江苏观山铜矿III、VII和VIII矿脉矿化金属元素特征和成因
Characteristics and Genesis of Mineralized Metal Elements in the III, VII, and VIII Ore Veins of Guanshan Copper Deposit, Jiangsu
DOI: 10.12677/AG.2023.1311119, PDF,   
作者: 谢晓华:江苏华东有色深部地质勘查有限责任公司,江苏 南京;江苏省有色金属华东地质勘查局八一三队,江苏 南京
关键词: 观山铜矿III、VII和VIII矿脉矿化元素丰度线性拟合成因Guanshan Copper Mine III VII and VIII Ore Veins Copper Ore-Forming Elements Abundance Linear Fit Genesiss
摘要: 江苏观山铜矿位于下扬子板块北缘沿江坳陷带内的溧水火山岩盆地大王山组地层中,III、VII和VIII矿脉产于观山铜矿西北角的粗安斑岩和角闪粗安斑岩中。为了查明三条矿脉矿化金属元素空间分布特征和共生关系,对主要成矿元素Cu、Au、Ag、Pb和Zn做了数学统计分析。在矿化金属元素丰度分析中,Cu在探槽样(TC) (2050 ppm)分别低于拨土样(BT) (2458 ppm)和钻孔样(ZK) (10,300 ppm);Ag在拨土样(BT) (7.25 ppm)低于钻孔样(ZK) (22.6 ppm);Au在拨土样(BT) (0.269 ppm)和钻孔样(ZK) (0.252 ppm)中相当;从拨土样(BT) (30.96 ppm)到钻孔样(ZK) (2332 ppm),Pb呈现逐渐富集;Zn在探槽样(TC) (327 ppm)和钻孔样(ZK) (346 ppm)类似。在矿化金属元素线性拟合中,Cu和Au在探槽样(TC)决定系数最高(0.754),线性拟合优度最好,Cu和Ag在拨土样(BT)决定系数为0.547,线性拟合优度次之,Cu和Pb、Zn决定系数分别低于0.5,线性拟合优度最差,无明显线性关系。通过对矿床地质年代学和同位素地球化学数据分析,显示该矿床形成于白垩纪早期(K1),成矿物质主要来自上地幔和下地壳,岩浆热液经过后期大气水的混合,在偏碱性、中低温度条件下成矿。通过以上对观山铜矿床内部III、VII和VIII矿脉主要矿化金属元素分析,阐明了主要矿化金属元素空间分布特征和共生关系,并对矿床演化地质过程进行简要概述,为后期在观山铜矿开展工作提供参考意见。
Abstract: Jiangsu Guanshan copper deposit, located in the Dawangshan Formation strata of Lishui volcanic basin in the Yanjiang depression zone on the northern edge of the lower Yangtze plate. III, VII and VIII ore veins occur in coarse andesite porphyry and hornblende coarse andesite porphyry in the Northwest Angle of Guanshan Copper Mine. In order to identify the distribution characteristics and co-exist of mineralized metal elements in three ore veins, it is based on mathematical statistical analysis of major ore-forming metal elements Cu, Au, Ag, Pb and Zn in three ore vein regions. The abundance of Cu in the trench sample (TC) (2050 ppm) is lower than that in the soil sample (BT) (2458 ppm) and the abundance of Cu in the borehole sample (ZK) (10,300 ppm); the abundance of Ag in BT (7.25 ppm) is lower than that in ZK (22.6 ppm); the abundance of Au in BT (0.269 ppm) is equivalent in ZK (0.252 ppm); Pb gradually enriched from BT (30.96 ppm) to ZK (2332 ppm); Zn has similar characteristics in TC (327 ppm) and ZK (346 ppm). In the analysis of the linear fitting of mineralized metal elements, Cu and Au have the highest determination coefficients (0.754) in the TC. The coefficient of determination for Cu and Ag in BT is 0.547. The determination coefficients for Cu, Pb, and Zn are all below 0.5, indicating a poor linear fit and no significant linear relationship. Based on the results from research and analysis of geological chronology and isotope geochemistry data of the deposit, it is indicated that the formation of this deposit occurred during the Early Cretaceous (K1) period. The ore-forming materials mainly originated from the upper mantle and lower crust. The mineralization took place under alkaline, medium to low-temperature conditions when magmatic hydrothermal fluids mixed with later atmospheric water. By analyzing the major ore-forming metal elements in internal veins III, VII, and VIII of the Guanshan Copper deposit, this study elucidated the spatial distribution characteristics and coexistence relationships of these elements. Additionally, a brief summary of the geological evolution process of the deposit was provided, offering references for future work in the Guanshan Copper deposit.
