高分子材料衍生多孔碳的制备及其电化学性能研究
Preparation and Electrochemical Properties of Porous Carbon Derived from Polymer Materials
DOI: 10.12677/MS.2021.112019, PDF,   
作者: 尚浩然, 陆 露, 叶向荣*:浙江师范大学化学与生命科学学院,浙江 金华
关键词: 高分子葡萄糖超级电容器比表面积Macromolecule Glucose Supercapacitor Specific Surface Area
摘要: 为了制备出适合有机电解液的多孔碳材料,提高其电化学性能,本文利用高分子作为碳源,葡萄糖作为诱导剂,通过KOH活化,制备出3D交联多孔碳材料。通过XRD、拉曼、XPS、SEM等方法对其进行表征。组装成超级电容器,通过电化学测试表明,在1 A g−1下具有较高的比电容。在20 A g−1的电流密度下循环10,000次,还有66.2%的电容保持率。此外,在10 A g−1的高电流密度下,具有较小的电容衰减。
Abstract: In order to prepare porous carbon material suitable for organic electrolyte and improve its elec-trochemical performance, this paper used polymer as carbon source and glucose as inducer, and prepared 3D cross-linked porous carbon material through KOH activation. It was characterized by XRD, Raman, XPS and SEM. The supercapacitor was assembled and the electrochemical test showed that it had a high specific capacitance at 1 A g−1. There is still capacitance retention of 66.2% at a current density of 20 A g−1 for 10,000 cycles. Furthermore at a high current density of 10 A g−1, there is only a small capacitance attenuation.
文章引用:尚浩然, 陆露, 叶向荣. 高分子材料衍生多孔碳的制备及其电化学性能研究[J]. 材料科学, 2021, 11(2): 143-150. https://doi.org/10.12677/MS.2021.112019

参考文献

[1] Liu, W.W., Yan, X.B., Lang, J.W., et al. (2012) Flexible and Conductive Nanocomposite Electrode Based on Graphene Sheets and Cotton Cloth for Supercapacitor. Journal of Materials Chemistry, 22, 17245-17253. [Google Scholar] [CrossRef
[2] Wang, Y., Shi, Z., Huang, Y., et al. (2009) Supercapacitor Devices Based on Graphene Materials. Journal of Physical Chemistry C, 113, 13103-13107. [Google Scholar] [CrossRef
[3] Snook, G.A., Kao, P. and Best, A.S. (2011) Conducting-Polymer-Based Supercapacitor Devices and Electrodes. Journal of Power Sources, 196, 1-12. [Google Scholar] [CrossRef
[4] Yan, J. Fan, Z.J., Sun, W., et al. (2012) Advanced Asymmetric Supercapacitors Based on Ni(OH)2/Graphene and Porous Graphene Electrodes with High Energy Density. Advanced Functional Materials, 22, 2632-2641. [Google Scholar] [CrossRef
[5] Simon, P. and Gogotsi, Y. (2008) Materials for Electrochemical Capacitors. Nature Materials, 7, 845-854. [Google Scholar] [CrossRef] [PubMed]
[6] Yan, J., Fan, Z., Wei, T., et al. (2010) Fast and Reversible Surface Redox Reaction of Graphene-MnO2 Composites as Supercapacitor Electrodes. Carbon, 48, 3825-3833. [Google Scholar] [CrossRef
[7] Xue, J.L., Zhao, Y., Cheng, H.H., et al. (2013) An All-Cotton-Derived, Arbitrarily Foldable, High-Rate, Electrochemical Supercapacitor. Physical Chemistry Chemical Physics, 15, 8042-8045. [Google Scholar] [CrossRef] [PubMed]
[8] 南吉星. 生物质碳基复合材料的制备及其超级电容器性能研究[D]: [硕士学位论文]. 郑州: 郑州大学, 2019.
[9] Wang, S., Ren, Z., Li, J., et al. (2014) Cotton-Based Hollow Carbon Fibers with High Specific Surface Area Prepared by Ammonia Etching for Supercapacitor Application. RSC Advances, 4, 31300-31307. [Google Scholar] [CrossRef
[10] Zhou, Q., Ye, X., Wan, Z., et al. (2015) A Three-Dimensional Flexible Supercapacitor with Enhanced Performance Based on Lightweight, Conductive Graphene-Cotton Fabric Electrode. Journal of Power Sources, 296, 186-196. [Google Scholar] [CrossRef
[11] Li, Z.J., Lv, W., Zhang, C., et al. (2015) A Sheet-Like Porous Carbon for High-Rate Supercapacitors Produced by the Carbonization of an Eggplant. Carbon, 92, 11-14. [Google Scholar] [CrossRef
[12] Zhang, L., Zhu, Y., Zhao, W., et al. (2018) Facile One-Step Synthesis of Three-Dimensional Freestanding Hierarchical Porous Carbon for High Energy Density Supercapacitors in Organic Electrolyte. Journal of Electroanalytical Chemistry, 818, 51-57. [Google Scholar] [CrossRef