共价有机骨架材料在光催化应用中的最新进展
Research Progress on Covalent Organic Frameworks for Photocatalytic Applications
DOI: 10.12677/MS.2024.142017, PDF,   
作者: 冯 嫣, 朱百慧, 职晓焱, 董方园, 宋敬璇, 傅仰河*：浙江师范大学含氟新材料研究所，先进催化材料教育部重点实验室，浙江 金华
关键词: 共价有机框架材料；光催化；合成方法；应用；Covalent Organic Frameworks； Photocatalysis； Synthetic Methods； Applications
摘要: 共价有机骨架(COFs)是具有高表面积和稳定孔隙率的结晶共价聚合物。COFs材料表现出许多突出的特性，如高比表面积和孔隙率、高的化学稳定性和热稳定性、结构易调控等。这些特殊的优势使COFs材料在光催化方面表现出显著的性能。此外，通过离子掺杂和异质结的形成，可以显著提高COFs材料作为光催化剂的活性。本文综述了COF基材料在光催化体系中的最新研究进展。首先，对COFs的制备方法进行了分析和比较。此外，还介绍了COFs基材料光催化反应的基本原理以及光催化制氢、CO2还原、染料降解、有机转化等方面的最新研究进展。
Abstract: Covalent organic frameworks (COFs) are crystalline covalent polymers with high surface area and stable porosity. COFs materials exhibit many outstanding properties, such as high specific surface area and porosity, high chemical and thermal stability, and easy structural modulation. These special advantages make COFs materials show remarkable performance in photocatalysis. In addition, the activity of COFs materials as photocatalysts can be significantly enhanced by ion doping and heterojunction formation. This paper reviews the recent research progress of COF-based materials in photocatalytic systems. Firstly, the preparation methods of COFs are analysed and compared. In addition, the basic principles of photocatalytic reactions of COFs-based materials and the latest research progress in photocatalytic hydrogen production, CO2 reduction, dye degradation, and organic conversion are presented.
文章引用：冯嫣, 朱百慧, 职晓焱, 董方园, 宋敬璇, 傅仰河. 共价有机骨架材料在光催化应用中的最新进展[J]. 材料科学, 2024, 14(2): 142-151. https://doi.org/10.12677/MS.2024.142017

参考文献

[1] Yang, H., Du, Y., Wan, S., et al. (2015) Mesoporous 2D Covalent Organic Frameworks Based on Shape-Persistent Ar-ylene-Ethynylene Macrocycles. Chemical Science, 6, 4049-4053. [Google Scholar] [CrossRef] 
[2] Liu, X., Huang, D., Lai, C., et al. (2019) Recent Advances in Covalent Organic Frameworks (COFs) as a Smart Sensing Ma-terial. Chemical Society Reviews, 48, 5266-5302. [Google Scholar] [CrossRef] 
[3] Wang, C., Liu, X.-M., Zhang, M., et al. (2019) Two-Dimensional Cobaltporphyrin-Based Cobalt-Organic Framework as an Efficient Photo-catalyst for CO2 Reduction Reaction: A Computational Study. ACS Sustainable Chemistry & Engineering, 7, 14102-14110. [Google Scholar] [CrossRef] 
[4] Côte, A.P., Benin, A.I., Ockwig, N.W., et al. (2005) Porous, Crystalline, Covalent Organic Frameworks. Science, 310, 1166-1170. [Google Scholar] [CrossRef] [PubMed]
[5] Shi, S., Liu, W., Li, Y., et al. (2024) Rational Design of Bimetallic Sites in Covalent Organic Frameworks for Efficient Photocatalytic Oxidative Coupling of Amines. Journal of Colloid and Interface Science, 655, 611-621. [Google Scholar] [CrossRef] [PubMed]
[6] Zhang Y.-P., Han, W., Yang, Y., et al. (2022) S-Scheme Hetero-junction of Black TiO2 and Covalent-Organic Framework for Enhanced Photocatalytic Hydrogen Evolution. Chemical Engineering Journal, 446, Article ID: 137213. [Google Scholar] [CrossRef] 
[7] An, X., Bian, J., Zhu, K., et al. (2022) Facet-Dependent Activity of TiO2/Covalent Organic Framework S-Scheme Heterostructures for CO2 Photoreduction. Chemical Engineering Journal, 442, Article ID: 135279. [Google Scholar] [CrossRef] 
[8] Yang, S., Sa, R., Zhong, H., et al. (2022) Microenvironments Ena-bled by Covalent Organic Framework Linkages for Modulating Active Metal Species in Photocatalytic CO2 Reduction. Advanced Functional Materials, 32, Article ID: 2110694. [Google Scholar] [CrossRef] 
[9] Yang, L., Wang, Y., Yuan, J., et al. (2022) Construction of Covalent-Integrated MOFs@COFs Composite Material for Efficient Synergistic Adsorption and Degradation of Pollutants. Chemical Engineering Journal, 446, Article ID: 137095. [Google Scholar] [CrossRef] 
