三维集流体实现无枝晶锂金属负极
3D Current Collectors Realizing Dendrite-Free Lithium Metal Anode
DOI: 10.12677/ms.2024.144054, PDF,   
作者: 王 翱：成都大学机械工程学院，四川 成都
关键词: 锂沉积；亲锂性；锂枝晶；3D集流体；Lithium Deposition； Lithiophilicity； Lithium Dendrites； 3D Current Collectors
摘要: 近年来，随着锂空气电池和锂硫电池的快速发展，具有高能量密度的锂金属电池再次受到动力电池研究人员的广泛关注。但是，在电池的循环过程中，锂金属负极存在锂枝晶、体积膨胀以及剧烈的副反应，这会导致电池充放电效率的降低并使得电池存在安全隐患。为了获得稳定的锂金属负极，提出了各种改性策略，例如，电解质添加剂、隔膜改性、人工SEI膜和3D集流体等。其中，集流体的改性直接影响着负极表面结构，并且3D集流体所具有的大的比表面积可以有效地降低局部电流密度，诱导锂的均匀成核与沉积。本文综述了3D集流体改性中具有指导意义的部分研究，旨在为进一步的3D集流体的设计提供参考。
Abstract: In recent years, with the rapid development of lithium-air batteries and lithium-sulfur batteries, lithium-metal batteries with high energy density have once again received extensive attention from power battery researchers. However, during the cycling process of the battery, the lithium metal anode is prone to dendrite formation, volume expansion, and intense side reactions, which can lead to a decrease in the efficiency of charge-discharge cycles and pose safety risks for the battery. To obtain a stable lithium metal anode, various modification strategies have been proposed, such as electrolyte additives, diaphragm modification, artificial SEI, and 3D current collectors. Among them, the modification of the collector directly affects the surface structure of the anode, and the large specific surface area of the 3D current collectors can effectively reduce the local current density and induce the uniform nucleation and deposition of lithium. In this paper, we review some of the instructive research in the modification of 3D collectors, aiming to provide reference for further design 3D collectors.
文章引用：王翱. 三维集流体实现无枝晶锂金属负极[J]. 材料科学, 2024, 14(4): 474-482. https://doi.org/10.12677/ms.2024.144054

参考文献

[1] Armand, M. and Tarascon, J.-M. (2001) Building Better Batteries. Nature, 451, 652-657. [Google Scholar] [CrossRef] [PubMed]
[2] Zhang, X., Wang, A. and Liu, X. (2019) Dendrites in Lithium Metal Anodes: Suppression, Regulation, and Elimination. Accounts of Chemical Research, 52, 3223-3232. [Google Scholar] [CrossRef] [PubMed]
[3] Simon, P., Gogotsi, Y. and Dunn, B. (2014) Where Do Batteries End and Supercapacitors Begin? Science, 343, 1210-1211. [Google Scholar] [CrossRef] [PubMed]
[4] Chen, S., Dai, F. and Cai, M. (2020) Opportunities and Challenges of High-Energy Lithium Metal Batteries for Electric Vehicle Applications. ACS Energy Letters, 5, 3140-3151. [Google Scholar] [CrossRef] 
[5] Yasin, G., Arif, M. and Mehtab, T. (2020) Understanding and Suppression Strategies toward Stable Li Metal Anode for Safe Lithium Batteries. Energy Storage Materials, 25, 644-678. [Google Scholar] [CrossRef] 
[6] Albertus, P., Babinec, S. and Litzelman, S. (2017) Status and Challenges in Enabling the Lithium Metal Electrode for High-Energy and Low-Cost Rechargeable Batteries. Nature Energy, 3, 16-21. [Google Scholar] [CrossRef] 
[7] Xiao, J., Li, Q. and Bi, Y. (2020) Understanding and Applying Coulombic Efficiency in Lithium Metal Batteries. Nature Energy, 5, 561-568. [Google Scholar] [CrossRef] 
[8] Krauskopf, T., Richter, F.H. and Zeier, W.G. (2020) Physicochemical Concepts of the Lithium Metal Anode in Solid-State Batteries. Chemical Reviews, 120, 7745-7794. [Google Scholar] [CrossRef] [PubMed]
[9] Bai, P., Li, J. and Brushett, F.R. (2016) Transition of Lithium Growth Mechanisms in Liquid Electrolytes. Energy & Environmental Science, 9, 3221-3229. [Google Scholar] [CrossRef] 
[10] Lin, D., Liu, Y. and Cui, Y. (2017) Reviving the Lithium Metal Anode for High-Energy Batteries. Nature Nanotechnology, 12, 194-206. [Google Scholar] [CrossRef] [PubMed]
