基于纳米银SERS防伪图案防伪标签研究
Research on Anti-Counterfeiting Label Based on Nano-Silver SERS Anti-Counterfeiting Pattern
DOI: 10.12677/jsta.2024.123056, PDF,    科研立项经费支持
作者: 蒙 雪*, 黄国现, 何聪颖, 苏检德, 刘凯依, 邓天霞, 黄富城, 李燕玲, 宋树祥, 刘林生#:广西师范大学电子与信息工程学院/集成电路学院,广西类脑计算与智能芯片重点实验室/广西高校集成电路与微系统重点实验室,广西 桂林
关键词: 银纳米颗粒化学还原法表面增强拉曼散射防伪安全油墨Silver Nanoparticles Chemical Reduction Method Surface Enhanced Raman Scattering Anti-Counterfeiting Safety Ink
摘要: 近年来,研制成本低,安全性能好,光化学性质稳定的新型防伪材料是信息安全的关键。本文采用化学还原法制备银纳米粒子,并将不同配体组合与银纳米粒子及油墨混合,制备用于防伪标签的SERS安全油墨。混合配体改善了复杂性和扩展了编码容量,使防伪标签难以复制。另外,SERS安全油墨与柔性衬底结合,克服了传统标签的难以贴附性。
Abstract: In recent years, developing new anti-counterfeiting materials with low cost, good safety performance and stable photochemical properties is the key to information security. In this paper, silver nanoparticles were prepared by chemical reduction method, and different ligand combinations were mixed with silver nanoparticles and ink to prepare SERS security ink for anti-counterfeiting labels. Mixed ligand improves complexity and expands coding capacity so that anti-counterfeiting labels are difficult to copy. In addition, the combination of SERS security ink and flexible substrate overcomes the difficulty of label adhesion.
文章引用:蒙雪, 黄国现, 何聪颖, 苏检德, 刘凯依, 邓天霞, 黄富城, 李燕玲, 宋树祥, 刘林生. 基于纳米银SERS防伪图案防伪标签研究[J]. 传感器技术与应用, 2024, 12(3): 521-529. https://doi.org/10.12677/jsta.2024.123056

参考文献

[1] Arppe, R. and Sørensen, T. (2017) Physical Unclonable Functions Generated through Chemical Methods for Anti-Counterfeiting. Nature Reviews Chemistry, 1, Article No. 0031. [Google Scholar] [CrossRef
[2] Huo, Y., Yang, Z., Wilson, T., et al. (2022) Recent Progress in SERS-Based Anti-Counterfeit Labels. Advanced Materials Interfaces, 9, Article ID: 2200201. [Google Scholar] [CrossRef
[3] Cheng, H., Lu, Y., Zhu, D., et al. (2020) Plasmonic Nanopapers: Flexible, Stable and Sensitive Multiplex PUF Tags for Unclonable Anti-Counterfeiting Applications. Nanoscale, 12, 9471-9480. [Google Scholar] [CrossRef
[4] Zhao, S., Gao, M. and Li, J. (2021) Lanthanides-Based Luminescent Hydrogels Applied as Luminescent Inks for Anti-Counterfeiting. Journal of Luminescence, 236, Article ID: 118128. [Google Scholar] [CrossRef
[5] Muthamma, K., Sunil, D. and Shetty, P. (2021) Carbon Dots as Emerging Luminophores in Security Inks for Anti-Counterfeit Applications—An Up-to-Date Review. Applied Materials Today, 23, Article ID: 101050. [Google Scholar] [CrossRef
[6] Wu, S., Nan, J., Wu, Y., et al. (2022) Low-Angle-Dependent Anticounterfeiting Label Decoded by Alcohol Tissue Wiping Based on a Multilayer Photonic Crystal Structure. ACS Applied Materials & Interfaces, 14, 27048-27055. [Google Scholar] [CrossRef] [PubMed]
[7] Dubey, C., Yadav, A., Baloni, D., et al. (2023) Multi-Stimuli-Responsive and Dynamic Color Tunable Security Ink for Multilevel Anticounterfeiting. Methods and Applications in Fluorescence, 11, Article ID: 025001. [Google Scholar] [CrossRef] [PubMed]
[8] Zhou, Y., Zhao, G., Bian, J., et al. (2020) Multiplexed SERS Barcodes for Anti-Counterfeiting. ACS Applied Materials & Interfaces, 12, 28532-28538. [Google Scholar] [CrossRef] [PubMed]
[9] Ren, W., Lin, G., Clarke, C., et al. (2020) Optical Nanomaterials and Enabling Technologies for High-Security-Level Anticounterfeiting. Advanced Materials, 32, Article ID: 1901430. [Google Scholar] [CrossRef] [PubMed]
[10] 刘小杰. 一种纳米图案限定的银纳米颗粒与金膜复合结构制备及其SERS效应测量[J]. 冶金与材料, 2019, 39(4): 11-12 14.
