改性沥青阻燃技术研究进展与性能评价
Research Progress and Performance Evaluation of Modified Asphalt Flame-Retardant Technology
DOI: 10.12677/HJCE.2023.1211158, PDF,    科研立项经费支持
作者: 向志亨*, 聂忆华, 刘 庆, 张若溪:湖南科技大学土木工程学院,湖南 湘潭
关键词: 道路沥青阻燃改性技术性能评价方法Road Asphalt Flame-Retardant Modification Technical Performance Evaluation Methods
摘要: 为推动阻燃改性沥青技术的发展,文章通过对沥青燃烧反应过程中组分变化的分析,进一步探究了其阻燃机理;通过对国内外阻燃改性沥青的原材料选配及制备流程的梳理和归纳,探究了阻燃剂掺量和制备工艺对阻燃效果的影响;从宏观角度调查了国内外阻燃改性沥青的基本性能评价方法;基于各类阻燃材料的差异性,对比评价了有机、无机阻燃剂与复合阻燃剂改性沥青的阻燃性能差异;最后从微观角度,对阻燃改性沥青的阻燃机理进行了阐述。
Abstract: In this paper, in order to promote the development of flame-retardant modified asphalt technology, the flame-retardant mechanism was further explored through the analysis of the change of components in the combustion reaction process of asphalt. Through the selection of raw materials and preparation process of flame-retardant modified asphalt at home and abroad, the influence of flame-retardant content and preparation process on the flame-retardant effect was explored. The basic performance evaluation methods of flame-retardant modified asphalt at home and abroad are investigated from the macroscopic point of view. Based on the difference of various flame-retardant materials, the flame-retardant properties of asphalt modified by organic flame retardant, inorganic flame retardant and composite flame retardant were compared and evaluated. Finally, the flame-retardant mechanism of flame-retardant modified asphalt is discussed from the microscopic point of view.
文章引用:向志亨, 聂忆华, 刘庆, 张若溪. 改性沥青阻燃技术研究进展与性能评价[J]. 土木工程, 2023, 12(11): 1379-1396. https://doi.org/10.12677/HJCE.2023.1211158

参考文献

[1] 龚景松, 傅维镳. 沥青燃料的热解特性研究[J]. 冶金能源, 2002, 21(4): 36-38+58.
[2] 刘圣洁, 林钰, 李梦然, 等. 基于MSCR试验的温拌阻燃沥青高温性能评价与分级[J]. 材料导报, 2023, 37(9): 146-151.
[3] 杨小龙, 申爱琴, 刘贵勇, 等. 考虑隧道阻燃的纳米黏土/ATH复合改性沥青优化设计[J]. 材料导报, 2022, 36(21): 96-103.
[4] 付剑锋, 成元海. 表面改性纳米阻燃沥青流变及阻燃性能[J]. 市政技术, 2022, 40(11): 182-190+195.
[5] 何兆益, 谭洋伟, 李家琪, 等. 埃洛石纳米管协效阻燃改性沥青性能及机理研究[J]. 材料导报, 2022, 36(2): 72-79.
[6] 申爱琴, 苏宇轩, 杨小龙, 等. ATH/MMT阻燃剂对沥青混合料性能的影响[J]. 长安大学学报(自然科学版), 2020, 40(2): 1-9.
[7] 王云鹤. 基质沥青热解燃烧特性与物质变迁规律研究[D]: [硕士学位论文]. 杭州: 中国计量大学, 2020.
[8] Xia, W.J., Xu, T. and Wang, H. (2019) Thermal Behaviors and Harmful Volatile Constituents Released from Asphalt Components at High Temperature. Journal of Hazardous Materials, 373, 741-752. [Google Scholar] [CrossRef] [PubMed]
[9] Xia, W.J., Xu, T., Wang, H., et al. (2019) Combustion Kinetics of Asphalt Binder Components and the Release Processes of Gaseous Products. Combustion and Flame, 206, 322-333. [Google Scholar] [CrossRef
[10] 黄亚东, 冯丹丹, 吴珂, 等. 沥青燃烧特性的实验研究[J]. 消防科学与技术, 2011, 30(6): 473-476.
[11] 林海成, 路建强, 杜傲伟, 等. 阻燃沥青的燃烧特性及动力学分析[J]. 内蒙古科技大学学报, 2022, 41(1): 93-98.
[12] 杨小龙, 申爱琴, 蒋宜馨, 等. 基于阻燃抑烟的纳米黏土改性沥青综述[J]. 交通运输工程学报, 2021, 21(5): 42-61.