[11] Yang, H., Guo, C. and Naveed, A. (2018) Recent Progress and Perspective on Lithium Metal Anode Protection. Energy Storage Materials, 14, 199-221. [Google Scholar] [CrossRef] 
[12] Zheng, J., Kim, M.S. and Tu, Z. (2020) Regulating Electrodeposition Morphology of Lithium: Towards Commercially Relevant Secondary Li Metal Batteries. Chemical Society Reviews, 49, 271-275. [Google Scholar] [CrossRef] 
[13] Brissot, C., Rosso, M. and Chazalviel, J.-N. (1999) Dendritic Growth Mechanisms in Lithium/Polymer Cells. Journal of Power Sources, 81, 925-929. [Google Scholar] [CrossRef] 
[14] Sand, H.J. (1901) III. On the Concentration at the Electrodes in a Solution, with Special Reference to the Liberation of Hydrogen by Electrolysis of a Mixture of Copper Sulphate and Sulphuric Acid. The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, 1, 45-79. [Google Scholar] [CrossRef] 
[15] Cheng, Y., Chen, J. and Chen, Y. (2021) Lithium Host: Advanced Architecture Components for Lithium Metal Anode. Energy Storage Materials, 38, 276-298. [Google Scholar] [CrossRef] 
[16] Cheng, X.-B., Peng, H.-J. and Huang, J.-Q. (2014) Dendrite-Free Nanostructured Anode: Entrapment of Lithium in a 3D Fibrous Matrix for Ultra-Stable Lithium-Sulfur Batteries. Small, 10, 4257-4263. [Google Scholar] [CrossRef] [PubMed]
[17] Zhang, R., Cheng, X.-B. and Zhao, C.-Z. (2016) Conductive Nanostructured Scaffolds Render Low Local Current Density to Inhibit Lithium Dendrite Growth. Advanced Materials, 28, 2155-2162. [Google Scholar] [CrossRef] [PubMed]
[18] Yuan, H., Ding, X. and Liu, T. (2022) A Review of Concepts and Contributions in Lithium Metal Anode Development. Materials Today, 53, 173-196. [Google Scholar] [CrossRef] 
[19] Wang, J., Lan, D. and Chen, G. (2022) Built-In Stable Lithiophilic Sites in 3D Current Collectors for Dendrite Free Li Metal Electrode. Small, 18, Article 2106718. [Google Scholar] [CrossRef] [PubMed]
[20] Yun, J., Park, B.-K. and Won, E.-S. (2020) Bottom-Up Lithium Growth Triggered by Interfacial Activity Gradient on Porous Framework for Lithium-Metal Anode. ACS Energy Letters, 5, 3108-3114. [Google Scholar] [CrossRef] 
[21] Kim, J., Lee, J. and Yun, J. (2020) Functionality of Dual-Phase Lithium Storage in a Porous Carbon Host for Lithium-Metal Anode. Advanced Functional Materials, 30, Article 1910538. [Google Scholar] [CrossRef] 
[22] Ye, M., Jin, X. and Nan, X. (2020) Paraffin Wax Protecting 3D Non-Dendritic Lithium for Backside-Plated Lithium Metal Anode. Energy Storage Materials, 24, 153-159. [Google Scholar] [CrossRef] 
[23] Yang, C., Yao, Y. and He, S. (2017) Ultrafine Silver Nanoparticles for Seeded Lithium Deposition toward Stable Lithium Metal Anode. Advanced Materials, 29, Article 1702714. [Google Scholar] [CrossRef] [PubMed]
[24] Zhang, R., Li, Y. and Qiao, L. (2021) Atomic Layer Deposition Assisted Superassembly of Ultrathin ZnO Layer Decorated Hierarchical Cu Foam for Stable Lithium Metal Anode. Energy Storage Materials, 37, 123-134. [Google Scholar] [CrossRef] 
[25] Chi, S.-S., Liu, Y. and Song, W.-L. (2017) Prestoring Lithium into Stable 3D Nickel Foam Host as Dendrite-Free Lithium Metal Anode. Advanced Functional Materials, 27, Article 1700348. [Google Scholar] [CrossRef] 
[26] Liu, S., Zhang, H. and Liu, X. (2021) Constructing Nanoporous Ni Foam Current Collectors for Stable Lithium Metal Anodes. Journal of Energy Chemistry, 58, 124-132. [Google Scholar] [CrossRef] 
