氢–氨能源转化中催化剂的设计策略
Design Strategy of Catalyst in Hydrogen-Ammonia Energy Conversion
摘要: 本文综述了直接氨燃料电池(DAFC)技术的最新进展,这是一种利用氨作为氢的替代能源的新型燃料电池技术。由于氨具有高能量密度、低成本、高安全性和易储运等优点,它被视为一种有前途的清洁能源载体。文章首先分析了全球能源需求的增长和环境污染问题的加剧,强调了开发可持续能源技术的重要性。随后,讨论了氢能源的优势和限制,并指出氨作为氢的替代品在解决燃料电池商业化瓶颈问题中的潜力。文中还介绍了电解水技术作为氢能源生产的关键环节,并探讨了直接氨燃料电池的工作原理及其环保和高效特性。最后,文章着重讨论了电催化反应机理、催化剂的设计策略,以及在提高电催化性能方面的挑战和机遇。
Abstract: This study reviews recent advances in direct ammonia fuel cell (DAFC) technology, a novel fuel cell technology that utilizes ammonia as an alternative energy source to hydrogen. Ammonia is regarded as a promising carrier of clean energy due to its advantages of high energy density, low cost, high safety and easy storage and transportation. Firstly, the paper analyzes the growth of global energy demand and the aggravation of environmental pollution, and emphasizes the importance of developing sustainable energy technology. Subsequently, the advantages and limitations of hydrogen energy are discussed, and the potential of ammonia as an alternative to hydrogen is pointed out in solving the bottleneck of fuel cell commercialization. The paper also introduces the water electrolysis technology as the key link of hydrogen energy production, and discusses the working principle, environmental protection and high efficiency characteristics of direct ammonia fuel cells. Finally, the paper focuses on the mechanism of electrocatalytic reaction, the design strategy of catalysts, and the challenges and opportunities in improving the performance of electrocatalysis.
文章引用:郭宝聪, 徐新楠, 许小慧, 程煜, 刘杰. 氢–氨能源转化中催化剂的设计策略[J]. 物理化学进展, 2024, 13(4): 658-669. https://doi.org/10.12677/japc.2024.134068

参考文献

[1] Tanaka, M., Takashima, R., Mori, S. and Oyama, T. (2017) Special Issue on Developing Sustainable Energy and Environmental Systems in Japan: Energy Crisis and Challenges. Journal of Energy Engineering, 143, 1-2. [Google Scholar] [CrossRef
[2] Maeda, K. and Domen, K. (2010) Photocatalytic Water Splitting: Recent Progress and Future Challenges. The Journal of Physical Chemistry Letters, 1, 2655-2661. [Google Scholar] [CrossRef
[3] Du, P. and Eisenberg, R. (2012) Catalysts Made of Earth-Abundant Elements (Co, Ni, Fe) for Water Splitting: Recent Progress and Future Challenges. Energy & Environmental Science, 5, 6012-6021. [Google Scholar] [CrossRef
[4] Gong, A. and Verstraete, D. (2017) Fuel Cell Propulsion in Small Fixed-Wing Unmanned Aerial Vehicles: Current Status and Research Needs. International Journal of Hydrogen Energy, 42, 21311-21333. [Google Scholar] [CrossRef
[5] Razi, F. and Dincer, I. (2022) Renewable Energy Development and Hydrogen Economy in MENA Region: A Review. Renewable and Sustainable Energy Reviews, 168, 112763. [Google Scholar] [CrossRef
[6] Midilli, A., Ay, M., Dincer, I. and Rosen, M.A. (2005) On Hydrogen and Hydrogen Energy Strategies. Renewable and Sustainable Energy Reviews, 9, 255-271. [Google Scholar] [CrossRef
[7] Liu, J., Liu, Y., Liu, N., Han, Y., Zhang, X., Huang, H., et al. (2015) Metal-Free Efficient Photocatalyst for Stable Visible Water Splitting via a Two-Electron Pathway. Science, 347, 970-974. [Google Scholar] [CrossRef] [PubMed]