文章引用:谢晓华. 江苏观山铜矿III、VII和VIII矿脉矿化金属元素特征和成因[J]. 地球科学前沿, 2023, 13(11): 1252-1267. https://doi.org/10.12677/AG.2023.1311119

参考文献

[1] 姜玲, 杨建勇, 等. 江苏省溧水县观山铜矿核查区资源储量调查报告[R]. 全国地质资料馆, 2010.
[2] 禹尧, 徐夕生. 长江中下游地区白垩纪富碱火山岩浆作用[J]. 地球科学(中国地质大学学报), 2009, 34(1): 105-116.
[3] 梁业恒, 孙晓明, 翟伟, 等. 江苏溧水观山高硫型铜铅金矿床40Ar/39Ar定年及其地质意义[J]. 高校地质学报, 2010, 16(2): 143-148.
[4] 王丽娟, 黄建平, 于津海, 等. 长江中下游溧水盆地中基性次火山岩-侵入岩的锆石U-Pb定年和Lu-Hf同位素[J]. 科学通报, 2014, 59(14): 1305-1317.
[5] 张少琴, 王丽娟, 杨颍鹤. 长江中下游溧水盆地火山岩的时代、地球化学特征及其地质意义[J]. 高校地质学报, 2015, 21(1): 15-30.
[6] 邓龙林, 朱伟, 石富军, 等. 江苏观山铜矿钻孔原生晕特征及深部找矿预测[J]. 矿产勘查, 2018, 9(10): 1926-1931.
[7] 刘俊, 彭芳. 江苏溧水火山岩盆地观山旋回岩石学特征[J]. 昆明工学院学报, 1991, 16(1): 12-20.
[8] 李超文, 郭锋, 李晓勇. 溧水盆地晚中生代基性火山岩成因与深部动力学过程探讨[J]. 地球化学, 2004, 33(4): 361-371.
[9] 高晓峰, 郭锋, 李超文, 等. 溧水盆地两类晚中生代中酸性火山岩的岩石成因[J]. 岩石矿物学杂志, 2007, 26(1): 1-12.
[10] 梁业恒, 孙晓明, 翟伟, 等. 江苏溧水盆地次火山岩元素地球化学[J]. 矿物学报, 2009, 29(z1): 63-65.
[11] 梁业恒, 孙晓明, 翟伟, 等. 江苏观山铜铅金矿床成矿流体地球化学和成因[J]. 矿床地质, 2008, 27(5): 605-612.
[12] 梁业恒, 孙晓明, 翟伟, 等. 江苏观山高硫型铜铅金矿床稳定同位素地球化学和成因意义[J]. 地质与勘探, 2010, 46(4): 698-704.
[13] 王堂喜, 唐端来. 江苏省溧水县观山铜多金属矿地质特征和成因探讨[C]//2006年华东六省一市地学科技论坛论文集. 南昌: 江西科学技术出版社, 2006: 117-121.
[14] 王振亮, 林天亮, 蔡永文. 综合物探方法在江苏观山铜多金属矿区寻找隐伏矿体的应用[J]. 矿产勘查, 2015, 6(1): 48-52.