[10] Hu, Z., Wang, Y., Wang, L., et al. (2024) Synthesis of S-Type Het-erostructure π-COF for Photocatalytic Tetracycline Degradation. Chemical Engineering Journal, 479, Article ID: 147534. [Google Scholar] [CrossRef] 
[11] Bhadra, M., Kandambeth, S., Sahoo, M.K., et al. (2019) Triazine Functionalized Porous Covalent Organic Framework for Photo-Organocatalytic E-Z Isomerization of Olefins. Journal of the American Chemical Society, 141, 6152-6156. [Google Scholar] [CrossRef] [PubMed]
[12] Guan, X., Ma, Y., Li, H., et al. (2018) Fast, Ambient Temperature and Pressure Ionothermal Synthesis of Three-Dimensional Covalent Organic Frameworks. Journal of the American Chemical Society, 140, 4494-4498. [Google Scholar] [CrossRef] [PubMed]
[13] Kuhn, P., Antonietti, M. and Thomas, A. (2008) Porous, Covalent Tria-zine-Based Frameworks Prepared by Ionothermal Synthesis. Angewandte Chemie International Edition, 47, 3450-3453. [Google Scholar] [CrossRef] [PubMed]
[14] Díaz De Greñu, B., Torres, J., García-González, J., et al. (2020) Mi-crowave-Assisted Synthesis of Covalent Organic Frameworks: A Review. ChemSusChem, 14, 208-233. [Google Scholar] [CrossRef] [PubMed]
[15] Ding, S.-Y. and Wang, W. (2013) Covalent Organic Frameworks (COFs): From Design to Applications. Chemical Society Reviews, 42, 548-568. [Google Scholar] [CrossRef] 
[16] Bisbey, R.P. and Dichtel, W.R. (2017) Covalent Organic Frameworks as a Platform for Multidimensional Polymerization. ACS Central Science, 3, 533-543. [Google Scholar] [CrossRef] [PubMed]
[17] Koo, B.T., Heden, R.F. and Clancy, P. (2017) Nucleation and Growth of 2D Covalent Organic Frameworks: Polymerization and Crystallization of COF Monomers. Physical Chemis-try Chemical Physics, 19, 9745-9754. [Google Scholar] [CrossRef] 
[18] Wei, P.-F., Qi, M.-Z., Wang, Z.-P., et al. (2018) Benzoxazole-Linked Ultrastable Covalent Organic Frameworks for Photocatalysis. Journal of the American Chemical Society, 140, 4623-4631. [Google Scholar] [CrossRef] [PubMed]
[19] Kuchenbuch, A. and Giernoth, R. (2015) Ionic Liquids beyond Simple Solvents: Glimpses at the State of the Art in Organic Chemistry. ChemistryOpen, 4, 677-681. [Google Scholar] [CrossRef] [PubMed]
[20] Maschita, J., Banerjee, T., Savasci, G., et al. (2020) Ionothermal Synthesis of Imide-Linked Covalent Organic Frameworks. Angewandte Chemie International Edition, 59, 15750-15758. [Google Scholar] [CrossRef] [PubMed]
[21] Yang, Q., Luo, M., Liu, K., et al. (2020) Covalent Organic Frame-works for Photocatalytic Applications. Applied Catalysis B-Environmental, 276, Article ID: 119174. [Google Scholar] [CrossRef] 
[22] Campbell, N.L., Clowes, R., Ritchie, L.K., et al. (2009) Rapid Microwave Synthesis and Purification of Porous Covalent Organic Frameworks. Chemistry of Materials, 21, 204-206. [Google Scholar] [CrossRef] 
[23] Wei, H., Chai, S., Hu, N., et al. (2015) The Microwave-Assisted Sol-vothermal Synthesis of a Crystalline Two-Dimen- sional Covalent Organic Framework with High CO2 Capacity. Chem-ical Communications, 51, 12178-12181. [Google Scholar] [CrossRef] 
[24] Lyu, H., Gao, B., He, F., et al. (2017) Ball-Milled Carbon Nanomateri-als for Energy and Environmental Applications. ACS Sustainable Chemistry & Engineering, 5, 9568-9585. [Google Scholar] [CrossRef] 
[25] Biswal, B.P., Chandra, S., Kandambeth, S., et al. (2013) Mechanochemical Synthesis of Chemically Stable Isoreticular Covalent Organic Frameworks. Journal of the American Chemical Society, 135, 5328-5331. [Google Scholar] [CrossRef] [PubMed]
