鼠李糖脂协同氮磷共改性活性炭/过一硫酸盐体系去除地下水中氧氟沙星
Association of Rhamnolipid and the System of Nitrogen-Phosphorus Co-Modified Activated Carbon/Peroxymonosulfate for Ofloxacin Removal from Groundwater
DOI: 10.12677/ms.2024.146100, PDF,   
作者: 陆艳星, 梁 艳*:广西大学资源环境与材料学院,广西 南宁
关键词: 氧氟沙星鼠李糖脂改性活性炭过一硫酸盐Ofloxacin Rhamnolipids Modified Activated Carbon Peroxymonosulfate
摘要: 本研究制备了一种非金属高效催化剂——氮磷共改性活性炭(NPAC),利用鼠李糖脂增强NPAC在多孔介质中的迁移能力和分散性,促进NPAC/过一硫酸盐(PMS)体系去除地下水中氧氟沙星;探究NPAC剂量、PMS浓度、氧氟沙星浓度、达西流速对NPAC/PMS体系去除氧氟沙星的影响。结果表明,在鼠李糖脂的协同作用下,NPAC/PMS体系在多孔介质环境中适用性较广,氧氟沙星的最高去除率达到84.30%。
Abstract: In this study, a metal-free and efficient catalyst, nitrogen-phosphorus co-modified activated carbon (NPAC), was prepared to facilitate the removal of ofloxacin from groundwater in the NPAC/ peroxymonosulfate (PMS) system by using rhamnolipids to enhance the mobility and dispersibility of NPAC in the porous medium. The influence of NPAC dosage, PMS concentration, ofloxacin concentration, and Darcy velocity on the removal of ofloxacin by NPAC/PMS system was investigated. Results showed that under the synergistic effect of rhamnolipids, the NPAC/PMS system was more widely applicable in porous media environments, with the highest removal rate of ofloxacin reaching 84.30%.
文章引用:陆艳星, 梁艳. 鼠李糖脂协同氮磷共改性活性炭/过一硫酸盐体系去除地下水中氧氟沙星[J]. 材料科学, 2024, 14(6): 889-897. https://doi.org/10.12677/ms.2024.146100

参考文献

[1] Lapworth, D.J., Baran, N., Stuart, M.E. and Ward, R.S. (2012) Emerging Organic Contaminants in Groundwater: A Review of Sources, Fate and Occurrence. Environmental Pollution, 163, 287-303. [Google Scholar] [CrossRef] [PubMed]
[2] Kibuye, F.A., Gall, H.E., Elkin, K.R., Swistock, B., Veith, T.L., Watson, J.E., et al. (2019) Occurrence, Concentrations, and Risks of Pharmaceutical Compounds in Private Wells in Central Pennsylvania. Journal of Environmental Quality, 48, 1057-1066. [Google Scholar] [CrossRef] [PubMed]
[3] Yu, Q., Zhang, Y., Liu, G., Shi, J., Wen, T. and Liu, M. (2022) A Magnetic Sludge Carbon Combined Persulfate-Based ISCO System for Leachate-Contaminated Groundwater Remediation. Journal of Water Process Engineering, 50, Article ID: 103331. [Google Scholar] [CrossRef
[4] Mousavi, S.A., Kamarehie, B., Almasi, A., Darvishmotevalli, M., Salari, M., Moradnia, M., et al. (2021) Removal of Rhodamine B from Aqueous Solution by Stalk Corn Activated Carbon: Adsorption and Kinetic Study. Biomass Conversion and Biorefinery, 13, 7927-7936. [Google Scholar] [CrossRef
[5] Pham, V.L., Kim, D. and Ko, S. (2020) Advanced Oxidative Degradation of Acetaminophen by Carbon Catalysts: Radical vs Non-Radical Pathways. Environmental Research, 188, 109767. [Google Scholar] [CrossRef] [PubMed]
[6] Liu, C., Hatton, J., Arnold, W.A., Simcik, M.F. and Pennell, K.D. (2020) In Situ Sequestration of Perfluoroalkyl Substances Using Polymer-Stabilized Powdered Activated Carbon. Environmental Science & Technology, 54, 6929-6936. [Google Scholar] [CrossRef] [PubMed]
[7] Manz, K.E., Kulaots, I., Greenley, C.A., Landry, P.J., Lakshmi, K.V., Woodcock, M.J., et al. (2023) Low-Temperature Persulfate Activation by Powdered Activated Carbon for Simultaneous Destruction of Perfluorinated Carboxylic Acids and 1,4-dioxane. Journal of Hazardous Materials, 442, Article ID: 129966. [Google Scholar] [CrossRef] [PubMed]
[8] 赵兴达. 羰基化活性炭催化过硫酸盐降解地下水中有机污染物的实验研究[D]: [硕士学位论文]. 北京: 中国石油大学, 2020.
[9] Septian, A., Kumar, A.V.N., Sivasankar, A., Choi, J., Hwang, I. and Shin, W.S. (2021) Colloidal Activated Carbon as a Highly Efficient Bifunctional Catalyst for Phenol Degradation. Journal of Hazardous Materials, 414, Article ID: 125474. [Google Scholar] [CrossRef] [PubMed]
[10] Chen, X., Oh, W., Hu, Z., Sun, Y., Webster, R.D., Li, S., et al. (2018) Enhancing Sulfacetamide Degradation by Peroxymonosulfate Activation with N-Doped Graphene Produced through Delicately-Controlled Nitrogen Functionalization via Tweaking Thermal Annealing Processes. Applied Catalysis B: Environmental, 225, 243-257. [Google Scholar] [CrossRef
[11] Zhu, S., Huang, X., Ma, F., Wang, L., Duan, X. and Wang, S. (2018) Catalytic Removal of Aqueous Contaminants on N-Doped Graphitic Biochars: Inherent Roles of Adsorption and Nonradical Mechanisms. Environmental Science & Technology, 52, 8649-8658. [Google Scholar] [CrossRef] [PubMed]
[12] Choong, Z., Lin, K.A., Lisak, G., Lim, T. and Oh, W. (2022) Multi-Heteroatom-Doped Carbocatalyst as Peroxymonosulfate and Peroxydisulfate Activator for Water Purification: A Critical Review. Journal of Hazardous Materials, 426, Article ID: 128077. [Google Scholar] [CrossRef] [PubMed]
[13] Liao, S., Ghosh, A., Becker, M.D., Abriola, L.M., Cápiro, N.L., Fortner, J.D., et al. (2021) Effect of Rhamnolipid Biosurfactant on Transport and Retention of Iron Oxide Nanoparticles in Water-Saturated Quartz Sand. Environmental Science: Nano, 8, 311-327. [Google Scholar] [CrossRef
[14] Liao, S., Liu, C., Pinchbeck, D., Cápiro, N.L., Fortner, J.D., Abriola, L.M., et al. (2021) Effects of Rhamnolipid Biosurfactant on the Dissolution and Transport of Silver Nanoparticles in Porous Media. Environmental Science: Nano, 8, 2492-2506. [Google Scholar] [CrossRef