[15] 朱伟, 邓龙林, 等. 综合物探方法在江苏观山铜矿深部勘查中的应用[J]. 矿产勘查, 2018, 9(6): 1244-1248.
[16] 楚之潮, 秦有余. 长江中下游铜矿地质特征[C]//长江中下游铁铜金银矿产地质论文集. 北京: 冶金工业出版社, 1996: 1-96.
[17] Weislogel, A.L., Graham, S.A., Chang, E.Z., et al. (2006) Detrital Zircon Provenance of the Late Triassic Songpan-Ganzi Complex: Sedimentary Record of Collision of the North and South China Blocks. Geology, 34, 97-100. [Google Scholar] [CrossRef
[18] 常印佛, 刘湘培, 等. 长江中下游地区铜铁成矿带[M]. 北京: 地质出版社, 1991.
[19] 翟裕生, 姚书振, 等. 长江中下游地区铁铜(金)成矿规律[M]. 北京: 地质出版社, 1992.
[20] 朱光, 徐嘉炜, 刘国生, 等. 下扬子地区前陆变形构造格局及其动力学机制[J]. 中国区域地质, 1999(1): 73-79.
[21] 董树文, 马立成, 刘刚, 等. 论长江中下游成矿动力学[J]. 地质学报, 2011, 85(5): 612-625.
[22] 华东有色金属矿产勘查开发院. 江苏省溧水县观山及其外围次火山岩型铜多金属矿普查工作设计书[R]. 南京: 华东有色金属矿产勘查开发院, 2005.
[23] 储国正. 长江中下游地区成矿地质背景分析[J]. 安徽地质, 2003, 13(1): 34-43, 53.
[24] 刘俊, 彭芳. 江苏溧水火山岩盆地观山旋回岩石学特征[J]. 昆明工学院学报, 1991, 16(1): 12-20..
[25] 江苏冶金地质勘探公司813队. 江苏溧水火山岩地区地质特征及成矿规律讨论[R]. 南京: 江苏冶金地质勘探公司813队, 1980.
[26] Gao, S., Luo, T.C., et al. (1999) Structure and Composition of the Continental Crust in East China. Science in China Series D: Earth Sciences, 42, 129-140. [Google Scholar] [CrossRef
[27] Taylor, S.R. and McLennan, S.M. (1985) The Continental Crust: Its Composition and Evolution. Blackwell, Oxford.
[28] 刘英俊, 曹励明, 等. 元素地球化学[M]. 北京: 科学出版社, 1984.
[29] 夏嘉生. 江苏漂水火山岩盆地内生金属矿床定位模式及找矿思路[J]. 江苏地质, 1995, 19(1): 5-11
[30] 周金城, 赵太平, 等. 溧水中生代橄榄安粗岩系的构造环境及演化关系[J]. 南京大学学报, 1994, 30(3): 504-509.
[31] 芮宗瑶, 黄崇轲, 等. 中国斑岩铜(钼)矿床[M]. 北京: 地质出版社, 1984.
[32] 钱鹏, 陆建军, 姚春亮. 德兴斑岩铜矿成矿流体演化与来源的流体包裹体研究[J]. 南京大学学报(自然科学), 2003, 39(3): 319-326.
[33] 吴德新, 赵元艺, 吕立娜, 等. 江西德兴朱砂红斑岩铜矿流体包裹体特征及其成矿意义[J]. 地质学报, 2013, 87(5): 677-690.
[34] Crear, D.A. and Barnes, H.L. (1976) Ore Solution Chemistry: Solubilities of Chalcopyrite and Chalcocite Assemblages in Hydrothermal Solution at 200 Degrees to 350 Degrees. Economic Geology, 71, 772-794. [Google Scholar] [CrossRef
[35] Feiss, P.G. (1978) Magmatic Sources of Copper in Porphyry Copper Deposits. Economic Geology, 73, 397-404. [Google Scholar] [CrossRef