[8] Lu, X., Du, B., Zhou, S., Zhu, W., Li, Y., Yang, Y., et al. (2023) Optimization of Power Allocation for Wind-Hydrogen System Multi-Stack PEM Water Electrolyzer Considering Degradation Conditions. International Journal of Hydrogen Energy, 48, 5850-5872. [Google Scholar] [CrossRef
[9] Winter, C. (2005) Into the Hydrogen Energy Economy? Milestones. International Journal of Hydrogen Energy, 30, 681-685. [Google Scholar] [CrossRef
[10] Abbasi, R., Setzler, B.P., Wang, J., Zhao, Y., Wang, T., Gottesfeld, S., et al. (2020) Low-Temperature Direct Ammonia Fuel Cells: Recent Developments and Remaining Challenges. Current Opinion in Electrochemistry, 21, 335-344. [Google Scholar] [CrossRef
[11] Ntais, S., Serov, A., Andersen, N.I., Roy, A.J., Cossar, E., Allagui, A., et al. (2016) Promotion of Ammonia Electrooxidation on Pt Nanoparticles by Nickel Oxide Support. Electrochimica Acta, 222, 1455-1463. [Google Scholar] [CrossRef
[12] Kang, Y., Wang, W., Li, J., Hua, C., Xue, S. and Lei, Z. (2017) High Performance Ptxeu Alloys as Effective Electrocatalysts for Ammonia Electro-Oxidation. International Journal of Hydrogen Energy, 42, 18959-18967. [Google Scholar] [CrossRef
[13] Schrock, R.R. (2006) Reduction of Dinitrogen. Proceedings of the National Academy of Sciences, 103, Article 17087. [Google Scholar] [CrossRef] [PubMed]
[14] de Levie, R. (1999) The Electrolysis of Water. Journal of Electroanalytical Chemistry, 476, 92-93. [Google Scholar] [CrossRef
[15] Okanishi, T., Okura, K., Srifa, A., Muroyama, H., Matsui, T., Kishimoto, M., et al. (2017) Comparative Study of Ammonia-Fueled Solid Oxide Fuel Cell Systems. Fuel Cells, 17, 383-390. [Google Scholar] [CrossRef
[16] Schüth, F., Palkovits, R., Schlögl, R. and Su, D.S. (2012) Ammonia as a Possible Element in an Energy Infrastructure: Catalysts for Ammonia Decomposition. Energy & Environmental Science, 5, 6278-6289. [Google Scholar] [CrossRef
[17] Cinti, G., Liso, V., Sahlin, S.L. and Araya, S.S. (2020) System Design and Modeling of a High Temperature PEM Fuel Cell Operated with Ammonia as a Fuel. Energies, 13, Article 4689. [Google Scholar] [CrossRef
[18] Sigal, C.T. and Vayenas, C.G. (1981) Ammonia Oxidation to Nitric Oxide in a Solid Electrolyte Fuel Cell. Solid State Ionics, 5, 567-570. [Google Scholar] [CrossRef
[19] Sun, H., Chen, L., Lian, Y., Yang, W., Lin, L., Chen, Y., et al. (2020) Topotactically Transformed Polygonal Mesopores on Ternary Layered Double Hydroxides Exposing Under-Coordinated Metal Centers for Accelerated Water Dissociation. Advanced Materials, 32, Article 2006784. [Google Scholar] [CrossRef] [PubMed]
[20] Liu, X., Liu, F., Yu, J., Xiong, G., Zhao, L., Sang, Y., et al. (2020) Charge Redistribution Caused by S, P Synergistically Active Ru Endows an Ultrahigh Hydrogen Evolution Activity of S-Doped Rup Embedded in N, P, S-Doped Carbon. Advanced Science, 7, Article 2001526. [Google Scholar] [CrossRef] [PubMed]
