LDH中引入氧空位用于电催化和和超级电容器的研究进展
Progress in the Introduction of Oxygen Vacancies in LDH for Electrocatalysis and Supercapacitors
摘要: 对清洁能源的迫切需求和现代电子技术的快速发展促使人们对绿色能源和新型储能技术的关注越来越多,尤其是电化学水分解和超级电容器。而最重要的是设计具有优良催化和储能性能的电极材料。层状双金属氢氧化物(LDHs)由于其组成、结构和形态的易调性引起了研究人员的强烈兴趣,同时在LDH中引入氧空位以提升其催化和储能性能得到了广泛研究并取得了各种卓有成效的成果。本文综述了电催化和超级电容器用具有氧空位的LDH基电极材料设计和研究的最新进展。从氧空位的形成、氧空位对于电催化和储能性能的提升等方面进行了讨论。通过科学家们的不断努力,富氧空位的LDH基材料的催化性能和储能性能都有了很大的提高,使其在现代应用中更具竞争力。
Abstract: With the urgent demand for clean energy and the rapid development of modern electronic technology, there is increasing attention on green energy and novel energy storage technologies, particularly electrochemical water splitting and supercapacitors. The design of electrode materials with excellent catalytic and energy storage performance is of paramount importance. Layered double hydroxides (LDHs) have attracted strong interest from researchers due to their tunability in composition, structure, and morphology. Meanwhile, the introduction of oxygen vacancies into LDHs to enhance their catalytic and energy storage performance has been widely studied, yielding various effective results. This review summarizes the latest progress in the design and research of LDH-based electrode materials with oxygen vacancies for electrocatalysis and supercapacitors. Discussions are provided on the formation of oxygen vacancies and their enhancement of electrocatalytic and energy storage performance. Through the continuous efforts of scientists, LDH-based materials rich in oxygen vacancies have shown significant improvements in catalytic and energy storage performance, making them more competitive in modern applications.
文章引用:李天鹏. LDH中引入氧空位用于电催化和和超级电容器的研究进展[J]. 物理化学进展, 2024, 13(2): 165-174. https://doi.org/10.12677/japc.2024.132020

参考文献

[1] Sharma, V., Aman, M. and Omar, S. (2022) NiMn-Layered Double Hydroxide Porous Nanoarchitectures as a Bifunctional Material for Accelerated P-Nitrophenol Reduction and Freestanding Supercapacitor Electrodes. ACS Applied Nano Materials, 5, 15651-15664. [Google Scholar] [CrossRef
[2] Yue, Q., Sun, J., Chen, S., Zhou, Y., Li, H., Chen, Y., Zhang, R., Wei, G. and Kang, Y. (2020) Hierarchical Mesoporous MXene-NiCoP Electrocatalyst for Water-Splitting. ACS Applied Materials & Interfaces, 12, 18570-18577. [Google Scholar] [CrossRef] [PubMed]
[3] Han, J., Zhang, J., Wang, T., Xiong, Q., Wang, W., Cao, L. and Dong, B. (2019) Zn Doped FeCo Layered Double Hydroxide Nanoneedle Arrays with Partial Amorphous Phase for Efficient Oxygen Evolution Reaction. ACS Sustainable Chemistry & Engineering, 7, 13105-13114. [Google Scholar] [CrossRef
[4] Xu, Z., Yeh, C.L., Chen, J.L., Lin, J.T., Ho, K.C. and Lin, R.Y.Y. (2022) Metal-Organic Framework-Derived 2D NiCoP Nanoflakes from Layered Double Hydroxide Nanosheets for Efficient Electrocatalytic Water Splitting at High Current Densities. ACS Sustainable Chemistry & Engineering, 10, 11577-11586. [Google Scholar] [CrossRef
[5] Senthil Raja, D., Chuah, X.F. and Lu, S.Y. (2018) In Situ Grown Bimetallic MOF-Based Composite as Highly Efficient Bifunctional Electrocatalyst for Overall Water Splitting with Ultrastability at High Current Densities. Advanced Energy Materials, 8, Article ID: 1801065. [Google Scholar] [CrossRef
