富勒烯材料的导电性和磁性研究
Studies on the Conductivity and Magnetism of Fullerene Materials
摘要: 作为碳的一种新的同素异形体，80年代中期富勒烯的发现证实了理论家认为可能存在具有二十面体对称性的多面体碳分子的预测。由于富勒烯具有独特的分子结构、磁性和电子固态特性，因此吸引了物理学、化学和生物学等不同领域科学家的兴趣。纯富勒烯和富勒烯基化合物均能显示有趣的固态特性，包括铁磁性、光电导性和非线性光学等行为，具有重要的研究价值。本文针对富勒烯的结构特点、固体特性、导电性及磁性进行了概述，重点分析富勒烯基供体–受体配合物及自由基离子盐的导电性和磁性，为富勒烯导体的磁性研究奠定基础。
Abstract: In the mid-1980s, the discovery of fullerenes, a new allotrope of carbon, confirmed theorists’ predictions that there might be polyhedral carbon molecules with icosahedral symmetry. Due to their unique molecular structure, magnetic and electronic solid-state properties, fullerenes have attracted the interest of scientists in different fields such as physics, chemistry and biology. Both pure fullerenes and fullerene-based compounds exhibit interesting solid-state properties, including ferromagnetism, photoconductivity and nonlinear optics. Therefore, fullerenes and fullerene- based compounds are of great research value. In this paper, the structural characteristics, solid properties, electrical conductivity and magnetic properties of fullerenes were summarized. Moreover, the electrical conductivity and magnetic properties of fullerene-based donor-accepter complexes and radical ionic salts were analyzed. This work will lay a foundation for the study of magnetic properties of fullerenes conductors.
文章引用：张腾坤, 崔会会, 丁欣宇. 富勒烯材料的导电性和磁性研究[J]. 物理化学进展, 2023, 12(4): 284-294. https://doi.org/10.12677/JAPC.2023.124029

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