Ti/RuO2电极高效降解RB19染料废水的研究
Study on Efficient Degradation of RB19 Dye Wastewater by Ti/RuO2 Electrode
摘要: 蒽醌染料产量大,用途广泛,结构中含有毒性较大的基团,一旦流入水环境中,对动植物的生长发育和人类的器官功能造成不可逆转的伤害。本文采用循环伏安法研究了活性蓝19 (RB19)在Ti/RuO2电极上的电化学氧化行为。此外,探究了以Ti/RuO2电极作为阳极电化学降解RB19模拟废水的最佳工艺参数。实验结果表明,在最佳条件下,RB19脱色率为80.8%,CODCr去除率为31.2%。Ti/RuO2电极对RB19的电化学降解效率较高,是一种理想的电极材料。
Abstract: Anthraquinone dye has large yield, widely used, and contains more toxic groups in its structure. Once it flows into the water environment, it causes irreversible damage to the growth and development of plants and animals and people’s organ functions. The electrochemical oxidation behavior of reactive blue 19 (RB19) on Ti/RuO2 electrode was studied by cyclic voltammetry. In addition, the optimum process parameters of electrochemical degradation of RB19 simulated wastewater using Ti/RuO2 electrode as anode were investigated. The results showed that the decolorization rate of RB19 was 80.8% and the removal rate of CODCr was 31.2%. Ti/RuO2 electrode had high electrochemical degradation efficiency for RB19 and was an ideal electrode material.
文章引用:陈琳, 李阳, 黄心睿, 张歌, 高晶, 明银安, 王营茹. Ti/RuO2电极高效降解RB19染料废水的研究[J]. 材料化学前沿, 2024, 12(2): 95-102. https://doi.org/10.12677/amc.2024.122013

参考文献

[1] Collivignarelli, M.C., Abba, A., Miino, M.C., et al. (2019) Treatments for Color Removal from Wastewater: State of the Art. Journal of Environmental Management, 236, 727-745. [Google Scholar] [CrossRef] [PubMed]
[2] Routoula, E. and Patwardhan, S.V. (2020) Degradation of Anthraquinone Dyes from Effluents: A Review Focusing on Enzymatic Dye Degradation with Industrial Potential. Environmental Science & Technology, 54, 647-664. [Google Scholar] [CrossRef] [PubMed]
[3] Jawad, A.H., Abdulhameed, A.S., Surip, S.N., et al. (2023) Hybrid Multifunctional Biocomposite of Chitosan Grafted Benzaldehyde/Montmorillonite/Algae for Effective Removal of Brilliant Green and Reactive Blue 19 Dyes: Optimization and Adsorption Mechanism. Journal of Cleaner Production, 393, Article ID: 136334. [Google Scholar] [CrossRef
[4] Cheng, S., Zhang, L., Xia, H., et al. (2017) Characterization and Adsorption Properties of La and Fe Modified Activated Carbon for Dye Wastewater Treatment. Green Processing and Synthesis, 6, 487-498. [Google Scholar] [CrossRef
[5] Li, C.J., Zhang, Y.J., Chen, H., et al. (2022) Development of Porous and Reusable Geopolymer Adsorbents for Dye Wastewater Treatment. Journal of Cleaner Production, 348, Article ID: 131278. [Google Scholar] [CrossRef
[6] Bilal, M., Rasheed, T., Iqbal, H.M.N., et al. (2018) Photocatalytic Degradation, Toxicological Assessment and Degradation Pathway of CI Reactive Blue 19 Dye. Chemical Engineering Research & Design, 129, 384-390. [Google Scholar] [CrossRef
[7] Mahmoodi, N.M., Keshavarzi, S. and Ghezelbash, M. (2017) Synthesis of Nanoparticle and Modelling of Its Photocatalytic Dye Degradation Ability from Colored Wastewater. Journal of Environmental Chemical Engineering, 5, 3684-3689. [Google Scholar] [CrossRef
[8] Zhang, J., Yu, H., Quan, X., et al. (2016) Ceramic Membrane Separation Coupled with Catalytic Ozonation for Tertiary Treatment of Dyestuff Wastewater in a Pilot-Scale Study. Chemical Engineering Journal, 301, 19-26. [Google Scholar] [CrossRef
[9] Xie, X., Zheng, X., Yu, C., et al. (2019) Highly Efficient Biodegradation of Reactive Blue 19 under the Activation of Tea Residue by a Newly Screened Mixed Bacterial Flora DDMY2. RSC Advances, 9, 24791-24801. [Google Scholar] [CrossRef
[10] Srinivasan, S. and Sadasivam, S.K. (2021) Biodegradation of Textile Azo Dyes by Textile Effluent Non-Adapted and Adapted Aeromonas Hydrophila. Environmental Research, 194, Article ID: 110643. [Google Scholar] [CrossRef] [PubMed]
[11] Lyu, J., Han, H., Wu, Q., et al. (2019) Enhancement of the Electrocatalytic Oxidation of Dyeing Wastewater (Reactive Brilliant Blue KN-R) over the Ce-Modified Ti-PbO2 Electrode with Surface Hydrophobicity. Journal of Solid State Electrochemistry, 23, 847-859. [Google Scholar] [CrossRef
[12] Mei, R.Q., Wei, Q.P., Zhu, C.W., et al. (2019) 3D Macroporous Boron-Doped Diamond Electrode with Interconnected Liquid Flow Channels: A High-Efficiency Electrochemical Degradation of RB-19 Dye Wastewater under Low Current. Applied Catalysis B: Environmental, 245, 420-427. [Google Scholar] [CrossRef