[13] 李祖伟, 陈辉强, 牟建波, 等. 沥青阻燃改性技术研究及其阻燃机理[J]. 长沙交通学院学报, 2002, 18(4): 44-47.
[14] Xia, W., Wang, S., Xu, T., et al. (2021) Flame Retarding and Smoke Suppressing Mechanisms of Nano Composite Flame Retardants on Bitumen and Bituminous Mixture. Construction and Building Materials, 266, Article ID: 121203. [Google Scholar] [CrossRef
[15] Shen, T.S., Huang, Y.H. and Chien, S.W. (2008) Using Fire Dynamic Simulation (FDS) to Reconstruct an Arson Fire Scene. Building and Environment, 43, 1036-1045. [Google Scholar] [CrossRef
[16] 盛燕萍, 乔云雁, 薛哲, 等. 阻燃剂表面改性对阻燃沥青性能的影响[J]. 硅酸盐通报, 2018, 37(3): 961-966.
[17] Tan, Y., Xie, J., Wang, Z., et al. (2023) Effect of Surfactant Modified Nano-Composite Flame Retardant on the Combustion and Viscosity-Temperature Properties of Asphalt Binder and Mixture. Powder Technology, 420, Article ID: 118188. [Google Scholar] [CrossRef
[18] 马建兵, 李波, 王强. 新型高效沥青阻燃剂燃烧试验分析[J]. 中国建材科技, 2011, 20(5): 44-47.
[19] Ren, F., Zhang, X., Wei, Z., et al. (2013) Effect of Particle Size and Content of Magnesium Hydroxide on Flame Retardant Properties of Asphalt. Journal of Applied Polymer Science, 129, 2261-2272. [Google Scholar] [CrossRef
[20] 许云, 王海春, 田泽宇, 等. 路面沥青阻燃性试验研究[J]. 青海大学学报(自然科学版), 2011, 29(6): 20-22.
[21] Chen, R., Gong, J., Jiang, Y., et al. (2018) Halogen-Free Flame Retarded Cold-Mix Epoxy Asphalt Binders: Rheological, Thermal and Mechanical Characterization. Construction and Building Materials, 186, 863-870. [Google Scholar] [CrossRef
[22] Jiang, Q., Li, N., Yang, F., et al. (2021) Rheology and Volatile Organic Compounds Characteristics of Warm-Mix Flame Retardant Asphalt. Construction and Building Materials, 298, Article ID: 123691. [Google Scholar] [CrossRef
[23] Pang, Q., Li, J., Gao, L., et al. (2020) Preparation and Evaluation of Composite Flame Retardant Asphalt in Tunnel. IOP Conference Series: Materials Science and Engineering, 741, Article ID: 012029. [Google Scholar] [CrossRef
[24] 熊剑平, 彭文举, 陈宇, 等. 基于热分析的阻燃沥青阻燃机理[J]. 长安大学学报(自然科学版), 2019, 39(2): 47-56.
[25] Yang, X., Shen, A., Jiang, Y., et al. (2021) Properties and Mechanism of Flame Retardance and Smoke Suppression in Asphalt Binder Containing Organic Montmorillonite. Construction and Building Materials, 302, Article ID: 124148. [Google Scholar] [CrossRef
[26] 王圆. 温拌剂和阻燃剂对SBS改性沥青性能的影响[J]. 四川建材, 2019, 45(1): 142-143.
[27] 帕尔哈提∙肉孜. 温拌阻燃沥青及其混合料性能研究[J]. 福建交通科技, 2018(3): 24-26.
[28] Ruzi, P. (2018) Study on Properties of Warm Mixed Flame Retardant Asphalt and Its Mixtures. Fujian Transportation Technology, No. 3, 24-26.
[29] 郭寅川, 王涵, 申爱琴, 等. ATH/OMMT复合改性沥青阻燃抑烟性能与机理分析[J]. 硅酸盐通报, 2020, 39(6): 1989-1997.
[30] Zheng, N., Chen, X., Li, Z., et al. (2021) Effect of ATH/EG Composite Flame Retardant on Properties of High Viscosity Asphalt. Journal of Physics: Conference Series, 2044, Article ID: 012025. [Google Scholar] [CrossRef
[31] 王昊武. 复合阻燃剂制备与阻燃沥青混合料性能研究[D]: [硕士学位论文]. 重庆: 重庆交通大学, 2021.
[32] 武斌. 复合氢氧化物沥青阻燃体系及其路用性能研究[D]: [硕士学位论文]. 杭州: 浙江大学, 2015.
[33] 李九苏, 王平, 王争愿, 等. 十溴二苯乙烷阻燃反应型常温沥青的研究[J]. 长沙理工大学学报(自然科学版), 2020, 17(2): 26-32.
