增材制造CoCrFeNi系高熵合金微观组织与性能研究进展
Research Progress on the Microstructure and Properties of CoCrFeNi High-Entropy Alloys in Additive Manufacturing
摘要: 高熵合金(HEAs)因其独特的微观结构与卓越性能，在国防、航空航天及海洋装备等领域备受瞩目。但传统制备工艺在获得复杂几何形状、优异综合性能的高熵合金仍存在限制。增材制造过程具有的大温度梯度和快速凝固速率等工艺特征，为高性能微观组织的高熵合金的制备提供了一种先进技术方法。本文总结了以CoCrFeNi为代表的系列高熵合金在增材制造过程中的微观组织与性能的特征及改善途径，为CoCrFeNi系高熵合金的应用提供参考。
Abstract: High-Entropy Alloys (HEAs) have attracted much attention in the fields of defense, aerospace and marine equipment due to their unique microstructure and excellent properties. However, there are still limitations in the traditional preparation process to obtain high-entropy alloys with complex geometries and excellent comprehensive properties. The process characteristics of additive manufacturing process, such as large temperature gradient and fast solidification rate, provide an advanced technical method for the preparation of high-entropy alloys with high-performance microstructures. In this paper, the characteristics and improvement methods of the microstructure and properties of a series of high-entropy alloys represented by CoCrFeNi in the additive manufacturing process are summarized, so as to provide a reference for the application of CoCrFeNi high-entropy alloys.
文章引用：周佳敏, 陈玉梅, 刘奕, 肖宁, 胡瑶, 薛江, 彭涛, 李时春. 增材制造CoCrFeNi系高熵合金微观组织与性能研究进展[J]. 材料科学, 2024, 14(8): 1203-1215. https://doi.org/10.12677/ms.2024.148134

参考文献

[1] 周琦琛. 激光熔覆CoCrFeNi基高熵合金涂层的组织与性能研究[D]: [硕士学位论文]. 镇江: 江苏科技大学, 2023.
[2] 余文康. 激光熔覆CoCrFeNi-X高熵合金涂层的制备与性能研究[D]: [硕士学位论文]. 武汉: 华中科技大学, 2021.
[3] 姚旭凯. 双丝-电弧增材制造AlCoCrFeNi系高熵合金组织和性能的研究[D]: [硕士学位论文]. 温州: 温州大学, 2022
[4] 丁一, 胡振峰, 梁秀兵, 等. 高熵合金高温抗氧化性的研究进展[J]. 表面技术, 2021, 50(1): 162-172.
[5] 王友星. 激光沉积CoCrFeNi系高熵合金柱状晶-等轴晶转变及性能研究[D]: [硕士学位论文]. 南昌: 华东交通大学, 2023.
[6] 李德胜. 激光熔覆CoCrFeNiTi-(WC)x高熵合金复合涂层工艺参数及组织性能的研究[D]: [硕士学位论文]. 南京: 南京农业大学, 2021.
[7] 陈扬, 涂坚, 张琰斌, 等. 形变和退火对Fe47Mn30Co10Cr10B3间隙高熵合金微观组织结构演变的影响[J]. 材料研究学报, 2021, 35(2): 143-153.
[8] Gu, Z., Xi, S. and Sun, C. (2020) Microstructure and Properties of Laser Cladding and CoCr2.5FeNi2Tix High-Entropy Alloy Composite Coatings. Journal of Alloys and Compounds, 819, Article 152986. [Google Scholar] [CrossRef] 
[9] 左润燕, 孙荣禄, 牛伟, 等. 激光熔覆CoCrFeNiTix高熵合金涂层的组织与性能[J]. 表面技术, 2022, 51(3): 363-370.
[10] 宫书林, 王永东, 李艳春, 等. 激光熔覆CoCrFeNiTix高熵合金涂层的组织与性能[J]. 粉末冶金材料科学与工程, 2024, 29(2): 118-124.
