NiFe2O4多层空心磁性粒子的制备与电磁性能
Preparation and Electromagnetic Properties of NiFe2O4 Multilayer Hollow Magnetic Particles
摘要: 本文采用葡萄糖辅助的水热法和不同温度下的热处理制备了NiFe2O4多层空心磁性粒子，并通过透射电镜(TEM)表征其形貌和组成。通过热重分析(TG-DTG)、X射线衍射(XRD)、傅里叶红外光谱(FTIR)、X射线光电子能谱(XPS)研究证实了生成纯相NiFe2O4多层空心粒子。利用振动磁强计研究了NiFe2O4空心粒子的磁性能，随着煅烧温度的升高，饱和磁化强度增大，矫顽力先增大后减小。采用矢量网络分析仪调查研究了NiFe2O4多层空心磁性粒子在2~18 GHz频段的电磁特性，结果显示由于空心多层结构，粒子具有优异的微波吸收性能。结果表明，在5~10 GHz范围内，样品的微波反射损耗低于−10 dB，在7.3 GHz处达到最小值−19 dB。
Abstract: In this paper, NiFe2O4 multilayer hollow magnetic particles were prepared by Glucose-assisted hydrothermal method and heat treatment at different temperatures, and their morphology and composition were characterized by transmission electron microscopy (TEM). The formation of pure NiFe2O4 hollow particles was confirmed by thermogravimetric analysis (TG-DTG), X-ray diffraction (XRD), Fourier infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). The magnetic properties of NiFe2O4 hollow particles are studied by a vibrating magnetometer. With the increase of calcination temperature, the saturation magnetization increases and the coercivity increases first and then decreases. The electromagnetic characteristics of NiFe2O4 multilayer hollow magnetic particles in the 2~18 GHz band were investigated by using a vector network analyzer. The results show that the NiFe2O4 multilayer magnetic particles have excellent microwave absorption properties due to the hollow multilayer structure. The results show that the microwave reflection loss of the sample is lower than −10 dB in the range of 5~10 GHz, and reaches the minimum value of −19 dB at 7.3 GHz.
文章引用：王楠, 夏宇翔, 吴彦川, 周遵宁. NiFe2O4多层空心磁性粒子的制备与电磁性能[J]. 材料科学, 2024, 14(5): 590-601. https://doi.org/10.12677/ms.2024.145066

参考文献

[1] 文连国. 电子对抗系统一体化侦察接收技术研究[D]: [硕士学位论文]. 南京: 东南大学, 2012.[CrossRef] 
[2] Chen, Y., Zhang, J., Li, Y., Zhang, J., Zhang, H, and Zhou, Z. (2021) Energetic and Magnetic Directional Aggregation Properties of KPA@Fe3O4 Composite Particles Prepared via a Microcrystalline Co-Precipitation Route. Nanotechnology, 33, Article ID: 085701. [Google Scholar] [CrossRef] [PubMed]
[3] Kurian, M. and Thankachan, S. (2021) Structural Diversity and Applications of Spinel Ferrite Core-Shell Nanostructures—A Review. Open Ceramics, 8, Article ID: 100179. [Google Scholar] [CrossRef] 
[4] Islam, I., Ali, I.O., et al. (2023) Synthesis of Magnetically Recyclable Spinel Ferrite (MFe2O4, M=Zn, Co, Mn) Nanocrystals Engineered by Sol Gel-Hydrothermal Technology: High Catalytic Performances for Nitroarenes Reduction. Applied Catalysis B: Environmental, 181, 389-402.
