二维MFI分子筛的合成方法及优化合成条件的研究进展
Research Progress on Synthesis Methods and Optimization of Synthesis Conditions of Two-Dimensional MFI Molecular Sieves
DOI: 10.12677/MS.2024.142024, PDF,   
作者: 李 毅:浙江师范大学含氟新材料研究所,浙江 金华
关键词: MFI型沸石二维合成成本 MFI Zeolites Two-Dimensional Synthesis Cost
摘要: 与三维块状MFI沸石相比,二维MFI沸石具有更大的表面积、更短的扩散距离和更灵活的结构,不同取向的MFI沸石分子筛膜具有不同的分离效果,在催化方面具有更大的优势。在二维MFI沸石的合成中,具有亲水和疏水基团的双功能模板起着重要作用。不同基团和不同链长的模板剂对合成的二维沸石的形貌和催化性能有重要影响。本文基于近年来二维MFI沸石的研究现状,介绍了层状MFI沸石的合成方法以及如何降低合成模板剂的成本和优化纳米片合成时间进行了讨论,并展望了未来的发展机遇和挑战。
Abstract: Compared with three-dimensional bulk MFI zeolite, two-dimensional MFI zeo-lite has larger surface area, shorter diffusion distance and more flexible structure. Different orientations of MFI zeolite molecular sieve membranes have different separation effects and have greater advantages in catalysis. In the synthesis of two-dimensional MFI zeolite, bifunctional templates with hydrophilic and hydrophobic groups play an important role. Template agents with different groups and different chain lengths have important effects on the morphology and catalytic performance of the synthesized two-dimensional zeolite. Based on the research status of two-dimensional MFI zeo-lite in recent years, this paper introduces the synthesis method of layered MFI zeolite, discusses how to reduce the cost of template synthesis and optimize the synthesis time of nanosheets, and looks forward to the future development opportunities and challenges.
文章引用:李毅. 二维MFI分子筛的合成方法及优化合成条件的研究进展[J]. 材料科学, 2024, 14(2): 208-216. https://doi.org/10.12677/MS.2024.142024

参考文献

[1] Čejka, J., Centi, G., Perez-Pariente, J. and Roth, W.J. (2012) Zeolite-Based Materials for Novel Catalytic Applications: Opportunities, Perspectives and Open Problems. Catalysis Today, 179, 2-15. [Google Scholar] [CrossRef
[2] Corma, A. (1995) Inorganic Solid Acids and Their Use in Ac-id-Catalyzed Hydrocarbon Reactions. Chemical Reviews, 95, 559-614. [Google Scholar] [CrossRef
[3] Tanabe, K. and Hölderich, W.F. (1999) Industrial Application of Solid Acid-Base Catalysts. Applied Catalysis A: General, 181, 399-434. [Google Scholar] [CrossRef
[4] Tatsumi, T. (2009) Metal-Substituted Zeolites as Heteroge-neous Oxidation Catalysts. In: Mizuno, Ed., N., Modern Heterogeneous Oxidation Catalysis: Design, Reactions and Characterization, Wiley, New York, 125-155. [Google Scholar] [CrossRef
[5] Kokotailo, G.T., Lawton, S.L., Olson, D.H. and Meier, W.M. (1978) Structure of Synthetic Zeolite ZSM-5. Nature, 272, 437-438. [Google Scholar] [CrossRef
[6] Liu, G., Liu, J., He, N., et al. (2018) Silicalite-1 Zeolite Acidification by Zinc Modification and Its Catalytic Properties for Isobu-tane Conversion. RSC Advances, 8, 18663-18671. [Google Scholar] [CrossRef
[7] Wu, L., Degirmenci, V., Magusin, P.C.M.M., et al. (2012) Dual Template Synthesis of a Highly Mesoporous SSZ-13 Zeolite with Improved Stability in the Methanol-to-Olefins Reaction. Chemical Communications, 48, 9492-9494. [Google Scholar] [CrossRef] [PubMed]
[8] Moliner, M. and Corma, A. (2014) Advances in the Synthesis of Titano-silicates: From the Medium Pore TS-1 Zeolite to Highly-Accessible Ordered Materials. Microporous and Mesoporous Materials, 189, 31-40. [Google Scholar] [CrossRef
[9] Peng, P., Gao, X.H., Yan, Z.F., et al. (2020) Diffusion and Catalyst Efficiency in Hierarchical Zeolite Catalysts. National Science Review, 7, 1726-1742. [Google Scholar] [CrossRef] [PubMed]
[10] Vuong, G.T. and Do, T.O. (2007) A New Route for the Synthesis of Uniform Nanozeolites with Hydrophobic External Surface in Organic Solvent Medium. Journal of the American Chemi-cal Society, 129, 3810-3811. [Google Scholar] [CrossRef] [PubMed]
