翅片结构对Ca(OH)2/CaO体系热化学储能反应器传热影响的模拟研究
Simulation Study on the Effect of Fin Structure on Heat Transfer in Ca(OH)2/CaO System Thermochemical Energy Storage Reactor
DOI: 10.12677/mos.2024.133227, PDF,   
作者: 马 岩, 梁四凯, 王志远*:上海理工大学能源与动力工程学院,上海;梁凯皓:华东理工大学机械与动力工程学院,上海
关键词: 热化学储能传热Ca(OH)2/CaO体系水解水合数值模拟Thermochemical Energy Storage Heat Transfer Ca(OH)2/CaO System Hydrolysis Hydrate Numerical Simulation
摘要: 热化学储能是实现太阳能光热发电长期稳定使用的有效方法,热化学储能反应器是实现热量存储和释放的核心装置。在热化学储能系统中,能够通过优化热化学储能反应器的结构提高其效率。因此,对储能反应器的性能、结构进行详细考察有助于反应器形式的改进和性能优化。采用COMSOL Multiphysics软件,模拟研究反应器内部载热流体通道内翅片排布对CaO/Ca(OH)2体系储/放热过程的影响。其中,热载体流道侧的流道采用半圆柱型翅片,翅片采用并列与交错两种排布方式。模拟结果表明,在孔隙率为0.5的条件下,水解过程中,对称式翅片反应器与交错式翅片反应器的反应时间大幅减少,相较于板式反应器,减少了27%的反应时间。在水合过程中,交错式翅片反应器相比板式减少7%的反应时间。
Abstract: Thermochemical energy storage is an effective method for achieving long-term stable use of solar thermal power generation, and the thermal chemical energy storage reactor is the core device for achieving heat storage and release. In thermochemical energy storage systems, the efficiency can be improved by optimizing the structure of the thermochemical energy storage reactor. Therefore, a detailed investigation of the performance and structure of energy storage reactors can help improve the reactor form and optimize its performance. Using numerical simulation methods to study the effect of fin arrangement in the heat carrying fluid channel inside the reactor on the heat storage/release process of CaO/Ca(OH)2 system. Among them, the flow channel on the heat carrier channel side adopts semi cylindrical fins, and the fins are arranged in two ways: parallel and staggered. The simulation results indicate that enhancing convective heat transfer capability has different effects in different reaction processes. During the hydrolysis process under the condition of 0.5 porosity, the reaction time of the symmetric and staggered fin reactors was significantly reduced, with a 27% reduction compared to the plate reactor. During the hydration process, the strengthening effect is not as significant as the hydration process, and the staggered fin reactor reduces the reaction time by 7% compared to the plate type. I hope that simulation research can provide guidance for the design and application of finned structure thermochemical energy storage reactors.
文章引用:马岩, 梁四凯, 梁凯皓, 王志远. 翅片结构对Ca(OH)2/CaO体系热化学储能反应器传热影响的模拟研究[J]. 建模与仿真, 2024, 13(3): 2489-2507. https://doi.org/10.12677/mos.2024.133227

参考文献

[1] 邹才能, 马锋, 潘松圻, 等. 论地球能源演化与人类发展及碳中和战略[J]. 石油勘探与开发, 2022, 49(2): 18.
[2] 凌祥, 宋丹阳, 陈晓轶, 等. 钙基热化学储能体系装备与系统研究进展[J]. 化工进展, 2021, 40(4): 1777-1796.
[3] 陈海生, 刘畅, 徐玉杰, 等. 储能在碳达峰碳中和目标下的战略地位和作用[J]. 储能科学与技术, 2021, 10(5): 1477-1485.
[4] 上官小英, 常海青, 梅华强. 太阳能发电技术及其发展趋势和展望[J]. 能源与节能, 2019(3): 60-63.
[5] Tao, W., Mantha, D. and Reddy, R.G. (2012) Thermal Stability of the Eutectic Composition in LiNO3-NaNO3-KNO3 Ternary System Used for Thermal Energy Storage. Solar Energy Materials & Solar Cells, 100, 162-168. [Google Scholar] [CrossRef
[6] 吴玉庭, 任楠, 马重芳. 熔融盐显热蓄热技术的研究与应用进展[J]. 储能科学与技术, 2013, 2(6): 586-592.
[7] Kumar, S., Kojlma, Y. and Kain, V. (2017) Nanoengineered Mg-MgH2 System for Solar Thermal Energy Storage. Solar Energy, 150, 532-537. [Google Scholar] [CrossRef
[8] 赵梦娇, 王登辉, 惠世恩, 等. 利用氧化还原反应储能的储能介质研究进展[J]. 热力发电, 2020, 49(8): 19-28.
[9] 刘彦铄, 王新赫, 张军社, 等. 太阳能甲烷重整反应器研究进展[J]. 化工进展, 2019, 38(12): 5339-5350.