[5] Zhang, Y., Jia, C., Wang, Q., Kong, Q., Chen, G., Guan, H. and Dong, C. (2019) MOFs-Derived Porous NiFe2O4 Nano-Octahedrons with Hollow Interiors for an Excellent Toluene Gas Sensor. Nanomaterials, 9, Article 1059. [Google Scholar] [CrossRef] [PubMed]
[6] Duan, H.Z., Zhou, F.L., Cheng, X., Chen, G.H. and Li, Q.L. (2017) Preparation of Hollow Microspheres of Ce3 Doped NiCo Ferrite with High Microwave Absorbing Performance. Journal of Magnetism and Magnetic Materials, 424, 467-471. [Google Scholar] [CrossRef] 
[7] Li, Z.W. and Yang, Z.H. (2015) Microwave Absorption Properties and Mechanism for Hollow Fe3O4 Nanosphere Composites. Journal of Magnetism and Magnetic Materials, 387, 131-138. [Google Scholar] [CrossRef] 
[8] Shu, Y., Zhao, T., Li, X., Yang, L. and Cao, S. (2022) Enhanced Electromagnetic Wave Absorption Properties Integrating Diverse Loss Mechanism of 3D Porous Ni/NiO Microspheres. Journal of Alloys and Compounds, 897, Article ID: 163227. [Google Scholar] [CrossRef] 
[9] Amiri, M., Davarani, S.S.H., Kaverlavani, S.K., Moosavifard, S.E. and Shamsipur, M. (2020) Construction of Hierarchical Nanoporous CuCo2V2O8 Hollow Spheres as a Novel Electrode Material for High-Performance Asymmetric Supercapacitors. Applied Surface Science, 527, Article ID: 146855. [Google Scholar] [CrossRef] 
[10] Wang, C., Ma, Y., Qin, Z., Wang, J. and Zhong, B. (2021) Synthesis of Hollow Spherical MoS2@ Fe3O4-GNs Ternary Composites with Enhanced Microwave Absorption Performance. Applied Surface Science, 569, Article ID: 150812. [Google Scholar] [CrossRef] 
[11] Mi, Y., Hu, W., Dan, Y. and Liu, Y. (2008) Synthesis of Carbon Micro-Spheres by a Glucose Hydrothermal Method. Materials Letters, 62, 1194-1196. [Google Scholar] [CrossRef] 
[12] Cai, H., Lin, X., Qin, Y. and Luo, X. (2017) Hydrothermal Synthesis of Carbon Microsphere from Glucose at Low Temperature and Its Adsorption Property of Uranium (VI). Journal of Radioanalytical and Nuclear Chemistry, 311, 695-706. [Google Scholar] [CrossRef] 
[13] Liu, J., Tian, P., Ye, J., Zhou, L., Gong, W., Lin, Y. and Ning, G. (2009) Hydrothermal Synthesis of Carbon Microspheres from Glucose: Tuning Sphere Size by Adding Oxalic Acid. Chemistry Letters, 38, 948-949. [Google Scholar] [CrossRef] 
[14] He, Q., Yu, Y., Wang, J., Suo, X. and Liu, Y. (2021) Kinetic Study of the Hydrothermal Carbonization Reaction of Glucose and Its Product Structures. Industrial & Engineering Chemistry Research, 60, 4552-4561. [Google Scholar] [CrossRef] 
[15] Zhou, T., Ma, R., Zhou, Y., Xing, R., Liu, Q., Zhu, Y. and Wang, J. (2018) Efficient N-Doping of Hollow Core-Mesoporous Shelled Carbon Spheres via Hydrothermal Treatment in Ammonia Solution for the Electrocatalytic Oxygen Reduction Reaction. Microporous and Mesoporous Materials, 261, 88-97. [Google Scholar] [CrossRef] 
[16] Wang, S., Sun, W., Yang, D.S. and Yang, F. (2019) Conversion of Soybean Waste to Sub-Micron Porous-Hollow Carbon Spheres for Supercapacitor via a Reagent and Template-Free Route. Materials Today Energy, 13, 50-55. [Google Scholar] [CrossRef] 
[17] Shi, X., Wu, Z., Liu, Z., Lv, J., Zi, Z. and Che, R. (2022) Interface Engineering in the Hierarchical Assembly of Carbon-Confined Fe3O4 Nanospheres for Enhanced Microwave Absorption. Journal of Materials Chemistry A, 10, 8807-8816. [Google Scholar] [CrossRef] 
[18] Ischia, G., Cutillo, M., Guella, G., Bazzanella, N., Cazzanelli, M., Orlandi, M. and Fiori, L. (2022) Hydrothermal Carbonization of Glucose: Secondary Char Properties, Reaction Pathways, and Kinetics. Chemical Engineering Journal, 449, Article ID: 137827. [Google Scholar] [CrossRef] 
[19] Yao, Z., Zhang, W. and Yu, X. (2023) Fabricating Porous Carbon Materials by One-Step Hydrothermal Carbonization of Glucose. Processes, 11, Article 1923. [Google Scholar] [CrossRef] 
[20] Srivastava, M., Ojha, A.K., Chaubey, S. and Materny, A. (2009) Synthesis and Optical Characterization of Nanocrystalline NiFe2O4 Structures. Journal of Alloys and Compounds, 481, 515-519. [Google Scholar] [CrossRef] 
[21] Jia, C., Zhang, Y., Kong, Q., et al. (2020) Soft-Template Synthesis of Mesoporous NiFe2O4 for Highly Sensitive Acetone Detection. Journal of Materials Science: Materials in Electronics, 31, 6000-6007. [Google Scholar] [CrossRef] 
[22] Xia, J.Y., Ning, Y., Luo, Y.H., Chen, W., Wu, X.H., et al. (2018) Structural and Magnetic Properties of Soft/Hard NiFe2O4@SrCo0.2Fe11.8O19 Core/Shell Composite Prepared by the Ball-Milling-Assisted Ceramic Process. Journal of Materials Science: Materials in Electronics, 29, 13903-13913.