[6] Wang, Y., Yan, D., El Hankari, S., Zou, Y. and Wang, S. (2018) Recent Progress on Layered Double Hydroxides and Their Derivatives for Electrocatalytic Water Splitting. Advanced Science, 5, Article ID: 1800064. [Google Scholar] [CrossRef] [PubMed]
[7] Cheng, J. and Wang, D. (2022) 2D Materials Modulating Layered Double Hydroxides for Electrocatalytic Water Splitting. Chinese Journal of Catalysis, 43, 1380-1398. [Google Scholar] [CrossRef
[8] Zhou, J.J., Ji, W., Xu, L., Yang, Y., Wang, W., Ding, H., Xu, X., Wang, W., Zhang, P., Hua, Z. and Chen, L. (2022) Controllable Transformation of CoNi-MOF-74 on Ni Foam into Hierarchical-Porous Co(OH)2/Ni(OH)2 Micro-Rods with Ultra-High Specific Surface Area for Energy Storage. Chemical Engineering Journal, 428, Article ID: 132123. [Google Scholar] [CrossRef
[9] Wu, H., Zhang, X., Xue, J., Zhang, H., Yang, L. and Li, S. (2021) Engineering Active Sites on Hierarchical ZnNi Layered Double Hydroxide Architectures with Rich Zn Vacancies Boosting Battery-Type Supercapacitor Performances. Electrochimica Acta, 374, Article ID: 137932. [Google Scholar] [CrossRef
[10] Wu, Y., Liu, Q., Wang, J., Liu, X. and Zhang, X. (2023) Effectively Morphology-Controlled NiMn Layered Double Hydroxide Microflowers by Conductive Silver Nanowires for Supercapacitor Electrodes. Electrochimica Acta, 460, Article ID: 142623. [Google Scholar] [CrossRef
[11] Jing, C., Dong, B. and Zhang, Y. (2020) Chemical Modifications of Layered Double Hydroxides in the Supercapacitor. Energy & Environmental Materials, 3, 346-379. [Google Scholar] [CrossRef
[12] Tomboc, G.M., Kim, J., Wang, Y., Son, Y., Li, J., Kim, J.Y. and Lee, K. (2021) Hybrid Layered Double Hydroxides as Multifunctional Nanomaterials for Overall Water Splitting and Supercapacitor Applications. Journal of Materials Chemistry A, 9, 4528-4557. [Google Scholar] [CrossRef
[13] Chala, S.A., Tsai, M.C., Su, W.N., Ibrahim, K.B., Thirumalraj, B., Chan, T.S., Lee, J.F., Dai, H. and Hwang, B.J. (2020) Hierarchical 3D Architectured Ag Nanowires Shelled with NiMn-Layered Double Hydroxide as an Efficient Bifunctional Oxygen Electrocatalyst. ACS Nano, 14, 1770-1782. [Google Scholar] [CrossRef] [PubMed]
[14] Jiao, Z., Chen, Y., Du, M., Demir, M., Yan, F., Xia, W., Zhang, Y., Wang, C., Gu, M., Zhang, X. and Zou, J. (2023) 3D Hollow NiCo LDH Nanocages Anchored on 3D CoO Sea Urchin-Like Microspheres: A Novel 3D/3D Structure for Hybrid Supercapacitor Electrodes. Journal of Colloid and Interface Science, 633, 723-736. [Google Scholar] [CrossRef] [PubMed]
[15] Xu, L., Li, Y., Li, M., Yu, N., Wang, W., Wei, F., Qi, J., Sui, Y., Li, L. and Zhang, L. (2024) Mo-Doped NiCo-LDH Nanoflower Derived from ZIF-67 Nanosheet Arrays for High-Performance Supercapacitors. Journal of Energy Storage, 77, Article ID: 109781. [Google Scholar] [CrossRef
[16] Wang, G. and Jin, Z. (2021) Oxygen-Vacancy-Rich Cobalt-Aluminium Hydrotalcite Structures Served as High-Performance Supercapacitor Cathode. Journal of Materials Chemistry C, 9, 620-632. [Google Scholar] [CrossRef
[17] Zhu, Y., Tahini, H.A., Hu, Z., Chen, Z.G., Zhou, W., Komarek, A.C., Lin, Q., Lin, H.J., Chen, C.T., Zhong, Y., Fernández-Díaz, M.T., Smith, S.C., Wang, H., Liu, M. and Shao, Z. (2020) Boosting Oxygen Evolution Reaction by Creating Both Metal Ion and Lattice-Oxygen Active Sites in A Complex Oxide. Advanced Materials, 32, Article ID: 1905025. [Google Scholar] [CrossRef] [PubMed]