[11] Lin, D., Xu, L., Jing, H., Han, Y., Zhao, L. and Minami, F. (2020) Effects of Annealing on the Structure and Mechanical Properties of FeCoCrNi High-Entropy Alloy Fabricated via Selective Laser Melting. Additive Manufacturing, 32, Article 101058. [Google Scholar] [CrossRef] 
[12] Tong, Z., Ren, X., Jiao, J., Zhou, W., Ren, Y., Ye, Y., et al. (2019) Laser Additive Manufacturing of FeCrCoMnNi High-Entropy Alloy: Effect of Heat Treatment on Microstructure, Residual Stress and Mechanical Property. Journal of Alloys and Compounds, 785, 1144-1159. [Google Scholar] [CrossRef] 
[13] Fan, N., Rafferty, A., Lupoi, R., Li, W., Xie, Y. and Yin, S. (2023) Microstructure Evolution and Mechanical Behavior of Additively Manufactured CoCrFeNi High-Entropy Alloy Fabricated via Cold Spraying and Post-Annealing. Materials Science and Engineering: A, 873, Article 144748. [Google Scholar] [CrossRef] 
[14] Chen, G., Zhu, Q., Chen, S., Yao, S., Wang, H., Zhao, L., et al. (2022) Influence of Heat Treatment on the Texture, Microstructure and Tensile Deformation Behaviours of Cold Rolled FeCoNiCr Sheets. Materials Science and Engineering: A, 848, Article 143412. [Google Scholar] [CrossRef] 
[15] Wu, Z., Bei, H., Otto, F., Pharr, G.M. and George, E.P. (2014) Recovery, Recrystallization, Grain Growth and Phase Stability of a Family of FCC-Structured Multi-Component Equiatomic Solid Solution Alloys. Intermetallics, 46, 131-140. [Google Scholar] [CrossRef] 
[16] Ranganathan, S. (2003) Alloyed Pleasures: Multimetallic Cocktails. Current Science, 85, 1404-1406.
[17] Joseph, J., Jarvis, T., Wu, X., Stanford, N., Hodgson, P. and Fabijanic, D.M. (2015) Comparative Study of the Microstructures and Mechanical Properties of Direct Laser Fabricated and Arc-Melted AlxCoCrFeNi High Entropy Alloys. Materials Science and Engineering: A, 633, 184-193. [Google Scholar] [CrossRef] 
[18] 易黄懿. 激光增材制造AlxCoCrFeNi系高熵合金相调控及其强韧化机理研究[D]: [硕士学位论文]. 长沙: 湖南大学, 2021.
[19] 李宇超. 同轴送粉激光增材制造AlxCoCrFeNi2.1系高熵合金凝固组织及性能[D]: [硕士学位论文]. 长沙: 湖南大学, 2020.
[20] 魏水淼, 马盼, 季鹏程, 等. 高熵合金增材制造研究进展[J]. 材料工程, 2021, 49(10): 1-17.
[21] Haase, C., Tang, F., Wilms, M.B., Weisheit, A. and Hallstedt, B. (2017) Combining Thermodynamic Modeling and 3D Printing of Elemental Powder Blends for High-Throughput Investigation of High-Entropy Alloys—Towards Rapid Alloy Screening and Design. Materials Science and Engineering: A, 688, 180-189. [Google Scholar] [CrossRef] 
[22] 邱贺方, 袁晓静, 罗伟蓬, 等. 增材制造AlCoCrFeNi2.1共晶高熵合金研究进展[J]. 材料工程, 2024, 52(1): 70-82.
[23] Ocelík, V., Janssen, N., Smith, N.S., et al. (2016) Additive Manufacturing of High-Entropy Alloys by Laser Processing. JOM, 68, 1810-1818. [Google Scholar] [CrossRef] 
[24] 王福超. 激光选区熔化CoCrFeNiMn高熵合金成形工艺优化及性能表征[D]: [硕士学位论文]. 武汉: 华中科技大学, 2019.
[25] Mohanty, A., Sampreeth, J.K., Bembalge, O., Hascoet, J.Y., Marya, S., Immanuel, R.J., et al. (2019) High Temperature Oxidation Study of Direct Laser Deposited AlxCoCrFeNi (X=0.3,0.7) High Entropy Alloys. Surface and Coatings Technology, 380, Article 125028. [Google Scholar] [CrossRef] 
[26] 秦青丰, 王云壮, 侯平, 等. 高熵合金增材制造造技术的研究进展[J]. 江苏理工学院学报, 2022, 28(6): 26-37, 46.
[27] 于丽莹, 王晨, 朱礼龙, 等. 激光增材制造AlxCoCrFeNi高熵合金的组织与性能[J]. 材料工程, 2024, 52(1): 220-230.
[28] Lu, H., Shen, Q., Chen, X., Wen, M. and Jayalakshmi, S. (2024) Dual Wire Arc Additive Manufacturing of Compositionally Graded Alx-Co-Cr-Fe-Ni High-Entropy Alloy. Journal of Materials Research and Technology, 29, 4052-4062. [Google Scholar] [CrossRef] 
[29] 沈晴凯. 绞丝电弧增材制造Al-Co-Cr-Fe-Ni高熵合金组织和性能研究[D]: [硕士学位论文]. 温州: 温州大学, 2021
[30] Niu, P., Li, R., Fan, Z., Cao, P., Zheng, D., Wang, M., et al. (2023) Inhibiting Cracking and Improving Strength for Additive Manufactured AlxCoCrFeNi High Entropy Alloy via Changing Crystal Structure from BCC-to-FCC. Additive Manufacturing, 71, Article 103584. [Google Scholar] [CrossRef] 
[31] 陈景润, 李珂, 王逸飞, 等. 激光表面重熔CoCrFeMnNi高熵合金组织及耐蚀性能研究[J]. 铸造, 2023, 72(10): 1244-1249.