[21] Zhu, Y., Chen, H., Hsu, C., Lin, T., Chang, C., Chang, S., et al. (2019) Operando Unraveling of the Structural and Chemical Stability of P-Substituted Cose2 Electrocatalysts toward Hydrogen and Oxygen Evolution Reactions in Alkaline Electrolyte. ACS Energy Letters, 4, 987-994. [Google Scholar] [CrossRef
[22] Liu, H., Guan, J., Yang, S., Yu, Y., Shao, R., Zhang, Z., et al. (2020) Metal-Organic-Framework-Derived Co2P Nanoparticle/Multi-Doped Porous Carbon as a Trifunctional Electrocatalyst. Advanced Materials, 32, Article 2003649. [Google Scholar] [CrossRef] [PubMed]
[23] Shan, J., Ling, T., Davey, K., Zheng, Y. and Qiao, S. (2019) Transition-Metal-Doped Ruir Bifunctional Nanocrystals for Overall Water Splitting in Acidic Environments. Advanced Materials, 31, Article 1900510. [Google Scholar] [CrossRef] [PubMed]
[24] Yang, W., Zhang, S., Chen, Q., Zhang, C., Wei, Y., Jiang, H., et al. (2020) Conversion of Intercalated MoO3 to Multi-Heteroatoms-Doped MoS2 with High Hydrogen Evolution Activity. Advanced Materials, 32, Article 2001167. [Google Scholar] [CrossRef] [PubMed]
[25] Xiong, Q., Wang, Y., Liu, P., Zheng, L., Wang, G., Yang, H., et al. (2018) Cobalt Covalent Doping in MoS2 to Induce Bifunctionality of Overall Water Splitting. Advanced Materials, 30, Article 1801450. [Google Scholar] [CrossRef] [PubMed]
[26] Shi, Y., Zhou, Y., Yang, D., Xu, W., Wang, C., Wang, F., et al. (2017) Energy Level Engineering of MoS2 by Transition-Metal Doping for Accelerating Hydrogen Evolution Reaction. Journal of the American Chemical Society, 139, 15479-15485. [Google Scholar] [CrossRef] [PubMed]
[27] Deng, J., Li, H., Xiao, J., Tu, Y., Deng, D., Yang, H., et al. (2015) Triggering the Electrocatalytic Hydrogen Evolution Activity of the Inert Two-Dimensional MoS2 Surface via Single-Atom Metal Doping. Energy & Environmental Science, 8, 1594-1601. [Google Scholar] [CrossRef
[28] Liu, Y., Hua, X., Xiao, C., Zhou, T., Huang, P., Guo, Z., et al. (2016) Heterogeneous Spin States in Ultrathin Nanosheets Induce Subtle Lattice Distortion to Trigger Efficient Hydrogen Evolution. Journal of the American Chemical Society, 138, 5087-5092. [Google Scholar] [CrossRef] [PubMed]
[29] Liu, H., Li, X., Ge, L., Peng, C., Zhu, L., Zou, W., et al. (2020) Accelerating Hydrogen Evolution in Ru-Doped Fecop Nanoarrays with Lattice Distortion toward Highly Efficient Overall Water Splitting. Catalysis Science & Technology, 10, 8314-8324. [Google Scholar] [CrossRef
[30] Yang, S., Gong, Y., Manchanda, P., Zhang, Y., Ye, G., Chen, S., et al. (2018) Rhenium-Doped and Stabilized MoS2 Atomic Layers with Basal-Plane Catalytic Activity. Advanced Materials, 30, Article 1803477. [Google Scholar] [CrossRef] [PubMed]
[31] Wang, K., Guo, Y., Chen, Z., Wu, D., Zhang, S., Yang, B., et al. (2021) Regulating Electronic Structure of Two-Dimensional Porous Ni/Ni3N Nanosheets Architecture by Co Atomic Incorporation Boosts Alkaline Water Splitting. InfoMat, 4, e12251. [Google Scholar] [CrossRef