[18] Zhong, H., Gao, G., Wang, X., Wu, H., Shen, S., Zuo, W., Cai, G., Wei, G., Shi, Y., Fu, D., Jiang, C., Wang, L.W. and Ren, F. (2021) Ion Irradiation Inducing Oxygen Vacancy-Rich NiO/NiFe2O4 Heterostructure for Enhanced Electrocatalytic Water Splitting. Small, 17, Article ID: 2103501. [Google Scholar] [CrossRef] [PubMed]
[19] Zhang, Y., Zhang, J., Li, G., Leng, D., Wang, W., Gao, Y., Gao, J., Liang, Q., Lu, H. and Wang, C. (2019) Metal-Organic Framework-Derived Porous TiO2 Nanotablets with Sensitive and Selective Ethanol Sensing. Journal of Materials Science: Materials in Electronics, 30, 17899-17906. [Google Scholar] [CrossRef
[20] Zubair, M., Kumar, P., Klingenhof, M., Subhash, B., Yuwono, J.A., Cheong, S., Yao, Y., Thomsen, L., Strasser, P., Tilley, R.D. and Bedford, N.M. (2023) Vacancy Promotion in Layered Double Hydroxide Electrocatalysts for Improved Oxygen Evolution Reaction Performance. ACS Catalysis, 13, 4799-4810. [Google Scholar] [CrossRef
[21] Liu, H., Zhao, D., Liu, Y., Tong, Y., Wu, X. and Shen, G. (2021) NiMoCo Layered Double Hydroxides for Electrocatalyst and Supercapacitor Electrode. Science China Materials, 64, 581-591. [Google Scholar] [CrossRef
[22] Gao, X., Wang, P., Pan, Z., Claverie, J.P. and Wang, J. (2020) Recent Progress in Two-Dimensional Layered Double Hydroxides and Their Derivatives for Supercapacitors. ChemSusChem, 13, 1226-1254. [Google Scholar] [CrossRef] [PubMed]
[23] Yang, S., Liu, Y., Hao, Y., Yang, X., Goddard Iii, W.A., Zhang, X.L. and Cao, B. (2018) Oxygen-Vacancy Abundant Ultrafine Co3O4/Graphene Composites for High-Rate Supercapacitor Electrodes. Advanced Science, 5, Article ID: 1700659. [Google Scholar] [CrossRef] [PubMed]
[24] Ma, Q., Cui, F., Zhang, J., Qi, X. and Cui, T. (2022) Surface Engineering of Co3O4 Nanoribbons Forming Abundant Oxygen-Vacancy for Advanced Supercapacitor. Applied Surface Science, 578, Article ID: 152001. [Google Scholar] [CrossRef
[25] Chen, K., Cao, Y.H., Yadav, S., Kim, G.C., Han, Z., Wang, W., Zhang, W.J., Dao, V. and Lee, I.H. (2023) Electronic Structure Reconfiguration of Nickel-Cobalt Layered Double Hydroxide Nanoflakes Via Engineered Heteroatom and Oxygen-Vacancies Defect for Efficient Electrochemical Water Splitting. Chemical Engineering Journal, 463, Article ID: 142396. [Google Scholar] [CrossRef
[26] He, J., Zhou, X., Xu, P. and Sun, J. (2021) Promoting Electrocatalytic Water Oxidation through Tungsten-Modulated Oxygen Vacancies on Hierarchical FeNi-Layered Double Hydroxide. Nano Energy, 80, Article ID: 105540. [Google Scholar] [CrossRef
[27] Li, C., Li, X.J., Zhao, Z.Y., Li, F.L., Xue, J.Y., Niu, Z., Gu, H.W., Braunstein, P. and Lang, J.P. (2020) Iron-Doped NiCo-MOF Hollow Nanospheres for Enhanced Electrocatalytic Oxygen Evolution. Nanoscale, 12, 14004-14010. [Google Scholar] [CrossRef
[28] Chen, L., Zhang, Y., Li, D., Wang, Y. and Duan, C. (2018) Magnesium-Regulated Oxygen Vacancies of Nickel Layered Double Hydroxides for Electrocatalytic Water Oxidation. Journal of Materials Chemistry A, 6, 18378-18383. [Google Scholar] [CrossRef
[29] Ding, Y., Yan, Z., Wang, G., Sang, H., Xu, Z. and Li, W. (2024) Regulating The Oxygen Vacancy and Electronic Structure of NiCo Layered Double Hydroxides by Molybdenum Doping for High-Power Hybrid Supercapacitors. Small, 20, Article ID: 2306382. [Google Scholar] [CrossRef] [PubMed]
