钾离子电池锰基正极材料研究进展
Research Progress on Manganese-Based Cathode Materials for Potassium-Ion Batteries
摘要: 化石能源枯竭促进规模储量需求的不断增加。钾离子电池因其成本低廉、元素丰度高、理论工作电压高以及电解液中K+卓越的传输动力学，将有望成商用锂离子电池的替代品。石墨作为钾离子电池负极展现出了优异的循环稳定性，因此，寻找与之相配的正极材料是钾离子电池面临的主要挑战。层状过渡金属氧化物因其结构稳定、合成过程简单及价格低廉等优点而被广泛研究。与以往对钾离子电池电极材料的综述不同，本文从锰基层状氧化物失效机理入手，结合各种改性方法，如阴、阳离子掺杂、形貌设计和调整截止电压等策略以提高电化学性能。最后，对未来钾离子电池领域的主要研究方向和热点进行了展望。
Abstract: The depletion of fossil fuels has led to an increasing demand for large-scale reserves. Potassium-ion batteries are expected to be a replacement for commercial lithium-ion batteries due to their low cost, high element abundance, high theoretical operating voltage, and excellent transport kinetics of K+ in the electrolyte. Graphite exhibits excellent cycling stability as the anode of potassiumion batteries, so finding a suitable cathode material is the main challenge for potassium-ion batteries. Layered transition metal oxides have been widely studied due to their stable structure, simple synthesis process, and low price. Different from the previous reviews on electrode materials for potassium-ion batteries, this paper starts from the failure mechanism of Mn-based layered oxides and combines various modification methods, such as anion and cation doping, morphology design, and adjustment of cut-off voltage to improve electrochemical performance. Finally, the main research directions and hotspots in the field of potassium-ion batteries in the future are prospected.
文章引用：杨佳悦. 钾离子电池锰基正极材料研究进展[J]. 材料科学, 2024, 14(2): 119-129. https://doi.org/10.12677/MS.2024.142015

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