[34] 金雷, 魏建国, 付其林, 等. DBDPE复合阻燃剂对SBS沥青性能的影响[J]. 长安大学学报(自然科学版), 2020, 40(2): 47-55+65.
[35] 付其林, 魏建国, 彭文举, 等. DBDPE-Sb2O3协同阻燃沥青的性能与机理[J]. 中国公路学报, 2020, 33(2): 44-55.
[36] 陈辉强, 唐伯明, 郝培文. BFR-Ti和ZB协同阻燃隧道路面沥青的阻燃性能及机理[J]. 重庆大学学报, 2013, 36(3): 53-58.
[37] Yu, J.Y., Cong, P.L. and Wu, S.P. (2009) Investigation of the Properties of Asphalt and Its Mixtures Containing Flame Retardant Modifier. Construction and Building Materials, 23, 2277-2282. [Google Scholar] [CrossRef
[38] 王平. 反应型常温阻燃沥青研制及混合料性能研究[D]: [硕士学位论文]. 长沙: 长沙理工大学, 2020.
[39] 王俊天. 隧道温拌阻燃沥青混合料性能研究[D]: [硕士学位论文]. 南京: 东南大学, 2021.
[40] 李梦林. LDHs/氢氧化物复合改性沥青阻燃性能与机理研究[D]: [硕士学位论文]. 武汉: 武汉理工大学, 2019.
[41] 陈辉强, 王雄, 李雁翔. 阻燃剂表面改性对温拌阻燃沥青燃烧特性及贮存稳定性的影响[J]. 中国科技论文, 2022, 17(4): 457-462.
[42] Yang, X., Shen, A., Su, Y., et al. (2020) Effects of Alumina Trihydrate (ATH) and Organic Montmorillonite (OMMT) on Asphalt Fume Emission and Flame Retardancy Properties of SBS-Modified Asphalt. Construction and Building Materials, 236, Article ID: 117576. [Google Scholar] [CrossRef
[43] 胡义成, 刘安刚, 刘青海, 等. 基于热重质谱联用技术的改性沥青阻燃抑烟性能分析[J]. 武汉理工大学学报(交通科学与工程版), 2022, 46(4): 707-712.
[44] 龙云霄, 陈辉强, 文中秋, 等. 基于表面改性的温拌阻燃沥青的制备及性能研究[J]. 公路, 2021, 66(10): 296-301.
[45] 刘贤鹏, 奚文彬, 邹莹雪, 等. 阻燃温拌剂复合改性对沥青高低温性能影响[J]. 武汉理工大学学报(交通科学与工程版), 2022, 46(3): 532-536.
[46] 李啟荣, 许新权, 贾致远, 等. ABA-Ti复合阻燃沥青的阻燃及路用性能研究[J]. 武汉理工大学学报(交通科学与工程版), 2021, 45(5): 971-975.
[47] Gu, L.Z., Zhu, K., et al. (2019) Effect of Various Metal Hydroxide Flame Retardants on the Rheological Properties of Asphalt Binder. Materials Science, 25, 348-355. [Google Scholar] [CrossRef
[48] Li, Y.-X., et al. (2022) Combustion Characteristics and Flame Retardant Mechanism of Warm-Mixed Flame-Retardant Asphalt Based on Cone Calorimeter. World of Mining-Surface & Underground, No. 1, 74.
[49] 苟宏伟, 杨晋雷, 黄亮, 等. 聚磷酸铵复合阻燃剂对沥青性能影响研究[J]. 甘肃科技纵横, 2020, 49(3): 20-23+63.
[50] Sheng, Y., Ahmed, A.T., Jia, H., et al. (2022) Preparation and Characterization of Low Flammable Asphalt for Tunnel Pavements. Construction and Building Materials, 359, Article ID: 129559. [Google Scholar] [CrossRef
[51] Bonati, A., Merusi, F., Polacco, G., et al. (2012) Ignitability and Thermal Stability of Asphalt Binders and Mastics for Flexible Pavements in Highway Tunnels. Construction and Building Materials, 37, 660-668. [Google Scholar] [CrossRef
[52] Li, J., He, Z., Yu, L., et al. (2021) Multi-Objective Optimization and Performance Characterization of Asphalt Modified by Nanocomposite Flame-Retardant Based on Response Surface Methodology. Materials, 14, Article 4367. [Google Scholar] [CrossRef] [PubMed]
[53] Yu, S., Shen, S., Steger, R., et al. (2022) Effect of Warm Mix Asphalt Additive on the Workability of Asphalt Mixture: From Particle Perspective. Construction and Building Materials, 360, Article ID: 129548. [Google Scholar] [CrossRef
[54] 王朝辉, 董彪, 高志伟, 等. 无机阻燃改性沥青结构表征及阻燃机理研究[J]. 功能材料, 2014, 45(13): 13045-13049+13055.