[30] Liu, Y., Zhang, M., Hu, D., Li, R., Hu, K. and Yan, K. (2019) Ar Plasma-Exfoliated Ultrathin NiCo-Layered Double Hydroxide Nanosheets for Enhanced Oxygen Evolution. ACS Applied Energy Materials, 2, 1162-1168. [Google Scholar] [CrossRef
[31] Liu, S., Zhu, J., Sun, M., Ma, Z., Hu, K., Nakajima, T., Liu, X., Schmuki, P. and Wang, L. (2020) Promoting the Hydrogen Evolution Reaction through Oxygen Vacancies and Phase Transformation Engineering on Layered Double Hydroxide Nanosheets. Journal of Materials Chemistry A, 8, 2490-2497. [Google Scholar] [CrossRef
[32] Li, J., Shi, J., Hu, Y., Li, M. and Kang, Y. (2024) Plasma-Induced Vacancy Defects of Ru-Doped CoFe Layered Double Hydroxide for Superior Oxygen Evolution Activity. Journal of Alloys and Compounds, 976, Article ID: 173076. [Google Scholar] [CrossRef
[33] Tang, Y., Liu, Q., Dong, L., Wu, H.B. and Yu, X.Y. (2020) Activating the Hydrogen Evolution and Overall Water Splitting Performance of NiFe LDH by Cation Doping and Plasma Reduction. Applied Catalysis B: Environmental, 266, Article ID: 118627. [Google Scholar] [CrossRef
[34] Tang, Y., Shen, H., Cheng, J., Liang, Z., Qu, C., Tabassum, H. and Zou, R. (2020) Fabrication of Oxygen‐Vacancy Abundant NiMn‐Layered Double Hydroxides for Ultrahigh Capacity Supercapacitors. Advanced Functional Materials, 30, Article ID: 1908223. [Google Scholar] [CrossRef
[35] Liang, H., Jia, H., Lin, T., Wang, Z., Li, C., Chen, S., Qi, J., Cao, J., Fei, W. and Feng, J. (2019) Oxygen-Vacancy-Rich Nickel-Cobalt Layered Double Hydroxide Electrode for High-Performance Supercapacitors. Journal of Colloid and Interface Science, 554, 59-65. [Google Scholar] [CrossRef] [PubMed]
[36] Chen, X., Zhang, Y., Yang, J., Xiao, J.D., Yang, Z. and Wang, J. (2023) Boosting Oxygen Evolution Performance of Nickel-Iron Layered Double Hydroxides by Controlling Oxygen Vacancies and Structural Disorder via N-Butyllithium Treatment. Inorganic Chemistry, 62, 19795-19803. [Google Scholar] [CrossRef] [PubMed]
[37] Zhu, K., Wu, T., Li, M., Lu, R., Zhu, X. and Yang, W. (2017) Perovskites Decorated with Oxygen Vacancies and Fe-Ni Alloy Nanoparticles as High-Efficiency Electrocatalysts for the Oxygen Evolution Reaction. Journal of Materials Chemistry A, 5, 19836-19845. [Google Scholar] [CrossRef
[38] GarcÍA-Mota, M., Bajdich, M., Viswanathan, V., Vojvodic, A., Bell, A.T. and Nørskov, J.K. (2012) Importance of Correlation in Determining Electrocatalytic Oxygen Evolution Activity on Cobalt Oxides. The Journal of Physical Chemistry C, 116, 21077-21082. [Google Scholar] [CrossRef
[39] Suntivich, J., May, K.J., Gasteiger, H.A., Goodenough, J.B. and Shao-Horn, Y. (2011) A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles. Science, 334, 1383-1385. [Google Scholar] [CrossRef] [PubMed]
[40] Man, I.C., Su, H.Y., Calle-Vallejo, F., Hansen, H.A., MartÍNez, J.I., Inoglu, N.G., Kitchin, J., Jaramillo, T.F., Nørskov, J.K. and Rossmeisl, J. (2011) Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces. ChemCatChem, 3, 1159-1165. [Google Scholar] [CrossRef
[41] Lee, S., Nam, G., Sun, J., Lee, J.S., Lee, H.W., Chen, W., Cho, J. and Cui, Y. (2016) Enhanced Intrinsic Catalytic Activity of λ-MnO2 by Electrochemical Tuning and Oxygen Vacancy Generation. Angewandte Chemie International Edition, 55, 8599-8604. [Google Scholar] [CrossRef] [PubMed]