[10] Andre, L. and Abanades, S. (2017) Evaluation and Performances Comparison of Calcium, Strontium and Barium Carbonates during Calcination/Carbonation Reactions for Solar Thermochemical Energy Storage. Journal of Energy Storage, 13, 193-205. [Google Scholar] [CrossRef
[11] Chen, C., Lovegrove, K.M., Sepulveda, A., et al. (2018) Design and Optimization of an Ammonia Synthesis System for Ammoniabased Solar Thermochemical Energy Storage. Solar Energy, 159, 992-1002. [Google Scholar] [CrossRef
[12] Shi, T., Xu, H., Qi, C., et al. (2021) Multi-Physics Modeling of Thermochemical Heat Storage with Enhance Heat Transfer. Applied Thermal Engineering, 198, Article ID: 117508. [Google Scholar] [CrossRef
[13] Khan, M.M.A., Ibbahim, N.I., Mahbubul, I.M., et al. (2018) Evaluation of Solar Collector Designs with Integrated Latent Heat Thermal Energy Storage: A Review. Solar Energy, 166, 334-350. [Google Scholar] [CrossRef
[14] 黄彩凤. 钙基热化学储能材料及反应器性能强化研究[D]: [硕士学位论文]. 北京: 中国科学院大学, 2020.
[15] 薛福, 马晓明, 游焰军. 储能技术类型及其应用发展综述[J]. 综合智慧能源, 2023, 45(9): 48-58.
[16] 曾光, 纪阳, 符津铭, 等. 热储能技术研究现状、热点趋势与应用进展[J]. 中国电机工程学报, 2023, 43(S1): 127-142.
[17] 孙峰, 彭浩, 凌祥. 中高温热化学反应储能研究进展[J]. 储能科学与技术, 2015, 4(6): 577-584.
[18] 顾正萌, 蒋世希, 吴家荣, 等. CaO/Ca(OH)2体系热化学储能应用关键问题的讨论[J]. 电力科技与环保, 2023, 39(4): 285-291.
[19] Desai, F., Jenne, S.P., Muthumar, P., et al. (2021) Thermochemical Energy Storage System for Cooling and Process Heating Applications: A Review. Energy Conversion and Management, 229, Article ID: 113617. [Google Scholar] [CrossRef
[20] 郑玉圆, 葛志伟, 韩翔宇, 等. 中高温钙基材料热化学储能的研究进展与展望[J]. 化工学报, 2023, 74(8): 3171-3192.
[21] 朱曼玲. Ca(OH)2/CaO热化学储能体系的性能研究[D]: [硕士学位论文]. 广州: 华南理工大学, 2021.
[22] 刘旭光. 基于内嵌加热管束反应器的Ca(OH)2/CaO储能系统研究[D]: [硕士学位论文]. 北京: 华北电力大学, 2022.
[23] Carrillo, A.J., Gonzalez, A.J., Romero, M., et al. (2019) Solar Energy on Demand: A Review on High Temperature Thermochemical Heat Storage Systems and Materials. Chemical Reviews, 119, 4777-4816. [Google Scholar] [CrossRef] [PubMed]
[24] Yan, J., Zhao, C.Y., Xia, B.Q., et al. (2019) The Effect of Dehydration Temperatures on the Performance of the CaO/Ca(OH)2 Thermochemical Heat Storage System. Energy, 186, Article ID: 115837. [Google Scholar] [CrossRef
[25] Dai, L., Long, X.F., Lou, B., et al. (2018) Thermal Cycling Stability of Thermochemical Energy Storage System Ca(OH)2/CaO. Applied Thermal Engineering, 133, 261-268. [Google Scholar] [CrossRef
[26] Wang, B., Wang, Z., Ma, Y., et al. (2021) Heat Transfer Enhancement of Indirect Heat Transfer Reactors for Ca(OH)2/CaO Thermochemical Energy Storage System. Processes, 9, Article No. 1136. [Google Scholar] [CrossRef
[27] 张志浩, 靳晓刚, 包恒兴, 等. 混合加热反应器内Ca(OH)2/CaO热化学储能体系实验[J]. 储能科学与技术, 2023, 12(1): 227-235.
[28] 徐其利, 孙杰, 魏进家. Ca(OH)2/CaO热化学储能过程中变孔隙率影响的多物理耦合数值模拟研究[J]. 工程热物理学报, 2023, 44(2): 289-296.
[29] 吴娟. 热化学储能体系Ca(OH)2/CaO H2O的性能研究[D]: [硕士学位论文]. 广州: 华南理工大学, 2015.
[30] 戴溜. Ca(OH)2/CaO体系热化学储热性能研究[D]: [硕士学位论文]. 广州: 华南理工大学, 2018.
[31] 边志国. 基于CaO/Ca(OH)2循环的钙基材料热化学储热性能强化研究[D]: [博士学位论文]. 济南: 山东大学, 2022.
[32] 徐艳. Ca(OH)2/CaO热化学储能体系的性能研究与数值分析[D]: [硕士学位论文]. 广州: 华南理工大学, 2019.