[23] Hoan, N.T.V., Minh, N.N., Lieu, N.T., Van Thang, N., Nguyen, V.T., Tu, N.T.T. and, Khieu, D.Q. (2021) Nickel Ferrite: Synthesis and Application for Voltammetric Determination of Uric Acid. Journal of Nanoparticle Research, 23, Article No. 23. [Google Scholar] [CrossRef] 
[24] Hua, M., Xu, L., Cui, F., Lian, J., Huang, Y., Bao, J. and Li, H. (2018) Hexamethylenetetramine-Assisted Hydrothermal Synthesis of Octahedral Nickel Ferrite Oxide Nanocrystallines with Excellent Supercapacitive Performance. Journal of Materials Science, 53, 7621-7636. [Google Scholar] [CrossRef] 
[25] Fathy, M.A., Kamel, A.H. and Hassan, S.S. (2022) Novel Magnetic Nickel Ferrite Nanoparticles Modified with Poly (Aniline-Co-O-Toluidine) for the Removal of Hazardous 2,4-Dichlorophenol Pollutant from Aqueous Solutions. RSC Advances, 12, 7433-7445. [Google Scholar] [CrossRef] 
[26] Li, Z., Ye, M., Han, A. and Du, H. (2016) Preparation, Characterization and Microwave Absorption Properties of NiFe2O4 and Its Composites with Conductive Polymer. Journal of Materials Science: Materials in Electronics, 27, 1031-1043. [Google Scholar] [CrossRef] 
[27] Şabikoğlu, İ. and Paralı, L. (2014) FTIR and VSM Properties of Samarium-Doped Nickel Ferrite. Functional Materials Letters, 7, Article ID: 1450046. [Google Scholar] [CrossRef] 
[28] Bala, M., Shivling, V.D. and Tyagi, S. (2024) Tailoring the Characteristics of Nickel Ferrite Based Composite for Tuning the Microwave Absorption Performance. Materials Chemistry and Physics, 312, Article ID: 128630. [Google Scholar] [CrossRef] 
[29] 魏学宾, 李石川, 汤润泽, 等. 新型核壳 Fe@ Fe3O4@TiO2纳米链的合成与性能[J]. 材料科学, 2017, 7(8): 735-744. [Google Scholar] [CrossRef] 
[30] Xiang, N., Zhou, Z., Ma, X., Zhang, H., Xu, X., Chen, Y. and Guo, Z. (2023) The in Situ Preparation of Ni-Zn Ferrite Intercalated Expanded Graphite via Thermal Treatment for Improved Radar Attenuation Property. Molecules, 28, Article 4128. [Google Scholar] [CrossRef] [PubMed]
[31] Han, B., Chu, W., Han, X., Xu, P., Liu, D., Cui, L. and Du, Y. (2020) Dual Functions of Glucose Induced Composition-Controllable Co/C Microspheres as High-Performance Microwave Absorbing Materials. Carbon, 168, 404-414. [Google Scholar] [CrossRef] 

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