渗硼温度对Inconel 625的微观组织及磨损性能的研究
Effect of Boronizing Temperature on Microstructure and Wear Properties of Inconel 625
DOI: 10.12677/amc.2025.132014, PDF,   
作者: 王宇祺, 詹嘉妮, 陈聪聪, 周 依:湖南工业大学材料与先进制造学院,湖南 株洲
关键词: 镍基合金Inconel 625固体渗硼耐磨性动力学Nickel-Based Alloy Inconel 625 Solid Boronizing Wear Resistance Kinetics
摘要: 研究了不同的渗硼温度(850℃~980℃)对Inconel 625镍基合金进行渗硼处理。研究表明,随着渗硼温度的增加,渗硼层的厚度会不断增加;当渗硼温度达到980℃时,渗层出现裂缝和孔洞;渗硼层主要由Ni3B和Cr2B等硬质相硼化物组成;在950℃时,合金的表面硬度达到1279.8 HV0.1的峰值,相较于基体263.4 HV0.1得到显著提升;渗硼处理后试样表面摩擦因数和截面磨痕面积显著减小;渗硼层厚度的平方与时间呈线性关系,B原子在Inconel 625渗层中的扩散激活能为227 KJ/mol1
Abstract: The boronizing treatment of Inconel 625 nickel-based alloy at different boronizing temperatures (850˚C~980˚C) was studied. The results show that the thickness of boronizing layer increases with the increase of boronizing temperature. When the boriding temperature reaches 980˚C, cracks and voids appear in the boriding layer. The boriding layer is mainly composed of hard phase borides such as Ni3B and Cr2B. At 950˚C, the surface hardness of the alloy reaches a peak of 1279.8 HV0.1, which is significantly improved compared with the matrix of 263.4 HV0.1; after boronizing treatment, the surface friction coefficient and cross-sectional wear scar area of the sample are significantly reduced. The square of the thickness of boronizing layer is linear with time, and the diffusion activation energy of B atom in Inconel 625 boronizing layer is 227 KJ/mol1.
文章引用:王宇祺, 詹嘉妮, 陈聪聪, 周依. 渗硼温度对Inconel 625的微观组织及磨损性能的研究[J]. 材料化学前沿, 2025, 13(2): 122-132. https://doi.org/10.12677/amc.2025.132014

参考文献

[1] Moskal, G., Niemiec, D., Chmiela, B., Kałamarz, P., Durejko, T., Ziętala, M., et al. (2020) Microstructural Characterization of Laser-Cladded Nicraly Coatings on Inconel 625 Ni-Based Superalloy and 316L Stainless Steel. Surface and Coatings Technology. [Google Scholar] [CrossRef
[2] Singh, V. and Meletis, E.I. (2006) Synthesis, Characterization and Properties of Intensified Plasma-Assisted Nitrided Superalloy Inconel 718. Surface and Coatings Technology, 201, 1093-1101. [Google Scholar] [CrossRef
[3] Sharma, Y.C., Kumar, R., Vidyasagar, V. and Bhardwaj, D. (2019) Low Temperature Plasma Ion Nitriding (PIN) of Inconel 690 Alloy. Materials Research Express, 6, Article 026559. [Google Scholar] [CrossRef
[4] Sun, Y. (2003) Kinetics of Layer Growth during Plasma Nitriding of Nickel Based Alloy Inconel 600. Journal of Alloys and Compounds, 351, 241-247. [Google Scholar] [CrossRef
[5] Ding, L., Hu, S., Wang, H. and Shen, J. (2022) Oxidation Behavior and High Temperature Friction and Wear Resistance of TiN-VC Reinforced VN Alloy/Co-Based Composite Coatings by Laser Cladding. Journal of Materials Engineering and Performance, 31, 3481-3492. [Google Scholar] [CrossRef
[6] Lee, K., Park, J., Kang, J., Lee, T.G., Kim, H. and Kim, K. (2020) Surface Modification of Solid-State Nanopore by Plasma-Polymerized Chemical Vapor Deposition of Poly (Ethylene Glycol) for Stable Device Operation. Nanotechnology, 31, Article 185503. [Google Scholar] [CrossRef] [PubMed]
[7] Yang, H., Kainuma, S., Yang, M., Muto, K. and Asano, T. (2021) Fundamental Study on Weather Resistance of Overlapping Layers between Al-5Mg Alloy Thermal Spray Coating and Heavy-Duty Paint Coating. IOP Conference Series: Materials Science and Engineering, 1165, Article 012003. [Google Scholar] [CrossRef
[8] Kulka, M., Makuch, N., Dziarski, P. and Piasecki, A. (2014) A Study of Nanoindentation for Mechanical Characterization of Chromium and Nickel Borides’ Mixtures Formed by Laser Boriding. Ceramics International, 40, 6083-6094. [Google Scholar] [CrossRef
[9] Petrova, R.S., Suwattananont, N., Pallegar, K.Κ. and Vangaveti, R. (2007) Boron Coating to Combat Corrosion and Oxidation. Corrosion Reviews, 25, 555-570. [Google Scholar] [CrossRef
[10] Leroy, L., Girault, P., Grosseau-Poussard, J.L. and Dinhut, J.F. (2002) Ion Implantation Reinforcement of the Protective Efficiency of Nickel in Artificial Sea-Water. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 198, 49-56. [Google Scholar] [CrossRef