[11] Serrano, D.P., Aguado, J., Morales, G., et al. (2009) Molecular and Meso- and Macroscopic Properties of Hierarchical Nanocrystalline ZSM-5 Zeolite Prepared by Seed Silanization. Chemistry of Materials, 21, 641-654. [Google Scholar] [CrossRef
[12] Na, K., Jo, C., Kim, J., et al. (2011) Directing Zeolite Structures into Hier-archically Nanoporous Architectures. Science, 333, 328-332. [Google Scholar] [CrossRef] [PubMed]
[13] Li, K., Valla, J. and Garcia-Martinez, J. (2014) Realizing the Commercial Potential of Hierarchical Zeolites: New Opportunities in Catalytic Cracking. ChemCatChem, 6, 46-66. [Google Scholar] [CrossRef
[14] Valtchev, V. and Tosheva, L. (2013) Porous Nanosized Particles: Preparation, Properties, and Applications. Chemical Reviews, 113, 6734-6760. [Google Scholar] [CrossRef] [PubMed]
[15] Wang, H. and Pinnavaia, T.J. (2006) MFI Zeolite with Small and Uniform Intracrystal Mesopores. Angewandte Chemie, 118, 7765-7768. [Google Scholar] [CrossRef
[16] Roth, W.J. and Čejka, J. (2011) Two-Dimensional Zeolites: Dream or Reality? Catalysis Science & Technology, 1, 43-53. [Google Scholar] [CrossRef
[17] Roth, W.J., Nachtigall, P., Morris, R.E. and Čejka, J. (2014) Two-Dimensional Zeolites: Current Status and Perspectives. Chemical Reviews, 114, 4807-4837. [Google Scholar] [CrossRef] [PubMed]
[18] Choi, M., Na, K., Kim, J., et al. (2009) Stable Sin-gle-Unit-Cell Nanosheets of Zeolite MFI as Active and Long-Lived Catalysts. Nature, 461, 246-249. [Google Scholar] [CrossRef] [PubMed]
[19] Xu, D.D., Jing, Z.F., Cao, F.L., Sun, H. and Che, S.N. (2014) Surfac-tants with Aromatic-Group Tail and Single Quaternary Ammonium Head for Directing Single-Crystalline Mesostructured Zeolite Nanosheets. Chemistry of Materials, 26, 4612-4619. [Google Scholar] [CrossRef
[20] Xu, D., Ma, Y., et al. (2014) π-π Interaction of Aromatic Groups in Amphiphilic Molecules Directing for Single- Crystalline Mesostructured Zeolite Nanosheets. Nature Communications, 5, Article No. 4262. [Google Scholar] [CrossRef] [PubMed]
[21] 刘晓玲, 姜健准, 张明森. 纳米薄片MFI结构分子筛合成的研究进展[J]. 石油化工, 2016, 45(1): 113-120. [Google Scholar] [CrossRef
[22] Machoke, A.G., Knoke, I.Y., Lopez-Orozco, S., et al. (2014) Synthesis of Multilamellar MFI-Type Zeolites under Static Conditions: The Role of Gel Composition on Their Properties. Microporous and Mesoporous Materials, 190, 324-333. [Google Scholar] [CrossRef
[23] Na, K., Choi, M., Park, W., et al. (2010) Pillared MFI Zeo-lite Nanosheets of a Single-Unit-Cell Thickness. Journal of the American Chemical Society, 132, 4169-4177. [Google Scholar] [CrossRef] [PubMed]
[24] Kim, W., Zhang, X., Lee, J, S., et al. (2012) Epitaxially Grown Layered MFI—Bulk MFI Hybrid Zeolitic Materials. ACS Nano, 6, 9978-9988. [Google Scholar] [CrossRef] [PubMed]
[25] Yamamoto, K., Garcia, S.E.B., Saito, F. and Muramatsu, A. (2006) Syn-thesis of Titanosilicate Zeolite from Bulk Titania via Mechanochemical Route. Chemistry Letters, 35, 570-571. [Google Scholar] [CrossRef
[26] Na, K., Jo, C., Kim, J., et al. (2011) MFI Titanosilicate Nanosheets with Single-Unit-Cell Thickness as an Oxidation Catalyst Using Peroxides. ACS Catalysis, 1, 901-907. [Google Scholar] [CrossRef
[27] Wang, J., Xu, L., Zhang, K., et al. (2012) Multilayer Structured MFI-Type Titanosilicate: Synthesis and Catalytic Properties in Selective Epoxidation of Bulky Molecules. Journal of Catalysis, 288, 16-23. [Google Scholar] [CrossRef