[26] Shinde, D.B., Aiyappa, H.B., Bhadra, M., et al. (2016) A Mechanochemi-cally Synthesized Covalent Organic Framework as a Proton-Conducting Solid Electrolyte. Journal of Materials Chemis-try A, 4, 2682-2690. [Google Scholar] [CrossRef] 
[27] Wen, M., Lu, S., Fan, C., et al. (2021) Covalent Organic Framework Supported Pd(II)-Catalyzed Conjugate Additions of Arylboronic Acids to α,β-Unsaturated Carboxylic Acids. Applied Organometallic Chemistry, 35, e6263. [Google Scholar] [CrossRef] 
[28] Liu, Y., Han, W.-K., Chi, W., et al. (2023) One-Dimensional Covalent Or-ganic Frameworks with Atmospheric Water Harvesting for Photocatalytic Hydrogen Evolution from Water Vapor. Ap-plied Catalysis B: Environmental, 338, Article ID: 123074. [Google Scholar] [CrossRef] 
[29] Wang, F.D., Yang, L.J., Wang, X.X., et al. (2023) Pyra-zine-Functionalized Donor-Acceptor Covalent Organic Frameworks for Enhanced Photocatalytic H2 Evolution with High Proton Transport. Small, 19, Article ID: 2207421. [Google Scholar] [CrossRef] [PubMed]
[30] Stegbauer, L., Schwinghammer, K. and Lotsch, B.V. (2014) A Hy-drazone-Based Covalent Organic Framework for Photocatalytic Hydrogen Production. Chemical Science, 5, 2789-2793. [Google Scholar] [CrossRef] 
[31] Vyas, V.S., Haase, F., Stegbauer, L., et al. (2015) A Tunable Azine Covalent Organic Framework Platform for Visible Light-Induced Hydrogen Generation. Nature Communications, 6, Ar-ticle No. 8508. [Google Scholar] [CrossRef] [PubMed]
[32] Yin, L., Zhao, Y., Xing, Y., et al. (2021) Structure-Property Relation-ship in β-Keto-Enamine-Based Covalent Organic Frameworks for Highly Efficient Photocatalytic Hydrogen Production. Chemical Engineering Journal, 419, Article ID: 129984. [Google Scholar] [CrossRef] 
[33] Ma, S., Deng, T., Li, Z., et al. (2022) Photocatalytic Hydrogen Production on a Sp2-Carbon-Linked Covalent Organic Frame-work. Angewandte Chemie International Edition, 61, e202208919. [Google Scholar] [CrossRef] [PubMed]
[34] Huang, W., Luo, W. and Li, Y. (2020) Two-Dimensional Semicon-ducting Covalent Organic Frameworks for Photocatalytic Solar Fuel Production. Materials Today, 40, 160-172. [Google Scholar] [CrossRef] 
[35] Li, J., Zhao, D., Liu, J., et al. (2020) Covalent Organic Frame-works: A Promising Materials Platform for Photocatalytic CO2 Reductions. Molecules, 25, Article No. 2425. [Google Scholar] [CrossRef] [PubMed]
[36] Peng, L., Chang, S., Liu, Z., et al. (2021) Visible-Light-Driven Photocatalytic CO2 Reduction over Ketoenamine-Based Covalent Organic Frameworks: Role of the Host Functional Groups. Catalysis Science & Technology, 11, 1717-1724. [Google Scholar] [CrossRef] 
[37] Fu, Y., Zhu, X., Huang, L., et al. (2018) Azine-Based Covalent Or-ganic Frameworks as Metal-Free Visible Light Photocatalysts for CO2 Reduction with H2O. Applied Catalysis B-Environmental, 239, 46-51. [Google Scholar] [CrossRef] 
[38] Li, J., Liu, P., Huang, H., et al. (2020) Metal-Free 2D/2D Black Phosphorus and Covalent Triazine Framework Heterostructure for CO2 Photoreduction. ACS Sustainable Chemistry & Engineering, 8, 5175-5183. [Google Scholar] [CrossRef] 
[39] Chen, X., Dang, Q., Sa, R., et al. (2020) Integrating Single Ni Sites into Biomimetic Networks of Covalent Organic Frameworks for Selective Photoreduction of CO2. Chemical Science, 11, 6915-6922. [Google Scholar] [CrossRef] 
[40] Lei, K., Wang, D., Ye, L., et al. (2020) A Metal-Free Donor-Acceptor Covalent Organic Framework Photocatalyst for Visible-Light-Driven Reduction of CO2 with H2O. ChemSusChem, 13, 1725-1729. [Google Scholar] [CrossRef] [PubMed]
