft-Template Method for Ethanol Oxidation. Journal of Physics and Chemistry of Solids, 146, Article ID: 109562.
[Google Scholar] [CrossRef
[33] Zhang, X., Li, H., Lv, X., et al. (2018) Facile Synthesis of Highly Efficient Amorphous Mn-MIL-100 Catalysts: Formation Mechanism and Structure Changes during Application in CO Oxidation. Chemistry—A European Journal, 24, 8822-8832.
[Google Scholar] [CrossRef] [PubMed]
[34] Zhang X, Lv X, Shi X, Yang Yang, Yiqiong Yang, (2019) Enhanced Hydrophobic UiO-66 (University of Oslo 66) Metal-Organic Framework with High Capacity and Selectivity for Toluene Capture from High Humid Air. Journal of Colloid and Interface Science, 539, 152-160.
[Google Scholar] [CrossRef] [PubMed]
[35] Wang, P., Wang, J., Shi, J., et al. (2020) Low Content of Samarium Doped CeO2 Oxide Catalysts Derived from Metal Organic Framework Precursor for Toluene Oxidation. Molecular Catalysis, 492, Article ID: 111027.
[Google Scholar] [CrossRef
[36] Wang, Y., Jia, A.P., Luo, M.F. and Lu, J.Q. (2015) Highly Active Spinel Type CoCr2O4 Catalysts for Dichloromethane Oxidation. Applied Catalysis B: Environmental, 165, 477-486.
[Google Scholar] [CrossRef
[37] Liu, J.D., Zhang, T.T., Jia, A.P., Luo, M.F. and Lu, J.Q. (2016) The Effect of Microstructural Properties of CoCr2O4 Spinel Oxides on Catalytic Combustion of Dichloromethane. Applied Surface Science, 369, 58-66.
[Google Scholar] [CrossRef
[38] Zhang, Y., Zeng, Z., Li, Y., et al. (2021) Effect of the A-Site Cation over Spinel AMn2O4 (A = Cu2+, Ni2+, Zn2+) for Toluene Combustion: Enhancement of the Synergy and the Oxygen Activation Ability. Fuel, 288, Article ID: 119700.
[Google Scholar] [CrossRef
[39] Cai, T., Huang, H., Deng, W., et al. (2015) Catalytic Combustion of 1, 2-Dichlorobenzene at Low Temperature over Mn-Modified Co3O4 Catalysts. Applied Catalysis B: Environmental, 166-167, 393-405.
[Google Scholar] [CrossRef
[40] González-Prior, J., López-Fonseca, R., Gutiérrez-Ortiz, J.I. and de Rivas, B. (2016) Oxidation of 1, 2-Dichloroethane over Nanocube-Shaped Co3O4 Catalysts. Applied Catalysis B: Environmental, 199, 384-393.
[Google Scholar] [CrossRef
[41] Ren, Q., Mo, S., Peng, R., et al. (2018) Controllable Synthesis of 3D Hierarchical Co3O4 Nanocatalysts with Various Morphologies for the Catalytic Oxidation of Toluene. Journal of Materials Chemistry A, 6, 498-509.
[Google Scholar] [CrossRef
[42] Rokicińska, A., Natkański, P., Dudek, B., et al. (2016) Co3O4-Pillared Montmorillonite Catalysts Synthesized by Hydrogel-Assisted Route for Total Oxidation of Toluene. Applied Catalysis B: Environmental, 195, 59-68.
[Google Scholar] [CrossRef
[43] Carabineiro, S.A.C., Chen, X., Konsolakis, M., et al. (2015) Catalytic Oxidation of Toluene on Ce-Co and La-Co Mixed Oxides Synthesized by Exotemplating and Evaporation Methods. Catalysis Today, 244, 161-171.
[Google Scholar] [CrossRef
[44] Hosseini, S.A., Salari, D., Niaei, A. and Oskoui, S.A. (2013) Physical-Chemical Property and Activity Evaluation of LaB0.5Co0.5O3 (B = Cr, Mn, Cu) and LaMnxCo1-xO3 (x = 0.1, 0.25, 0.5) Nano Perovskites in VOC Combustion. Journal of Industrial and Engineering Chemistry, 19, 1903-1909.
[Google Scholar] [CrossRef
[45] Rousseau, S., Loridant, S., Delichere, P., et al. (2009) La1-xSrxCo1-yFeyO3 Perovskites Prepared by Sol-Gel Method: Characterization and Relationships with Catalytic Properties for Total Oxidation of Toluene. Applied Catalysis B: Environmental, 88, 438-447.