[42] Guo, Y., Tong, Y., Chen, P., Xu, K., Zhao, J., Lin, Y., Chu, W., Peng, Z., Wu, C. and Xie, Y. (2015) Engineering The Electronic State of a Perovskite Electrocatalyst for Synergistically Enhanced Oxygen Evolution Reaction. Advanced Materials, 27, 5989-5994. [Google Scholar] [CrossRef] [PubMed]
[43] Zhao, Z., Shao, Q., Xue, J., Huang, B., Niu, Z., Gu, H., Huang, X. and Lang, J. (2022) Multiple Structural Defects in Ultrathin NiFe-LDH Nanosheets Synergistically and Remarkably Boost Water Oxidation Reaction. Nano Research, 15, 310-316. [Google Scholar] [CrossRef
[44] Wu, K., Shi, L., Wang, Z., Zhu, Y., Tong, X., He, W., Wang, J., Zheng, L., Kang, Y., Shan, W., Wang, Z., Huang, A. and Jiang, B. (2023) A General Strategy to Generate Oxygen Vacancies in Bimetallic Layered Double Hydroxides for Water Oxidation. Chemical Communications, 59, 3138-3141. [Google Scholar] [CrossRef
[45] Wang, H., Yuan, Y., Gu, J., Jia, Z. Lu, Z., Bai, Z., Yang, L. and Yang, X. (2020) Facile One-Pot Synthesis of Layered Double Hydroxides Nanosheets with Oxyge N Vacancies Grown on Carbon Nanotubes for Efficient Oxygen Evolution Reaction. Journal of Power Sources, 467, Article ID: 228354. [Google Scholar] [CrossRef
[46] Liu, Y., Chen, Y., Ge, R., Li, W., Zhang, Y., Feng, L. and Che, R. (2020) 3D Freestanding Flower-Like Nickel-Cobalt Layered Double Hydroxides Enriched with Oxygen Vacancies as Efficient Electrocatalysts for Water Oxidation. Sustainable Materials and Technologies, 25, e00170. [Google Scholar] [CrossRef
[47] Liu, S., Zhang, H., Hu, E., Zhu, T., Zhou, C., Huang, Y., Ling, M., Gao, X. and Lin, Z. (2021) Boosting Oxygen Evolution Activity of NiFe-LDH Using Oxygen Vacancies and Morphological Engineering. Journal of Materials Chemistry A, 9, 23697-23702. [Google Scholar] [CrossRef
[48] Li, D., Li, T., Hao, G., Guo, W., Chen, S., Liu, G., Li, J. and Zhao, Q. (2020) IrO2 Nanoparticle-Decorated Single-Layer NiFe LDHs Nanosheets with Oxygen Vacancies for the Oxygen Evolution Reaction. Chemical Engineering Journal, 399, Article ID: 125738. [Google Scholar] [CrossRef
[49] Yuan, Z., Bak, S.M., Li, P., Jia, Y., Zheng, L., Zhou, Y., Bai, L., Hu, E., Yang, X.Q., Cai, Z., Sun, Y. and Sun, X. (2019) Activating Layered Double Hydroxide with Multivacancies by Memory Effect for Energy-Efficient Hydrogen Production at Neutral PH. ACS Energy Letters, 4, 1412-1418. [Google Scholar] [CrossRef
[50] Ding, Q., Yin, J., Huang, Y., Wang, C., Luo, H., Sun, S., Xu, Y. and Li, H. (2024) Construction of Porous Flower-Like Ru-Doped CoNiFe Layered Double Hydroxide for Supercapacitors and Oxygen Evolution Reaction Catalysts. Journal of Colloid and Interface Science, 664, 263-274. [Google Scholar] [CrossRef] [PubMed]
[51] Lin, Z., Li, X., Zhang, H., Xu, B.B., Wasnik, P., Li, H., Singh, M.V., Ma, Y., Li, T. and Guo, Z. (2023) Research Progress of MXenes and Layered Double Hydroxides for Supercapacitors. Inorganic Chemistry Frontiers, 10, 4358-4392. [Google Scholar] [CrossRef
[52] Jiang, H., Ke, Q., Qiu, X., Chen, J., Chen, P., Wang, S., Luo, X. and Rao, B. (2023) NiCo Layered Double Hydroxide Nanocages for High-Performance Asymmetric Supercapacitors. Inorganic Chemistry Frontiers, 10, 2154-2164. [Google Scholar] [CrossRef
[53] Wang, L. and Chen, X. (2022) NiCo Layered Double Hydroxide on Three-Dimensional Modified Graphite Paper for High-Performance Supercapacitors. Journal of Alloys and Compounds, 907, Article ID: 164411. [Google Scholar] [CrossRef