[41] Cui, J.-X., Wang, L.-J., Feng, L., et al. (2021) A Metal-Free Covalent Organic Framework as a Photocatalyst for CO2 Reduction at Low CO2 Concentration in a Gas-Solid System. Journal of Materials Chemistry A, 9, 24895-24902. [Google Scholar] [CrossRef] 
[42] He, J., Wang, X., Jin, S., et al. (2022) 2D Metal-Free Heterostructure of Covalent Triazine Framework/G-C3N4 for Enhanced Photocatalytic CO2 Reduction with High Selectivity. Chinese Journal of Catalysis, 43, 1306-1315. [Google Scholar] [CrossRef] 
[43] Chakrabortty, P., Ghosh, S., Das, A., et al. (2022) Visi-ble-Light-Driven Sustainable Conversion of Carbon Dioxide to Methanol Using a Metal-Free Covalent Organic Frame-work as a Recyclable Photocatalyst. Catalysis Science & Technology, 12, 3484-3497. [Google Scholar] [CrossRef] 
[44] Yadav, R.K., Kumar, A., Park, N.-J., et al. (2016) A Highly Efficient Covalent Organic Framework Film Photocatalyst for Selective Solar Fuel Production from CO2. Journal of Materials Chemistry A, 4, 9413-9418. [Google Scholar] [CrossRef] 
[45] Ran, L., Li, Z., Ran, B., et al. (2022) Engineering Single-Atom Active Sites on Covalent Organic Frameworks for Boosting CO2 Photoreduction. Journal of the American Chemical Society, 144, 17097-17109. [Google Scholar] [CrossRef] [PubMed]
[46] Niu, F., Tao, L., Deng, Y., et al. (2014) A Covalent Triazine Framework as an Efficient Catalyst for Photodegradation of Methylene Blue Under Visible Light Illumination. New Journal of Chemistry, 38, 5695-5699. [Google Scholar] [CrossRef] 
[47] Guan, X., Li, H., Ma, Y., et al. (2019) Chemically Stable Polyaryleth-er-Based Covalent Organic Frameworks. Nature Chemistry, 11, 587-594. [Google Scholar] [CrossRef] [PubMed]
[48] Ma, S., Li, Z., Jia, J., et al. (2021) Amide-Linked Covalent Or-ganic Frameworks as Efficient Heterogeneous Photocatalysts in Water. Chinese Journal of Catalysis, 42, 2010-2019. [Google Scholar] [CrossRef] 
[49] Cui, F.Z., Liang, R.R., Qi, Q.Y., et al. (2019) Efficient Re-moval of Cr(VI) from Aqueous Solutions by a Dual-Pore Covalent Organic Framework. Advanced Sustainable Systems, 3, Article ID: 1800150. [Google Scholar] [CrossRef] 
[50] Gong, Y.-N., Guan, X. and Jiang, H.-L. (2023) Covalent Organic Frameworks for Photocatalysis: Synthesis, Structural Features, Fundamentals and Performance. Coordination Chemistry Reviews, 475, Article ID: 214889. [Google Scholar] [CrossRef] 
[51] Li, H., Wang, L. and Yu, G. (2021) Covalent Organic Frameworks: Design, Synthesis, and Performance for Photocatalytic Applications. Nano Today, 40, Article ID: 101247. [Google Scholar] [CrossRef] 
[52] Shang, P., Yan, X., Li, Y., et al. (2023) Heterogeneous Photo-catalytic Borylation of Aryl Iodides Mediated by Isoreticular 2D Covalent Organic Frameworks. Chinese Chemical Let-ters, 34, Article ID: 107584. [Google Scholar] [CrossRef] 
[53] Liu, H., Li, C., Li, H., et al. (2020) Structural Engineering of Two-Dimensional Covalent Organic Frameworks for Visible-Light-Driven Organic Transformations. ACS Applied Ma-terials & Interfaces, 12, 20354-20365. [Google Scholar] [CrossRef] [PubMed]
[54] Li, Q., Lan, X., An, G., et al. (2020) Visible-Light-Responsive An-thraquinone Functionalized Covalent Organic Frameworks for Metal-Free Selective Oxidation of Sulfides: Effects of Morphology and Structure. ACS Catalysis, 10, 6664-6675. [Google Scholar] [CrossRef] 
[55] Xiong, K., Wang, Y., Zhang, F., et al. (2023) Linker Length-Dependent Photocatalytic Activity of β-Ketoenamine Covalent Organic Frameworks. Applied Catalysis B: Environmental, 322, Article ID: 122135. [Google Scholar] [CrossRef] 

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