稀土金属有机骨架材料荧光传感环境污染物的研究进展
Research Progress on Lanthanide Metal-Organic of Frameworks Fluorescent Sensing for Environmental Pollutants
DOI: 10.12677/JAPC.2023.123020, PDF,    国家自然科学基金支持
作者: 何顺生*, 陈 骏, 徐毅飞, 郭闯云, 胡心茹, 韦佳敏, 刘维桥, 杨廷海#：江苏理工学院化学化工学院，江苏 常州；翟永恒：江苏绿泰检测科技有限公司，江苏 无锡
关键词: 稀土金属有机骨架材料；荧光传感；传感机理；环境污染物；Lanthanide Metal-Organic of Frameworks； Fluorescent Sensing； Sensing Mechanism； Environmental Pollutant
摘要: 稀土金属有机骨架材料(LnMOFs)由于其稀土金属离子(Ln3+)独特的电子结构和“天线效应”，具有优秀的光物理性质，包括尖锐的特征发射峰、大的斯托克斯位移值、长发光寿命和高量子效率等。LnMOFs材料由于与客体分子之间的相互作用而引起荧光性能的变化，从而实现对环境污染物的识别传感，因此在荧光传感应用方面得到了广泛的研究。本文我们综述了近年来LnMOFs在环境污染物识别和检测方面的研究进展，包括阴阳离子、有机溶剂分子、硝基芳香族化合物和农药。
Abstract: Lanthanide Metal-Organic of Frameworks (LnMOFs) have excellent photophysical properties, including sharp characteristic emission peak, large stokes shift value, long luminous lifetime and high quantum efficiency due to lanthanide metal ions (Ln3+) unique electronic structure and the “antenna effect”. LnMOFs materials have potential application in the field of fluorescence sensing due to changes in their fluorescence performance caused by interactions with guest molecules, thereby achieving recognition and sensing for environmental pollutants. In this paper, we review the progress of LnMOFs in fluorescent sensing of environmental pollutants, including anion and cationic ions, organic solvent molecules, nitro-aromatic compounds and pesticides.
文章引用：何顺生, 陈骏, 徐毅飞, 郭闯云, 胡心茹, 韦佳敏, 翟永恒, 刘维桥, 杨廷海. 稀土金属有机骨架材料荧光传感环境污染物的研究进展[J]. 物理化学进展, 2023, 12(3): 171-186. https://doi.org/10.12677/JAPC.2023.123020

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