[13] Irikura, K., Bocchi, N., Rocha-Filho, R.C., et al. (2016) Electrodegradation of the Acid Green 28 Dye Using Ti/Beta-PbO2 and Ti-Pt/Beta-PbO2 Anodes. Journal of Environmental Management, 183, 306-313. [Google Scholar] [CrossRef] [PubMed]
[14] Umukoro, E.H., Peleyeju, M.G., Ngila, J.C., et al. (2017) Towards Wastewater Treatment: Photo-Assisted Electrochemical Degradation of 2-Nitrophenol and Orange II Dye at a Tungsten Trioxide Exfoliated Graphite Composite Electrode. Chemical Engineering Journal, 317, 290-301. [Google Scholar] [CrossRef
[15] Orts, F., Del Rio, A.I., Molina, J., et al. (2018) Electrochemical Treatment of Real Textile Wastewater: Trichromy Procion HEXL (R). Journal of Electroanalytical Chemistry, 808, 387-394. [Google Scholar] [CrossRef
[16] Rodríguez-Narváez, O.M., Picos, A.R., Bravo-Yumi, N., et al. (2021) Electrochemical Oxidation Technology to Treat Textile Wastewaters. Current Opinion in Electrochemistry, 29, Article ID: 100806. [Google Scholar] [CrossRef
[17] Goren, A.Y., Recepoglu, Y.K., Edebali, O., et al. (2022) Electrochemical Degradation of Methylene Blue by a Flexible Graphite Electrode: Techno-Economic Evaluation. Acs Omega, 7, 32640-32652. [Google Scholar] [CrossRef] [PubMed]
[18] Bezerra Rocha, J.H., Soares Gomes, M.M., Vieira Dos Santos, E., et al. (2014) Electrochemical Degradation of Novacron Yellow C-RG Using Boron-Doped Diamond and Platinum Anodes: Direct and Indirect Oxidation. Electrochimica Acta, 140, 419-426. [Google Scholar] [CrossRef
[19] Degaki, A.H., Pereira, G.F., Rocha, R.C., et al. (2014) Effect of Specific Active Chlorine Species and Temperature on the Electrochemical Degradation of the Reactive Blue 19 Dye Using a Boron-Doped Diamond or DSA Anode in a Flow Reactor. Electrocatalysis, 5, 8-15. [Google Scholar] [CrossRef
[20] Abu Ghalwa, N.M. and Zaggout, F.R. (2006) Electrodegradation of Methylene Blue Dye in Water and Wastewater Using Lead Oxide/Titanium Modified Electrode. Journal of Environmental Science and Health Part A, Toxic/Hazardous Substances & Environmental Engineering, 41, 2271-2282. [Google Scholar] [CrossRef] [PubMed]
[21] Hu, Z., Guo, C., Wang, P., et al. (2022) Electrochemical Degradation of Methylene Blue by Pb Modified Porous SnO2 Anode. Chemosphere, 305, Article ID: 135447. [Google Scholar] [CrossRef] [PubMed]
[22] Elumalai, G., Sowmya, B., Rajan, R.K., et al. (2023) Experimental Study of Photo Electro-Fenton Method for the Removal of Reactive Yellow 186: Influence of Operational Parameters. Environmental Progress & Sustainable Energy, 42, e14061. [Google Scholar] [CrossRef
[23] Cheng, N., Huang, J. and Wang, Y. (2022) Establishment of Electrochemical Treatment Method to Dye Wastewater and Its Application to Real Samples. Main Group Chemistry, 21, 523-537. [Google Scholar] [CrossRef
[24] Wang, Q., Tu, S.Q., Wang, W.Y., et al. (2021) Fabrication of In2O3 Doped PbO2 Anode and Its Application for Electrochemical Degradation of Norfloxacin in Aqueous Solutions. Journal of Environmental Chemical Engineering, 9, Article ID: 106462. [Google Scholar] [CrossRef
[25] Britschgi, J., Bilke, M., Schuhmann, W., et al. (2022) Indirect Electrooxidation of Methane to Methyl Bisulfate on a Boron-Doped Diamond Electrode. Chemelectrochem, 9, e202101253. [Google Scholar] [CrossRef
[26] Roth, H., Gendel, Y., Buzatu, P., et al. (2016) Tubular Carbon Nanotube-Based Gas Diffusion Electrode Removes Persistent Organic Pollutants by a Cyclic Adsorption—Electro-Fenton Process. Journal of Hazardous Materials, 307, 1-6. [Google Scholar] [CrossRef] [PubMed]
[27] Alaoui, A., El Kacemi, K., El Ass, K., et al. (2015) Activity of Pt/MnO2 Electrode in the Electrochemical Degradation of Methylene Blue in Aqueous Solution. Separation and Purification Technology, 154, 281-289. [Google Scholar] [CrossRef
[28] Belal, R.M., Zayed, M.A., El-Sherif, R.M., et al. (2022) Electrochemical Degradation and Degree of Mineralization of the BY28 Dye in a Supporting Electrolyte Mixture Using an Expanded Dimensionally Stable Anode. Electrocatalysis, 13, 26-36. [Google Scholar] [CrossRef