[Google Scholar] [CrossRef
[46] Ferri, D. and Forni, L. (1998) Methane Combustion on Some Perovskite-Like Mixed Oxides. Applied Catalysis B: Environmental, 16, 119-126.
[Google Scholar] [CrossRef
[47] Luo, Y., Wang, K., Chen, Q., et al. (2015) Preparation and Characterization of Electrospun La1-xCexCoOδ: Application to Catalytic Oxidation of Benzene. Journal of Hazardous Materials, 296, 17-22.
[Google Scholar] [CrossRef] [PubMed]
[48] Zhao, Z., Dai, H., Deng, J., et al. (2012) Three-Dimensionally Ordered Macroporous La0.6Sr0.4FeO3-δ: High-Efficiency Catalysts for the Oxidative Removal of Toluene. Microporous and Mesoporous Materials, 163, 131-139.
[Google Scholar] [CrossRef
[49] Ji, K., Dai, H., Deng, J., et al. (2013) Glucose-Assisted Hydrothermal Preparation and Catalytic Performance of Porous LaFeO3 for Toluene Combustion. Journal of Solid State Chemistry, 199, 164-170.
[Google Scholar] [CrossRef
[50] Liu, Y., Dai, H., Du, Y., et al. (2012) Controlled Preparation and High Catalytic Performance of Three-Dimensionally Ordered Macroporous LaMnO3 with Nanovoid Skeletons for the Combustion of Toluene. Journal of Catalysis, 287, 149-160.
[Google Scholar] [CrossRef
[51] Ji, K., Dai, H., Deng, J., et al. (2013) Catalytic Removal of Toluene over Three-Dimensionally Ordered Macroporous Eu1-xSrxFeO3. Chemical Engineering Journal, 214, 262-271.
[Google Scholar] [CrossRef
[52] Ji, K., Dai, H., Deng, J., et al. (2013) Three-Dimensionally Ordered Macroporous Eu0.6Sr0.4FeO3 Supported Cobalt Oxides: Highly Active Nanocatalysts for the Combustion of Toluene. Applied Catalysis B: Environmental, 129, 539-548.
[Google Scholar] [CrossRef
[53] He, C.B., Pan, K.L. and Chang, M.B. (2018) Catalytic Oxidation of Trichloroethylene from Gas Streams by pErovskite-Type Catalysts. Environmental Science and Pollution Research, 25, 11584-11594.
[Google Scholar] [CrossRef] [PubMed]
[54] Pan, K.L., He, C.B. and Chang, M.B. (2018) Oxidation of TCE by Combining Perovskite-Type Catalyst with DBD. IEEE Transactions on Plasma Science, 47, 1152-1163.
[Google Scholar] [CrossRef
[55] Aranzabal A., Romero-Sáez, M., Elizundia, U., et al. (2012) Deactivation of H-Zeolites during Catalytic Oxidation of Trichloroethylene. Journal of Catalysis, 296, 165-174.
[Google Scholar] [CrossRef
[56] Blanch-Raga, N., Palomares, A.E., Martínez-Triguero, J. and Valencia, S. (2016) Cu and Co Modified β Zeolite Catalysts for the Trichloroethylene Oxidation. Applied Catalysis B: Environmental, 187, 90-97.
[Google Scholar] [CrossRef
[57] Wang, L., Zhang, C., He, H., Liu, F.D. and Wang, C.X. (2016) Effect of Doping Metals on OMS-2/γ-Al2O3 Catalysts for Plasma-Catalytic Removal of o-Xylene. The Journal of Physical Chemistry C, 120, 6136-6144.
[Google Scholar] [CrossRef
[58] Tanasoi, S., Mitran, G., Tanchoux, N., et al. (2011) Transition Metal-Containing Mixed Oxides Catalysts Derived from LDH Precursors for Short-Chain Hydrocarbons Oxidation. Applied Catalysis A: General, 395, 78-86.
[Google Scholar] [CrossRef
[59] Tanasoi, S., Tanchoux, N., Urdă, A., et al. (2009) New Cu-Based Mixed Oxides Obtained from LDH Precursors, Catalysts for Methane Total Oxidation. Applied Catalysis A: General, 363, 135-142.
[Google Scholar] [CrossRef
[60] Zeng, X., Li, B., Liu, R., Li, X. and Zhu, T.L. (2020) Investigation of Promotion Effect of Cu Doped MnO2 Catalysts on Ketone-Type VOCs Degradation in a One-Stage Plasma-Catalysis System. Chemical Engineering Journal, 384, Article ID: 123362.
