原位合成碳化物增强高熵合金微观结构和耐磨损行为研究
Study on Microstructure and Wear Resistance Behavior of In-Situ Synthesized Carbide Reinforced High Entropy Alloy
DOI: 10.12677/ms.2024.145068, PDF,    科研立项经费支持
作者: 韩云飞, 王小荣*:兰州交通大学机电工程学院,甘肃 兰州
关键词: 等离子熔覆技术原位合成显微硬度摩擦磨损Plasma Cladding Technology In-Situ Synthesis Microhardness Frictional Wear
摘要: 选用AlMoZrSi高熵合金粉末和Cr3C2合金粉末作为熔覆原材料。利用等离子熔覆技术在TC11钛合金表面制备原位合成MC型碳化物增强熔覆层,并对其微观组织和物相特征进行表征。此外,还和基体对比研究了显微硬度和耐磨损性能。结果显示:AlMoZrSi(Cr3C2)x (x = 7.5%, 10%)高熵合金熔覆层均由BCC基体相和原位合成的MC型碳化物增强相构成。根据显微硬度和磨损率测试显示:AlMoZrSi(Cr3C2)x (x = 7.5%, 10%)高熵合金的平均显微硬度分别是846.33 HV,1009.27 HV,分别是基体显微硬度390.3 HV的2.17和2.56倍,磨损率分别为2.176 × 107 mm3/N/m和1.979 × 107 mm3/N/m,相较于基体分别提高了19.2%和26.5%。AlMoZrSi(Cr3C2)0.1高熵合金熔覆层具有优异的综合力学性能。
Abstract: AlMoZrSi high entropy alloy powder and Cr3C2 alloy powder were selected as cladding raw materials. The in-situ synthesized MC carbide reinforced cladding layer was prepared on the surface of TC11 titanium alloy by plasma cladding technology, and its microstructure and phase characteristics were characterized. In addition, the microhardness and wear resistance were also studied in comparison with the matrix. Results show: The cladding layers of AlMoZrSi(Cr3C2)x (x = 7.5%, 10%) high-entropy alloys are composed of BCC matrix phase and in-situ synthesized MC-type carbide reinforced phase. According to the microhardness and wear rate test, it is shown that: the average microhardness of AlMoZrSi(Cr3C2)x (x = 7.5%, 10%) high entropy alloys are 846.33 HV and 1009.27 HV, which are 2.17 and 2.56 times of the matrix microhardness 390.3 HV, respectively. The wear rates are 2.176 × 107 mm3/N/m and 1.979 × 107 mm3/N/m, which are 19.2% and 26.5% higher than that of the matrix, respectively. The AlMoZrSi(Cr3C2)0.1 high-entropy alloy cladding layer exhibits excellent comprehensive mechanical properties.
文章引用:韩云飞, 王小荣. 原位合成碳化物增强高熵合金微观结构和耐磨损行为研究[J]. 材料科学, 2024, 14(5): 614-623. https://doi.org/10.12677/ms.2024.145068

参考文献

[1] 张纪奎, 孔祥艺, 马少俊, 等. 激光增材制造高强高韧TC11钛合金力学性能及航空主承力结构应用分析[J]. 航空学报, 2021, 42(10): 460-470.
[2] 吴晓东, 侯智敏, 李浩, 等. TC11钛合金零件组织缺陷分析[J]. 中国金属通报, 2019(2): 115, 117.