[11] Mishigdorzhiyn, U., Chen, Y., Ulakhanov, N. and Liang, H. (2020) Microstructure and Wear Behavior of Tungsten Hot-Work Steel after Boriding and Boroaluminizing. Lubricants, 8, Article 26. [Google Scholar] [CrossRef
[12] Öge, M., Küçük, Y., Öge, T.Ö., Günen, A., Kanca, Y. and Gök, M.S. (2023) Effect of Boriding on High Temperature Tribological Behavior of Cocrmo Alloy. Tribology International, 187, Article 108697. [Google Scholar] [CrossRef
[13] Delgado-Brito, A.M., López-Suero, D., Ruiz-Ríos, A., García-León, R.A., Martínez-Trinidad, J., Oseguera-Peña, J., et al. (2019) Effect of the Diffusion Annealing Process in the Indentation Properties of Cobalt Boride Layer. Ceramics International, 45, 7767-7777. [Google Scholar] [CrossRef
[14] Mendoza, C.I.V., Mendoza, J.L.R., Galván, V.I., Hodgkins, R.P., Valdivieso, A.L., Palacios, L.L.S., et al. (2014) Effect of Substrate Roughness, Time and Temperature on the Processing of Iron Boride Coatings: Experimental and Statistical Approaches. International Journal of Surface Science and Engineering, 8, 71-91. [Google Scholar] [CrossRef
[15] Yan, P.X., Zhang, X.M., Xu, J.W., Wu, Z.G. and Song, Q.M. (2001) High-temperature Behavior of the Boride Layer of 45# Carbon Steel. Materials Chemistry and Physics, 71, 107-110. [Google Scholar] [CrossRef
[16] Mu, D., Shen, B., Yang, C. and Zhao, X. (2009) Microstructure Analysis of Boronized Pure Nickel Using Boronizing Powders with Sic as Diluent. Vacuum, 83, 1481-1484. [Google Scholar] [CrossRef
[17] Chen, T. and Koyama, S. (2020) Influence of Boriding Temperature on Microstructure and Tribological Properties of Titanium. Solid State Sciences, 107, Article 106369. [Google Scholar] [CrossRef
[18] Li, H., Qiao, M. and Zhou, C. (2014) Formation and Cyclic Oxidation Resistance of Hf-Co-Modified Aluminide Coatings on Nickel Base Superalloys. Materials Chemistry and Physics, 143, 915-920. [Google Scholar] [CrossRef
[19] Aytekin, H. and Akçin, Y. (2013) Characterization of Borided Incoloy 825 Alloy. Materials & Design, 50, 515-521. [Google Scholar] [CrossRef
[20] Lou, D.C., Solberg, J.K., Akselsen, O.M. and Dahl, N. (2009) Microstructure and Property Investigation of Paste Boronized Pure Nickel and Nimonic 90 Superalloy. Materials Chemistry and Physics, 115, 239-244. [Google Scholar] [CrossRef
[21] Campos, I., Ramírez, G., Figueroa, U., Martínez, J. and Morales, O. (2007) Evaluation of Boron Mobility on the Phases FeB, Fe2B and Diffusion Zone in AISI 1045 and M2 Steels. Applied Surface Science, 253, 3469-3475. [Google Scholar] [CrossRef
[22] Malakhov, D.V. and DeBoer, A.A. (2024) Thermodynamic Aspects of Powder-Pack Boronizing. Journal of Phase Equilibria and Diffusion, 45, 367-383. [Google Scholar] [CrossRef
[23] Ozbek, I. (2014) Mechanical Properties and Kinetics of Borided AISI M50 Bearing Steel. Arabian Journal for Science and Engineering, 39, 5185-5192. [Google Scholar] [CrossRef
[24] Atul, S.C., Adalarasan, R. and Santhanakumar, M. (2015) Study on Slurry Paste Boronizing of 410 Martensitic Stainless Steel Using Taguchi Based Desirability Analysis (TDA). International Journal of Manufacturing, Materials, and Mechanical Engineering, 5, 64-77. [Google Scholar] [CrossRef
[25] Ozdemir, O., Omar, M.A., Usta, M., Zeytin, S., Bindal, C. and Ucisik, A.H. (2008) An Investigation on Boriding Kinetics of AISI 316 Stainless Steel. Vacuum, 83, 175-179. [Google Scholar] [CrossRef
[26] Contreras, A., León, C., Jimenez, O., Sosa, E. and Pérez, R. (2006) Electrochemical Behavior and Microstructural Characterization of 1026 Ni-B Coated Steel. Applied Surface Science, 253, 592-599. [Google Scholar] [CrossRef
[27] Domínguez, M.O., Silva, J.Z., Keddam, M., Mejía, O.D. and Espinosa, M.E. (2015) Diffusion Model and Characterisation of Fe2B Layers on AISI 1018 Steel. International Journal of Surface Science and Engineering, 9, 281-297. [Google Scholar] [CrossRef
[28] Tabur, M., Izciler, M., Gul, F. and Karacan, I. (2009) Abrasive Wear Behavior of Boronized AISI 8620 Steel. Wear, 266, 1106-1112. [Google Scholar] [CrossRef