[27] Yang, C.-P., Yin, Y.-X. and Zhang, S.-F. (2015) Accommodating Lithium into 3D Current Collectors with a Submicron Skeleton towards Long-Life Lithium Metal Anodes. Nature Communications, 6, Article No. 8058. [Google Scholar] [CrossRef] [PubMed]
[28] Lu, B., Olivera, E. and Scharf, J. (2021) Quantitatively Designing Porous Copper Current Collectors for Lithium Metal Anodes. ACS Applied Energy Materials, 4, 6454-6465. [Google Scholar] [CrossRef] 
[29] Li, Q., Zhu, S. and Lu, Y. (2017) 3D Porous Cu Current Collector/Li-Metal Composite Anode for Stable Lithium-Metal Batteries. Advanced Functional Materials, 27, Article 1606422. [Google Scholar] [CrossRef] 
[30] Xie, L., Tang, C. and Bi, Z. (2021) Hard Carbon Anodes for Next-Generation Li-Ion Batteries: Review and Perspective. Advanced Energy Materials, 11, Article 2101650. [Google Scholar] [CrossRef] 
[31] Jiang, X., Chen, Y. and Meng, X. (2022) The Impact of Electrode with Carbon Materials on Safety Performance of Lithium-Ion Batteries: A Review. Carbon, 191, 448-470. [Google Scholar] [CrossRef] 
[32] Man, J., Liu, K. and Zhang, H. (2021) Dendrite-Free Lithium Metal Anode Enabled by Ion/Electron-Conductive N-Doped 3D Carbon Fiber Interlayer. Journal of Power Sources, 489, Article 229524. [Google Scholar] [CrossRef] 
[33] Zhang, R., Chen, X. and Shen, X. (2018) Coralloid Carbon Fiber-Based Composite Lithium Anode for Robust Lithium Metal Batteries. Joule, 2, 764-777. [Google Scholar] [CrossRef] 
[34] Liu, H. (2022) A Flexible Artificial Solid-Electrolyte Interlayer Supported by Compactness-Tailored Carbon Nanotube Network for Dendrite-Free Lithium Metal Anode. Journal of Energy Chemistry, 69, 421-427. [Google Scholar] [CrossRef] 
[35] Sun, B., Li, P. and Zhang, J. (2018) Dendrite-Free Sodium-Metal Anodes for High-Energy Sodium-Metal Batteries. Advanced Materials, 30, Article 1801334. [Google Scholar] [CrossRef] [PubMed]
[36] Cheng, H., Zhang, S. and Mei, J. (2020) Lithiated Carbon Cloth as a Dendrite-Free Anode for High-Performance Lithium Batteries. Sustainable Energy & Fuels, 4, 5773-5782. [Google Scholar] [CrossRef] 
[37] Yan, K., Lu, Z. and Lee, H.-W. (2016) Selective Deposition and Stable Encapsulation of Lithium through Heterogeneous Seeded Growth. Nature Energy, 1, Article No. 16010. [Google Scholar] [CrossRef] 
[38] Fang, R., Han, Z. and Li, J. (2022) Rationalized Design of Hyperbranched Trans-Scale Graphene Arrays for Enduring High-Energy Lithium Metal Batteries. Science Advances, 8, eadc9961. [Google Scholar] [CrossRef] [PubMed]
[39] Liu, K., Kong, B. and Liu, W. (2018) Stretchable Lithium Metal Anode with Improved Mechanical and Electrochemical Cycling Stability. Joule, 2, 1857-1865. [Google Scholar] [CrossRef] 
[40] Zou, P., Wang, Y. and Chiang, S.-W. (2018) Directing Lateral Growth of Lithium Dendrites in Micro-Compartmented Anode Arrays for Safe Lithium Metal Batteries. Nature Communications, 9, Article No. 464. [Google Scholar] [CrossRef] [PubMed]
[41] Huang, G., Han, J. and Zhang, F. (2018) Lithiophilic 3D Nanoporous Nitrogen-Doped Graphene for Dendrite-Free and Ultrahigh-Rate Lithium-Metal Anodes. Advanced Materials, 31, Article 1805334. [Google Scholar] [CrossRef] [PubMed]
[42] Zhang, T., Lu, H. and Yang, J. (2020) Stable Lithium Metal Anode Enabled by a Lithiophilic and Electron/Ion Conductive Framework. ACS Nano, 14, 5618-5627. [Google Scholar] [CrossRef] [PubMed]
[43] Ding, Y., Sun, Y. and Shi, Z. (2023) Bismuthene Arrays Harvesting Reversible Plating-Alloying Electrochemistry toward Robust Lithium Metal Batteries. Small Structures, 4, Article 2200313. [Google Scholar] [CrossRef] 