[3] Davydova, A., Domashenkov, A., Sova, A., Movtchan, I., et al. (2016) Selective Laser Melting of Boron Carbide Particles Coated by a Cobalt-Based Metal Layer. Journal of Materials Processing Technology, 229, 361-366. [Google Scholar] [CrossRef
[4] Liao, W.-B., Zhang, H., Liu, Z.-Y., et al. (2019) High Strength and Deformation Mechanisms of Al0.3CoCrFeNi High-Entropy Alloy Thin Films Fabricated by Magnetron Sputtering. Entropy, 21, Article 146. [Google Scholar] [CrossRef] [PubMed]
[5] Wang, X., Jiang, K. and Zhou, L. (2015) Characterization and Phase Stability of Pyrochlore (Nd1-xCex)2Zr2O7 y(X=0-1). Journal of Nuclear Materials, 458, 156-161. [Google Scholar] [CrossRef
[6] Xie, Y., Wen, X., Yan, J., et al. (2023) Microstructure and Wear Resistance of AlCoCrFeNiCuSnX High-Entropy Alloy Coatings by Plasma Cladding. Vacuum, 214, Article 112176. [Google Scholar] [CrossRef
[7] Lu, J., Wang, B., Qiu, X., et al. (2017) Microstructure Evolution and Properties of CrCuFexNiTi High-Entropy Alloy Coating by Plasma Cladding on Q235. Surface and Coatings Technology, 328, 313-318. [Google Scholar] [CrossRef
[8] Ding, H., Dai, J., Dai, T., et al. (2020) Effect of Preheating/Post-Isothermal Treatment Temperature on Microstructures and Properties of Cladding on U75V Rail Prepared by Plasma Cladding Method. Surface and Coatings Technology, 399, Article 126122. [Google Scholar] [CrossRef
[9] Yeh, J.-W., Chen, S.-K., Lin, S.-J., et al. (2004) Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes. Advanced Engineering Materials, 6, 299-303. [Google Scholar] [CrossRef
[10] Peng, Y.B., Zhang, W., Li, T.C., et al. (2019) Microstructures and Mechanical Properties of FeCoCrNi High Entropy Alloy/WC Reinforcing Particles Composite Coatings Prepared by Laser Cladding and Plasma Cladding. International Journal of Refractory Metals and Hard Materials, 84, Article 105044. [Google Scholar] [CrossRef
[11] 李想, 赵伟, 潘延瑞, 张辉, 李玲玉. 等离子熔覆WC增强镍基合金涂层组织与性能研究[J]. 齐鲁工业大学学报, 2022, 36(5): 51-54.
[12] Hu, Y., Wang, Z. and Pang, M. (2022) Effect of WC Content on Laser Cladding Ni-Based Coating on the Surface of Stainless Steel. Materials Today Communications, 31, Article 103357.
[13] 张雪, 崔洪芝, 王明亮, 等. Al含量对AlxCoCrFeNi系高熵合金组织和耐蚀性能的影响[J]. 材料热处理学报, 2018, 39(12): 29-36.
[14] 刘谦, 王昕阳, 黄燕滨, 等. Mo含量对CoCrFeNiMo高熵合金组织及耐蚀性能的影响[J]. 材料研究学报, 2020, 34(11): 868-874.
[15] 董琬晴. Zr、Nb元素添加对CoFeMnNi系高熵合金组织结构与性能影响的研究[D]: [硕士学位论文]. 秦皇岛: 燕山大学, 2020.
[16] 张平, 李远田, 张金勇, 等. Si对AlCoCrFeNi高熵合金热腐蚀行为的影响[J]. 稀有金属材料与工程, 2021, 50(10): 3640-3647.
[17] 古艳玲, 陈扬, 安金华, 等. 碳化物陶瓷颗粒对双相高熵合金基复合材料微观组织和力学性能的影响[J]. 复合材料学报, 2023, 40(5): 3047-3059.
[18] Yurchenko, N., Panina, E., Tikhonovsky, M., et al. (2020) Structure and Mechanical Properties of an in situ Refractory Al20Cr10Nb15Ti20V25Zr10 High Entropy Alloy Composite. Materials Letters, 264, Article 127372. [Google Scholar] [CrossRef
[19] Peng, Y., Zhang, W., Li, T., et al. (2020) Effect of WC Content on Microstructures and Mechanical Properties of FeCoCrNi High-Entropy Alloy/WC Composite Coatings by Plasma Cladding. Surface & Coatings Technology, 385, Article 125326. [Google Scholar] [CrossRef
[20] 王虎, 王智慧. 等离子熔覆法制备AlxCoCrFeNi高熵合金微观组织与性能研究[J]. 材料导报, 2018, 32(4): 589-592 597.
[21] 丁林. 激光熔覆Ti-VN合金/Co基复合涂层微观组织结构和性能研究[D]: [博士学位论文]. 天津: 天津大学, 2023.
[22] 张爱军, 韩杰胜, 苏博, 等. AlCoCrFeNi高熵合金的高温摩擦磨损性能[J]. 摩擦学学报, 2017, 37(6): 776-783.
[23] Qunshuang, M., Yajiang, L. and Juan, W. (2017) Effects of Ti Addition on Microstructure Homogenization and Wear Resistance of Wide-Band Laser Clad Ni60/WC Composite Coatings. International Journal of Refractory Metals and Hard Materials, 64, 225-233. [Google Scholar] [CrossRef
[24] 李剑锋, 朱真才, 彭玉兴, 等. 原位合成M23C6-WC双相碳化物协同增强激光熔覆层摩擦磨损行为的研究[J]. 摩擦学学报, 2021, 41(6): 843-857.
[25] Wang, S., Zhang, S., Zhang, C.H., et al. (2017) Effect of Cr3C2 Content on 316 L Stainless Steel Fabricated by Laser Melting Deposition. Vacuum, 147, 92-98. [Google Scholar] [CrossRef