[28] Ding, H., Ni, X., Zhang, Y., et al. (2017) Synthesis of B-Oriented MFI Nanosheets with High-Aspect Ratio by Suppressing Intergrowth with 2D GO Nanosheets. CrystEngComm, 19, 3263-3270. [Google Scholar] [CrossRef
[29] Goesten, M.G., Zhu, X., Mezari, B. and Hensen, E.J.M. (2017) On Layered Silicates and Zeolitic Nanosheets. Angewandte Chemie International Edition, 56, 5160-5163. [Google Scholar] [CrossRef] [PubMed]
[30] Zhou, X., Chen, H., Zhu, Y., et al. (2013) Dual-Mesoporous ZSM-5 Zeolite with Highly B-Axis-Oriented Large Mesopore Channels for the Production of Benzoin Ethyl Ether. Chemistry: A European Journal, 19, 10017-10023. [Google Scholar] [CrossRef] [PubMed]
[31] Zhu, X., Rohling, R., Filonenko, G., et al. (2014) Synthesis of Hier-archical Zeolites Using an Inexpensive Mono- Quaternary Ammonium Surfactant as Mesoporogen. Chemical Commu-nications, 50, 14658-14661. [Google Scholar] [CrossRef
[32] Liu, M., Li, J., Jia, W., et al. (2015) Seed-Induced Synthesis of Hierar-chical ZSM-5 Nanosheets in the Presence of Hexadecyltrimethyl Ammonium Bromide. RSC Advances, 5, 9237-9240. [Google Scholar] [CrossRef
[33] Shan, Z., Wang, H., Meng, X., et al. (2010) Designed Synthesis of TS-1 Crystals with Controllable B-Oriented Length. Chemical Communications, 47, 1048-1050. [Google Scholar] [CrossRef
[34] Liu, Y., Zhou, X., Pang, X., et al. (2013) Improved Para-Xylene Selec-tivity in Meta-Xylene Isomerization over ZSM-5 Crystals with Relatively Long B-Axis Length. ChemCatChem, 5, 1517-1523. [Google Scholar] [CrossRef
[35] Zhang, L., Song, Y., Li, G., et al. (2015) F-Assisted Synthesis of a Hierarchical ZSM-5 Zeolite for Methanol to Propylene Reaction: AB-Oriented Thinner Dimensional Morphology. RSC Advances, 5, 61354-61363. [Google Scholar] [CrossRef
[36] Feng, R., Yan, X., Hu, X., et al. (2020) Phosphorus-Modified B-Axis Oriented Hierarchical ZSM-5 Zeolites for Enhancing Catalytic Performance in a Methanol to Propylene Reaction. Applied Catalysis A: General, 594, Article ID: 117464. [Google Scholar] [CrossRef
[37] Meng, L., Zhu, X., Wannapakdee, W., et al. (2018) A Dual-Templating Synthesis Strategy to Hierarchical ZSM-5 Zeolites as Efficient Catalysts for the Methanol-to-Hydrocarbons Reaction. Journal of Catalysis, 361, 135-142. [Google Scholar] [CrossRef
[38] Park, W., Yu, D., Na, K., et al. (2011) Hierarchically Struc-ture-Directing Effect of Multi-Ammonium Surfactants for the Generation of MFI Zeolite Nanosheets. Chemistry of Ma-terials, 23, 5131-5137. [Google Scholar] [CrossRef
[39] Jo, C., Cho, K., Kim, J., et al. (2014) MFI Zeolite Nanosponges Possessing Uniform Mesopores Generated by Bulk Crystal Seeding in the Hierarchical Surfactant-Directed Synthesis. Chemical Communications, 50, 4175-4177. [Google Scholar] [CrossRef
[40] Chen, Y.H., Han, D.M., Zhang, Q., et al. (2020) In-Situ Synthesis of Hierarchical Lamellar ZSM-5 Zeolite with Enhanced MTP Catalytic Performance by a Facile Seed-Assisted Method. Journal of Porous Materials, 27, 1265-1275. [Google Scholar] [CrossRef
[41] Bian, K., Hou, Z.G., Duan, X.R., et al. (2019) Synthesis and Catalytic Performance of 2D HZSM-5 Nano-Sheet for Ethylbenzene Production from Benzene with Dilute Ethylene. Chemical Journal of Chinese Universities-Chinese, 40, 784-792.
[42] Li, X., Prins, R. and Van Bokhoven, J.A. (2009) Synthesis and Characterization of Mesoporous Mordenite. Journal of Catalysis, 262, 257-265. [Google Scholar] [CrossRef
[43] Naranov, E.R., Sadovnikov, A.A., Vatsouro, I.M. and Maximov, A.L. (2020) The Mechanism of Promoter-Induced Zeolite Nanosheet Crystallization under Hydrothermal and Microwave Irradiation Conditions. Inorganic Chemistry Frontiers, 7, 1400-1410. [Google Scholar] [CrossRef