臭氧–铁碳催化氧化法降解高浓度有机废水的研究
Study on Degradation of High Concentration Organic Wastewater by Ozone-Iron-Carbon Catalytic Oxidation
摘要: 本文论述了臭氧 + 铁碳协同反应处置高浓度有机废水的预处理技术研究,具体研究废液COD指标的降解率,考察体系的pH、臭氧浓度、温度以及时间对废液COD指标降解的影响,确定臭氧–铁碳协同降解废液COD的最佳条件,有效地解决了高浓度有机废水的处理难题,COD降解率高达97%以上,为产生高浓度有机废水厂家提供宝贵建议。
Abstract: In this paper, the pretreatment technology of high-concentration organic wastewater treated by synergistic reaction of ozone and iron carbon is discussed. The degradation rate of COD index of waste liquid is studied specifically, and the influence of pH, O3 concentration, temperature and time of the system on COD degradation effect is investigated. The optimum conditions of COD degradation by ozone-iron and carbon were determined. Effectively solve the problem of high concentration organic wastewater treatment, COD degradation rate of up to 97%, for the production of high concentration organic wastewater manufacturers to provide valuable advice.
文章引用:朱海杰, 郭鹏飞, 王振宇, 王臣, 高东东. 臭氧–铁碳催化氧化法降解高浓度有机废水的研究[J]. 环境保护前沿, 2023, 13(4): 925-931. https://doi.org/10.12677/AEP.2023.134113

参考文献

[1] 史季, 樊军红. 高级氧化技术在水处理中的研究进展[J]. 工程技术(文摘版), 2016(7): 00030.
[2] 郜子兴, 杨文玲. 臭氧催化氧化技术在废水处理中的研究进展[J]. 应用化工, 2017, 46(12): 2455-2458, 2462.
[3] 张先炳. 臭氧/微电解工艺处理活性偶氮染料废水的效能与作用机制[D]: [博士学位论文]. 哈尔滨: 哈尔滨工业大学, 2015.
[4] 霍子平. 试析微电解技术在工业废水处理中的应用[J]. 建筑工程技术与设计, 2017(36): 2424.
[5] Zeng, Z., Zou, H., Li, X., et al. (2012) Ozonation of Acidic Phenol Wastewater with O3/Fe(II) in a Rotating Packed Bed Reactor: Optimization by Response Surface Methodology. Chemical Engineering and Processing: Process Intensification, 60, 1-8. [Google Scholar] [CrossRef
[6] Wang, Y.P., Wang, L.J., Peng, P.Y., et al. (2006) Treatment of Naphthalene Derivatives with Iron-Carbon Micro-Electrolysis. Transactions of Nonferrous Metals Society of China, 16, 1442-1447. [Google Scholar] [CrossRef
[7] Cheng, H., Xu, W., Liu, J., et al. (2007) Pretreatment of Wastewater from Triazine Manufacturing by Coagulation, Electrolysis, and Internal Microelectrolysis. Journal of Haz-ardous Materials, 146, 385-392. [Google Scholar] [CrossRef] [PubMed]
[8] Zhao, W. (2011) Ozonation of Cationic Red X-GRL in Aqueous Solution: Kinetics and Modeling. Journal of Hazardous Materials, 187, 526-533. [Google Scholar] [CrossRef] [PubMed]
[9] Wang, M.X., Zhu, S.Q. and He, X.W. (2001) Study on Micro Electrolysis Treatment for Decolorizing Dyed Water. Journal of China University of Mining and Technology, 11, 212-216.
[10] Wang, Y., Zhang, H., Zhang, J.H., et al. (2011) Degradation of Tetracycline in Aqueous Media by Ozonation in an Internal Loop-Lift Reactor. Journal of Hazardous Materials, 1929, 35-43. [Google Scholar] [CrossRef] [PubMed]
[11] 张子间. 微电解法在废水处理中的研究及应用[J]. 工业安全与环保, 2004, 30(4): 8-10. [Google Scholar] [CrossRef
[12] Zhao, Q.H., Ge, Y.N., Zuo, P., et al. (2016) Degrada-tion of Thiamethoxam in Aqueous Solution by Ozonation: Influencing Factors, Intermediates, Degradation Mechanism and Toxicity Assessment. Chemosphere, 146, 105-112. [Google Scholar] [CrossRef] [PubMed]
[13] 董姣, 董文艺, 张先炳, 等. 臭氧/微电解工艺对8种染料单独及混合配水的处理效能[J]. 环境工程学报, 2016, 10(4): 1835-1841.
[14] Ikhlaq, A., Brown, D.R. and Kasprzyk-Hordem, B. (2014) Catalytic Ozonation for the Removal of Organic Contaminants in Water on ZSM-5 Zeo-lites. Applied Catalysis B: Environmental, 154/155, 110-122. [Google Scholar] [CrossRef
[15] Sevimli, M.F. and Sarikaya, H.Z. (2002) Ozone Treatment of Textile Effluents and Dyes: Effect of Applied Ozone Dose, pH and Dye Concentration. Journal of Chemical Technology & Biotechnology, 77, 842-850. [Google Scholar] [CrossRef
[16] 牟洁. 臭氧氧化技术在水处理中的应用研究[J]. 环境与发展, 2018, 30(1): 81-82.