[11] 黎小椿, 庞永丰, 苏可珍, 等. 表面增强拉曼光谱法测定农药残留的研究进展[J]. 食品科技, 2019, 44(12): 354-359. [Google Scholar] [CrossRef
[12] Li, D., Brunie, J., Sun, F., et al. (2022) Anti-Counterfeiting SERS Security Labels Derived from Silver Nanoparticles and Aryl Diazonium Salts. Nanoscale Advances, 4, 5037-5043. [Google Scholar] [CrossRef
[13] Jimenez de Aberasturi, D., Serrano-Montes, A.B., Langer, J., et al. (2016) Surface Enhanced Raman Scattering Encoded Gold Nanostars for Multiplexed Cell Discrimination. Chemistry of Materials, 28, 6779-6790. [Google Scholar] [CrossRef
[14] Huo, Y., Curry, S., Trowbridge, A., et al. (2021) Surface-Enhanced Raman Scattering-Based Molecular Encoding with Gold Nanostars for Anticounterfeiting Applications. Materials Advances, 2, 5116-5123. [Google Scholar] [CrossRef
[15] Shikha, S., Salafi, T., Cheng, J., et al. (2017) Versatile Design and Synthesis of Nano-Barcodes. Chemical Society Reviews, 46, 7054-7093. [Google Scholar] [CrossRef
[16] Li, D., Luo, Y., Onidas, D., He, L., Jin, M., Gazeau, F., Pinson, J. and Mangeney, C. (2021) Surface Functionalization of Nanomaterials by Aryl Diazonium Salts for Biomedical Sciences. Advances in Colloid and Interface Science, 294, Article ID: 102479. [Google Scholar] [CrossRef] [PubMed]
[17] Lee, P.C. and Meisel, D. (1982) Adsorption and Surface-Enhanced Raman of Dyes on Silver and Gold Sols. The Journal of Physical Chemistry, 86, 3391-3395. [Google Scholar] [CrossRef
[18] Pham, T.T.H., Vu, X.H., Dien, N.D., et al. (2023) Synthesis of Cuprous Oxide/Silver (Cu2O/Ag) Hybrid as Surface-Enhanced Raman Scattering Probe for Trace Determination of Methyl Orange. Royal Society Open Science, 10, Article ID: 221623. [Google Scholar] [CrossRef] [PubMed]
[19] Cao, Y., Liang, P., Dong, Q., Wang, D., Zhang, D., Tang, L., Wang, L., Jin, S., Ni, D. and Yu, Z. (2019) Facile Reduction Method Synthesis of Defective MoO2x Nanospheres Used for SERS Detection with High Chemical Enhancement. Analytical Chemistry, 91, 8683-8690. [Google Scholar] [CrossRef] [PubMed]
[20] 李春颖, 赖克强, 张源园, 等. 表面增强拉曼光谱检测鱼肉中禁用和限用药物研究[J]. 化学学报, 2013, 71(2): 221-226.
[21] 徐宁宁, 张芹, 郭伟, 等. Au@PVP核壳纳米粒子作为表面增强拉曼散射基底检测孔雀石绿[J]. 分析化学, 2016, 44(9): 1378-1384.