[44] Kim, H., Jeong, G. and Kim, Y.-U. (2013) Metallic Anodes for Next Generation Secondary Batteries. Chemical Society Reviews, 42, 9011-9034. [Google Scholar] [CrossRef] [PubMed]
[45] Liu, F., Xiao, Q. and Wu, H.B. (2018) Fabrication of Hybrid Silicate Coatings by a Simple Vapor Deposition Method for Lithium Metal Anodes. Advanced Energy Materials, 8, Article 1701744. [Google Scholar] [CrossRef] 
[46] Zhang, R., Wen, S. and Wang, N. (2018) N-Doped Graphene Modified 3D Porous Cu Current Collector toward Microscale Homogeneous Li Deposition for Li Metal Anodes. Advanced Energy Materials, 8, Article 1800914. [Google Scholar] [CrossRef] 
[47] Tian, B., Huang, Z. and Xu, X. (2018) Three-Dimensional Ag/Carbon Nanotube-Graphene Foam for High Performance Dendrite Free Li/Na Metal Anodes. Journal of Materials Science & Technology, 132, 50-58. [Google Scholar] [CrossRef] 
[48] Ke, X., Liang, Y. and Ou, L. (2019) Surface Engineering of Commercial Ni Foams for Stable Li Metal Anodes. Energy Storage Materials, 23, 547-555. [Google Scholar] [CrossRef] 
[49] Xia, Y., Jiang, Y. and Qi, Y. (2019) 3D Stable Hosts with Controllable Lithiophilic Architectures for High-Rate and High-Capacity Lithium Metal Anodes. Journal of Power Sources, 442, Article 227214. [Google Scholar] [CrossRef] 
[50] He, Y., Xu, H. and Shi, J. (2019) Polydopamine Coating Layer Modified Current Collector for Dendrite-Free Li Metal Anode. Energy Storage Materials, 23, 418-426. [Google Scholar] [CrossRef] 
[51] Fan, Y., Liao, J. and Luo, D. (2023) in Situ Formation of a Lithiophilic Surface on 3D Current Collectors to Regulate Lithium Nucleation and Growth for Dendrite-Free Lithium Metal Anodes. Chemical Engineering Journal, 453, Article 139903. [Google Scholar] [CrossRef] 
[52] Qiu, Z., Shen, S. and Liu, P. (2023) Plasma Enhanced Lithium Coupled with Cobalt Fibers Arrays for Advanced Energy Storage. Advanced Functional Materials, 33, Article 2214987. [Google Scholar] [CrossRef] 
[53] Wang, X., Pan, Z. and Wu, Y. (2019) Infiltrating Lithium into Carbon Cloth Decorated with Zinc Oxide Arrays for Dendrite-Free Lithium Metal Anode. Nano Research, 12, 525-529. [Google Scholar] [CrossRef] 
[54] Liu, Y., Lin, D. and Liang, Z. (2016) Lithium-Coated Polymeric Matrix as a Minimum Volume-Change and Dendrite-Free Lithium Metal Anode. Nature Communications. Nature Publishing Group, 7, 1-9. [Google Scholar] [CrossRef] [PubMed]
[55] Wang, L., Yu, Z. and Zhong, Y. (2022) Controllable and Homogeneous Lithium Electrodeposition via Lithiophilic Anchor Points. The Journal of Physical Chemistry Letters, 13, 5977-5985. [Google Scholar] [CrossRef] [PubMed]
[56] Gao, T., Xu, D. and Yu, Z. (2021) A 3D Lithium Metal Anode Reinforced by Scalable In-Situ Copper Oxide Nanostick Copper Mesh. Journal of Alloys and Compounds, 865, Article 158908. [Google Scholar] [CrossRef] 
[57] Ma, P., Zhuang, Z. and Cao, J. (2022) ZnO-CoO Composite Nanosphere Array-Modified Carbon Cloth for Low-Voltage Hysteresis Li Metal Anodes. ACS Applied Energy Materials, 5, 6417-6422. [Google Scholar] [CrossRef] 
[58] Fan, Y., Li, H. and He, X. (2022) In Situ Grown MnO2Nanoflower Arrays on Ni Foam (MnO2@NF) as 3D Lithiophilic Hosts for a Stable Lithium Metal Anode. ACS Applied Energy Materials, 5, 10034-10044. [Google Scholar] [CrossRef] 
[59] Ponraj, R., Yun, J.H. and Wang, J.E. (2022) Regulating Lithium Metal Interface Using Seed-Coating Layer for High-Power Batteries. Chemical Engineering Journal, 433, Article 134380. [Google Scholar] [CrossRef] 

为你推荐