[32] Pan, Y., Sun, K., Lin, Y., Cao, X., Cheng, Y., Liu, S., et al. (2019) Electronic Structure and D-Band Center Control Engineering over M-Doped Cop (M=Ni, Mn, Fe) Hollow Polyhedron Frames for Boosting Hydrogen Production. Nano Energy, 56, 411-419. [Google Scholar] [CrossRef
[33] Greeley, J. and Nørskov, J.K. (2007) Large-Scale, Density Functional Theory-Based Screening of Alloys for Hydrogen Evolution. Surface Science, 601, 1590-1598. [Google Scholar] [CrossRef
[34] Yin, J., Jin, J., Zhang, H., Lu, M., Peng, Y., Huang, B., et al. (2019) Atomic Arrangement in Metal-Doped NiS2 Boosts the Hydrogen Evolution Reaction in Alkaline Media. Angewandte Chemie International Edition, 58, 18676-18682. [Google Scholar] [CrossRef] [PubMed]
[35] Ling, T., Zhang, T., Ge, B., Han, L., Zheng, L., Lin, F., et al. (2019) Well-Dispersed Nickel and Zinc-Tailored Electronic Structure of a Transition Metal Oxide for Highly Active Alkaline Hydrogen Evolution Reaction. Advanced Materials, 31, Article 1807771. [Google Scholar] [CrossRef] [PubMed]
[36] Zhang, J., Shang, X., Ren, H., Chi, J., Fu, H., Dong, B., et al. (2019) Modulation of Inverse Spinel Fe3O4 by Phosphorus Doping as an Industrially Promising Electrocatalyst for Hydrogen Evolution. Advanced Materials, 31, Article 1905107. [Google Scholar] [CrossRef] [PubMed]
[37] Yang, W., Zhang, S., Chen, Q., Zhang, C., Wei, Y., Jiang, H., et al. (2020) Conversion of Intercalated MoO3 to Multi-Heteroatoms-Doped MoS2 with High Hydrogen Evolution Activity. Advanced Materials, 32, Article 2001167. [Google Scholar] [CrossRef] [PubMed]
[38] Chen, Z., Fan, T., Yu, X., Wu, Q., Zhu, Q., Zhang, L., et al. (2018) Gradual Carbon Doping of Graphitic Carbon Nitride Towards Metal-Free Visible Light Photocatalytic Hydrogen Evolution. Journal of Materials Chemistry A, 6, 15310-15319. [Google Scholar] [CrossRef
[39] Wang, Y., Zhang, Y., Liu, Z., Xie, C., Feng, S., Liu, D., et al. (2017) Layered Double Hydroxide Nanosheets with Multiple Vacancies Obtained by Dry Exfoliation as Highly Efficient Oxygen Evolution Electrocatalysts. Angewandte Chemie International Edition, 56, 5867-5871. [Google Scholar] [CrossRef] [PubMed]
[40] Zhang, T., Wu, M., Yan, D., Mao, J., Liu, H., Hu, W., et al. (2018) Engineering Oxygen Vacancy on Nio Nanorod Arrays for Alkaline Hydrogen Evolution. Nano Energy, 43, 103-109. [Google Scholar] [CrossRef
[41] Tan, C., Luo, Z., Chaturvedi, A., Cai, Y., Du, Y., Gong, Y., et al. (2018) Preparation of High-Percentage 1T-Phase Transition Metal Dichalcogenide Nanodots for Electrochemical Hydrogen Evolution. Advanced Materials, 30, Article 1705509. [Google Scholar] [CrossRef] [PubMed]
[42] Tsai, C., Li, H., Park, S., Park, J., Han, H.S., Nørskov, J.K., et al. (2017) Electrochemical Generation of Sulfur Vacancies in the Basal Plane of MoS2 for Hydrogen Evolution. Nature Communications, 8, Article No. 15113. [Google Scholar] [CrossRef] [PubMed]
[43] Wu, W., Niu, C., Wei, C., Jia, Y., Li, C. and Xu, Q. (2019) Activation of MoS2 Basal Planes for Hydrogen Evolution by Zinc. Angewandte Chemie International Edition, 58, 2029-2033. [Google Scholar] [CrossRef] [PubMed]