材料表面微环境的高效调控优化界面化学反应的研究进展
Research Progress on the Efficient Regulation of the Surface Microenvironment of Materials to Optimize the Chemical Reaction at the Interface
DOI: 10.12677/JOCR.2023.114031, PDF,    国家自然科学基金支持
作者: 薛涵斐, 王嘉博, 李同飞, 钱 涛, 程 煜*：南通大学化学化工学院，江苏 南通
关键词: 催化；微环境；二氧化碳还原；氮还原；三相界面；Electrocatalysis； Microenvironment； Carbon Dioxide Reduction； Nitrogen Reduction； Three-Phase Interface
摘要: 纳米材料的表界面性质和化学反应微环境对催化性能(活性、选择性和耐久性)的密切相关。然而，相应的材料微环境对涉及气体的化学反应的影响机制尚不清楚。本文将影响涉及气体的化学反应热力学和动力学的因素分为气体扩散、质子供应和电子转移。对文献进行分类和系统的调研，重点是通过对催化剂层面调控策略，如促进气体亲和性，调节疏水性和增强导电性等方面的研究。最后，提出了今后在研究材料微环境对气体化学反应的策略和方向。
Abstract: The surface-interface properties of nanomaterials and the reaction microenvironment are closely related to the catalytic performance (activity, selectivity and durability). However, the mechanisms by which the corresponding material microenvironments influence electrochemical reactions involving gases are not clear. In this paper, the factors affecting the thermodynamics and kinetics of electrochemical reactions involving gases are categorized into gas diffusion, proton supply, and electron transfer. This categorization and a systematic survey of the literature focuses on the electrocatalyst level modulation strategies, such as promoting gas affinity, modulating hydrophobicity and enhancing electrical conductivity through research. Finally, future strategies and directions in the study of material microenvironments for gas electrochemical reactions are proposed.
文章引用：薛涵斐, 王嘉博, 李同飞, 钱涛, 程煜. 材料表面微环境的高效调控优化界面化学反应的研究进展[J]. 有机化学研究, 2023, 11(4): 334-345. https://doi.org/10.12677/JOCR.2023.114031

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