[55] 贺海, 王朝辉, 刘志胜, 等. 新型无机阻燃改性沥青的制备与路用性能研究[J]. 公路交通科技, 2014, 31(7): 45-52.
[56] 魏建国, 谢成, 付其林. 阻燃剂对沥青与沥青混合料性能的影响[J]. 中国公路学报, 2013, 26(6): 30-37.
[57] 刘涛, 言志超, 刘祥. 聚磷酸铵阻燃沥青的研究[J]. 石油沥青, 2013, 27(5): 45-48.
[58] 刘细军, 任艳. 氢氧化铝阻燃剂对沥青及沥青混合料性能的影响[J]. 石油沥青, 2013, 27(5): 54-57.
[59] 陈辉强, 郝培文. 钛酸酯偶联剂对沥青阻燃剂表面改性的研究[J]. 武汉理工大学学报, 2009, 31(17): 66-69.
[60] Xia, W., Zhou, X. and Yang, X. (2022) Suppressive Effects of Composite Flame Retardant on Smoke Release, Combustion Soot and Residue Constituents of Asphalt Mixture. Journal of the Energy Institute, 103, 60-71. [Google Scholar] [CrossRef
[61] Wang, S., Tan, L. and Xu, T. (2022) Synergistic Effects of Developed Composite Flame Retardant on VOCs Constituents of Heated Asphalt and Carbonized Layer Compositions. Journal of Cleaner Production, 367, Article ID: 133107. [Google Scholar] [CrossRef
[62] 李娜, 关甫洋, 徐希娟. 对含有不同阻燃剂的改性沥青胶浆的性能试验研究[J]. 中外公路, 2014, 34(3): 308-311.
[63] Ren, Y., Chen, M., Yang, T., et al. (2021) Effect of Steel Slag Aggregate on Pavement and Flame-Retardant Performance of Warm-Mixed Flame-Retardant Asphalt Concrete. Materials, 14, 635. [Google Scholar] [CrossRef] [PubMed]
[64] 王朝辉, 李蕊, 赵娟娟, 等. 两种新型无机复合阻燃改性沥青的流变性能及其阻燃机制[J]. 复合材料学报, 2014, 31(6): 1597-1603.
[65] Abdullah, M.E., Hainin, M.R., Yusoff, N.I.M., et al. (2016) Laboratory Evaluation on the Characteristics and Pollutant Emissions of Nanoclay and Chemical Warm Mix Asphalt Modified Binders. Construction and Building Materials, 113, 488-497. [Google Scholar] [CrossRef
[66] 秦先涛, 陈拴发, 祝斯月, 等. 沥青路面矿物纤维复合阻燃材料及其热重行为研究[J]. 公路交通科技, 2013, 30(12): 7-14.
[67] 何立平, 申爱琴, 梁军林, 等. 阻燃沥青及沥青混合料的阻燃性能及路用性能[J]. 公路交通科技, 2013, 30(12): 15-22.
[68] 王朝辉, 孙晓龙, 刘志胜, 等. 隧道沥青路面阻燃剂的现状与发展[J]. 筑路机械与施工机械化, 2013, 30(12): 41-48.
[69] 李立寒, 邹小龙, 陈春羽. 复配阻燃沥青氧指数和路用性能研究[J]. 建筑材料学报, 2013, 16(1): 76-80.
[70] 陈辉强, 郝培文. 阻燃改性沥青的研发及其混合料的性能评价[J]. 武汉理工大学学报, 2008, 30(12): 58-62.
[71] 夏威. 阻燃沥青混合料在隧道路面中的应用研究[J]. 黑龙江交通科技, 2023, 46(4): 109-111.
[72] 马加春, 李勇, 吴波, 等. 温拌阻燃沥青在昆明西北绕城高速公路上的应用研究[J]. 城市道桥与防洪, 2015(3): 167-170+184+17.
[73] 吴喜荣, 李素贤. 温拌阻燃降噪沥青混合料在隧道路面的应用技术[J]. 水利与建筑工程学报, 2014, 12(6): 172-175.
[74] 程毅, 南雪峰, 宋宪辉. 阻燃温拌沥青技术在丹通高速公路隧道路面中的应用[J]. 辽宁省交通高等专科学校学报, 2013, 15(4): 11-14.