CO2氧化丙烷催化剂研究进展
Advances in Catalysts for CO2 Oxidation of Propane
DOI: 10.12677/MS.2023.1312125, PDF,   
作者: 洪 广：成都大学，机械工程学院，四川 成都
关键词: 丙烷；丙烯；金属催化剂；二氧化碳； Propane； Propylene； Metal Catalysts； Carbon Dioxide
摘要: 由于丙烯需求的快速增长和含丙烷页岩气的勘探，丙烷脱氢制取丙烯工艺越来越受到人们关注，丙烷直接脱氢制丙烯(DHP)提供了较高的丙烷收率，但由于焦炭的形成容易导致催化剂快速失活。CO2辅助丙烷脱氢(CO2-ODHP)是一种很有前景的实现高量产丙烯和CO2利用的技术。近年来对CO2-ODP反应的探索结果表明反应机理限制、CO2利用率低、快速失活仍是限制金属氧化物基催化剂发展的主要因素。金属基催化剂因其独特的性能可以通过催化剂设计调控丙烷脱氢复杂的反应偏向，是未来采用丙烷催化制备丙烯，解决焦炭和烧结问题，提高丙烷脱氢制丙烯产率的一种重要手段。
Abstract: Due to the rapid growth of propylene demand and the exploration of propane-containing shale gas, the process of propane dehydrogenation to propylene has received increasing attention. Direct dehy-drogenation of propane to propylene (DHP) provides high propane yields but is prone to rapid catalyst deactivation due to coke formation. CO2-assisted dehydrogenation of propane (CO2-ODHP) is a promising technology to achieve high volume production of propylene and CO2 utilization. The results of exploring the CO2-ODHP reaction in recent years indicate that reaction mechanism limitation, lowCO2 utilization, and rapid deactivation are still the main factors for the development of metal oxide-based catalysts. Metal-based catalysts, due to their unique properties, can be used to modulate the complex reaction bias of propane dehydrogenation through the design of catalyst, which is an important means to solve the coke and sintering problems and increase the yield of propylene from propane dehydrogenation in the future by using propane catalytic preparation of propylene.
文章引用：洪广. CO2氧化丙烷催化剂研究进展[J]. 材料科学, 2023, 13(12): 1124-1135. https://doi.org/10.12677/MS.2023.1312125

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