[54] Spahr, M.E., Novák, P., Schnyder, B., Haas, O. and Nesper, R. (1998) Characterization of Layered Lithium Nickel Manganese Oxides Synthesized by a Novel Oxidative Coprecipitation Method and Their Electrochemical Performance as Lithium Insertion Electrode Materials. Journal of the Electrochemical Society, 145, 1113. [Google Scholar] [CrossRef
[55] Cao, X.M., Liu, D., Sun, Z.J. and Zhang, Q. (2024) In Situ Construction of Core-Shell Structured Cobalt Oxide@Nickel-Cobalt-Layered Double Hydroxide Nanorods with Abundant Oxygen Vacancies towards Boosting Electrochemical Energy Storage. Inorganic Chemistry Frontiers, 11, 789-798. [Google Scholar] [CrossRef
[56] Zhai, T., Xie, S., Yu, M., Fang, P., Liang, C., Lu, X. and Tong, Y. (2014) Oxygen Vacancies Enhancing Capacitive Properties of MnO2 Nanorods for Wearable Asymmetric Supercapacitors. Nano Energy, 8, 255-263. [Google Scholar] [CrossRef
[57] Khazaee, Z., Mahjoub, A.R., Khavar, A.H.C., Srivastava, V. and Sillanpää, M. (2020) Preparation of Phosphorus-Modified BiOx as Versatile Catalyst for Enhanced Photo-Reduction of Cr(VI) and Oxidation of Organic Dyes. Solar Energy, 207, 1282-1299. [Google Scholar] [CrossRef
[58] Li, J., Liu, Z., Zhang, Q., Cheng, Y., Zhao, B., Dai, S., Wu, H.H., Zhang, K., Ding, D., Wu, Y., Liu, M. and Wang, M.S. (2019) Anion and Cation Substitution in Transition-Metal Oxides Nanosheets for High-Performance Hybrid Supercapacitors. Nano Energy, 57, 22-33. [Google Scholar] [CrossRef
[59] Zhou, G., Gao, X., Wen, S., Wu, X., Zhang, L., Wang, T., Zhao, P., Yin, J. and Zhu, W. (2022) Magnesium-Regulated Oxygen Vacancies of Cobalt-Nickel Layered Double Hydroxide Nanosheets for Ultrahigh Performance Asymmetric Supercapacitors. Journal of Colloid and Interface Science, 612, 772-781. [Google Scholar] [CrossRef] [PubMed]
[60] Zhang, H., Bai, Y., Chen, H., Wu, J., Li, C.M., Su, X. and Zhang, L. (2022) Oxygen-Defect-Rich 3D Porous Cobalt-Gallium Layered Double Hydroxide for High-Performance Supercapacitor Application. Journal of Colloid and Interface Science, 608, 1837-1845. [Google Scholar] [CrossRef] [PubMed]
[61] Wang, T., Liu, K., Gao, Z., Zeng, Z., Mao, R., Zhu, G., Ni, J., Xu, X., Jia, R. and Han, S. (2022) Oxygen Vacancy-Rich Flower-Like Nickel Cobalt Layered Double Hydroxides for Supercapacitors with Ultrahigh Capacity. Ceramics International, 48, 19798-19805. [Google Scholar] [CrossRef
[62] Jiang, S., Qiao, Y., Fu, T., Peng, W., Yu, T., Yang, B., Xia, R. and Gao, M. (2021) Integrated Battery-Capacitor Electrodes: Pyridinic N-Doped Porous Carbon-Coated Abundant Oxygen Vacancy Mn-Ni-Layered Double Oxide for Hybrid Supercapacitors. ACS Applied Materials & Interfaces, 13, 34374-34384. [Google Scholar] [CrossRef] [PubMed]
[63] Zhang, H., Lv, Y., Wu, X., Guo, J. and Jia, D. (2022) Electrodeposition Synthesis of High Performance MoO3-X@Ni-Co Layered Double Hydroxide Hierarchical Nanorod Arrays for Flexible Solid-State Supercapacitors. Chemical Engineering Journal, 431, Article ID: 133233. [Google Scholar] [CrossRef
[64] Xu, X., Lu, H., Xu, D., Zhou, P., Ying, Y., Li, L. and Liu, Y. (2023) Oxygen-Rich Vacancies CuCoLDH with 1D/2D Nanoarray Structure for High Performance Asymmetric Supercapacitor. Applied Surface Science, 614, Article ID: 156174. [Google Scholar] [CrossRef