[Google Scholar] [CrossRef
[61] Todorova, S., Blin, J.L., Naydenov, A., et al. (2020) Co3O4-MnOx Oxides Supported on SBA-15 for CO and VOCs Oxidation. Catalysis Today, 357, 602-612.
[Google Scholar] [CrossRef
[62] Xiao, Z., Yang, J., Ren, R., et al. (2020) Facile Synthesis of Homogeneous Hollow Microsphere Cu-Mn Based Catalysts for Catalytic Oxidation of Toluene. Chemosphere, 247, Article ID: 125812.
[Google Scholar] [CrossRef] [PubMed]
[63] Zeng, Y., Haw, K.G., Wang, Z., et al. (2021) Double Redox Process to Synthesize CuO-CeO2 Catalysts with Strong Cu-Ce Interaction for Efficient Toluene Oxidation. Journal of Hazardous Materials, 404, Article ID: 124088.
[Google Scholar] [CrossRef] [PubMed]
[64] Wang, L., Xie, H., Wang, X., et al. (2017) Preparation of LaMnO3 for Catalytic Combustion of Vinyl Chloride. Chinese Journal of Catalysis, 38, 1406-1412.
[Google Scholar] [CrossRef
[65] Wang, J., Shi, Z. and Zhou, R. (2020) High Activity of CeO2-TiO2 Composites for Deep Oxidation of 1, 2-Dichlo- roethane. Journal of Rare Earths, 38, 906-911.
[Google Scholar] [CrossRef
[66] Kim, J., Lee, J.E., Lee, H.W., et al. (2020) Catalytic Ozonation of Toluene Using Mn-M Bimetallic HZSM-5 (M: Fe, Cu, Ru, Ag) Catalysts at Room Temperature. Journal of Hazardous Materials, 397, Article ID: 122577.
[Google Scholar] [CrossRef] [PubMed]
[67] Kinnunen, N.M., Suvanto, M., Moreno, M.A., et al. (2009) Methane Oxidation on Alumina Supported Palladium Catalysts: Effect of Pd Precursor and Solvent. Applied Catalysis A: General, 370, 78-87.
[Google Scholar] [CrossRef
[68] Danielis, M., Colussi, S., de Leitenburg, C. and Trovarelli, A. (2020) The Role of Palladium Salt Precursors in Pd-PdO/ CeO2 Catalysts Prepared by Dry Milling for Methane Oxidation. Catalysis Communications, 135, Article ID: 105899.
[Google Scholar] [CrossRef
[69] He, C., Cheng, J., Zhang, X., et al. (2019) Recent Advances in the Catalytic Oxidation of Volatile Organic Compounds: A Review Based on Pollutant Sorts and Sources. Chemical Reviews, 119, 4471-4568.
[Google Scholar] [CrossRef] [PubMed]
[70] Kim, S.C., Nahm, S.W. and Park, Y.K. (2015) Property and Performance of Red Mud-Based Catalysts for the Complete Oxidation of Volatile Organic Compounds. Journal of Hazardous Materials, 300, 104-113.
[Google Scholar] [CrossRef] [PubMed]
[71] Liu, X., Zeng, J., Shi, W., et al. (2017) Catalytic Oxidation of Benzene over Ruthenium-Cobalt Bimetallic Catalysts and Study of Its Mechanism. Catalysis Science & Technology, 7, 213-221.
[Google Scholar] [CrossRef
[72] Li, G., Zhang, C., Wang, Z., et al. (2018) Fabrication of Mesoporous Co3O4 Oxides by Acid Treatment and Their Catalytic Performances for Toluene Oxidation. Applied Catalysis A: General, 550, 67-76.
[Google Scholar] [CrossRef
[73] Wang, J., Liu, X., Zeng, J.L. and Zhu, T.Y. (2016) Catalytic Oxidation of Trichloroethylene over TiO2 Supported Ruthenium Catalysts. Catalysis Communications, 76, 13-18.
[Google Scholar] [CrossRef
[74] Yang, J., Huang, Y., Chen, Y.W., et al. (2020) Active Site-Directed Tandem Catalysis on CuO/VO-MnO2 for Efficient and Stable Catalytic Ozonation of S-VOCs under Mild Condition. Nano Today, 35, Article ID: 100944.
[Google Scholar] [CrossRef