[32] 刘广, 周溯源, 杨海威, 等. 3D打印CoCrFeMnNi高熵合金的微观组织、室温及低温力学性能[J]. 材料导报, 2020, 34(11): 11076-11080.
[33] 谢会起. 选区激光熔化成形CoCrFeMnNi高熵合金组织与性能研究[D]: [硕士学位论文]. 太原: 中北大学, 2022.
[34] 焦加飞. 激光增材制造CoCrFeMnNi高熵合金力学性能与热腐蚀行为研究[D]: [硕士学位论文]. 镇江: 江苏大学, 2020.
[35] 李田野. Mo和C对CoCrFeMnNi系高熵合金组织及性能的影响[D]: [硕士学位论文]. 西安: 西安工业大学, 2019.
[36] Wang, P., Huang, P., Ng, F.L., Sin, W.J., Lu, S., Nai, M.L.S., et al. (2019) Additively Manufactured CoCrFeNiMn High-Entropy Alloy via Pre-Alloyed Powder. Materials & Design, 168, Article 107576. [Google Scholar] [CrossRef] 
[37] Zhang, Z., Ma, P., Fang, Y., Yang, Z., Zhang, N., Prashanth, K.G., et al. (2023) Effect of NiCoFeAlTi High Entropy Intermetallic Reinforcement Particle Size on the Microstructure and Mechanical Properties of CoCrFeMnNi High-Entropy Alloy Composites Fabricated by Selective Laser Melting. Journal of Alloys and Compounds, 947, Article 169417. [Google Scholar] [CrossRef] 
[38] 汪克威, 董勇, 赵朕东, 曾卓见, 胡永俊, 章争荣. WC-10CoCrFeMnNi高熵硬质合金微观组织及力学性能研究[J]. 稀有金属与硬质合金, 2024, 52(2): 89-94, 109.
[39] 陈瑞润, 张淑婧, 秦刚, 等. Y添加对CoCrFeMnNi高熵合金组织及力学性能的影响[J]. 特种铸造及有色合金, 2022, 42(3): 286-291.
[40] 刘贺朋. 冷轧和退火对CoCrFeNiMnCx高熵合金组织和力学性能的影响[D]: [硕士学位论文]. 郑州: 郑州大学, 2022.
[41] 韩曦, 张红霞, 闫志峰, 等. 放电等离子烧结CoCrFeMnNi/6061Al复合材料的组织与力学性能研究[J]. 热加工工艺, 2021, 50(12): 77-79.
[42] 韩曦, 张红霞, 闫志峰, 等. CoCrFeMnNi/6061Al复合材料制备及微区力学性能研究[J]. 铸造技术, 2019, 40(7): 639-641.
[43] Čech, J., Čapek, J., Průša, F. and Haušild, P. (2022) Effect of the Processing Routes on the Properties of CoCrFeMnNi Alloy. Powder Metallurgy Progress, 22, 25-30. [Google Scholar] [CrossRef] 
[44] 杨天海. 石墨烯增强CoCrFeMnNi高熵合金微观组织和力学性能研究[D]: [硕士学位论文]. 郑州: 郑州大学, 2021.
[45] 姚小飞, 魏敬鹏, 吕煜坤, 李田野. (CoCrFeMnNi)97.02Mo2.98高熵合金σ相析出演变及力学性能[J]. 金属学报, 2020, 56(5): 769-775.
[46] Lu, Y., Dong, Y., Jiang, H., Wang, Z., Cao, Z., Guo, S., et al. (2020) Promising Properties and Future Trend of Eutectic High Entropy Alloys. Scripta Materialia, 187, 202-209. [Google Scholar] [CrossRef] 
[47] Melia, M.A., Carroll, J.D., Whetten, S.R., Esmaeely, S.N., Locke, J., White, E., et al. (2019) Mechanical and Corrosion Properties of Additively Manufactured CoCrFeMnNi High Entropy Alloy. Additive Manufacturing, 29, Article 100833. [Google Scholar] [CrossRef] 
[48] Li, H., Fu, W., Chen, T., Huang, Y., Ning, Z., Sun, J., et al. (2022) Toward Tunable Microstructure and Mechanical Properties in Additively Manufactured CoCrFeMnNi High Entropy Alloy. Journal of Alloys and Compounds, 924, Article 166513. [Google Scholar] [CrossRef] 

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