超级电容器用碳基材料的合成
Synthesis of Carbon-Based Materials for Supercapacitors
摘要: 电子设备的快速发展以及未来交通、能源生产需求促使研究人员研发具有更高功率容量、更长循环寿命和更高能量密度的新型设备。超级电容器是一种极具潜力的装置,具有出色的功率密度和极长的循环寿命。然而,超级电容由于表面积的可及性有限以及电解质的工作电位窗口受限,其能量密度较低。为解决能量密度低的问题,近年来人们积极开发新型高容量电极材料和新型、先进的电解质,如离子液体、凝胶聚合物甚至固态电解质。在这篇简短综述中,详细讨论了根据电荷存储机制分类的不同类型超级电容器。由于碳基活性材料是本文的重点,最后还讨论了诸如碳化、活化和掺杂等合成参数,这些参数会影响材料的物理化学特性,影响超级电容器的性能,最后给出结论和展望。
Abstract: The rapid development of electronic devices and the needs of future transportation and energy production have prompted researchers to develop new devices with higher power capacity, longer cycle life and higher energy density. Supercapacitors are a highly promising device with excellent power density and extremely long cycle life. However, supercapacitors have low energy densities due to the limited accessibility of surface area and the restricted working potential window of electrolytes. To solve the problem of low energy density, new high-capacity electrode materials and new, advanced electrolytes, such as ionic liquids, gel polymers and even solid-state electrolytes, have been actively developed in recent years. In this short review, different types of supercapacitors categorized according to the charge storage mechanism are discussed in detail. Since carbon-based active materials are the focus of this paper, the synthesis parameters such as carbonization, activation and doping, which affect the physicochemical properties of the materials and the performance of supercapacitors, are also discussed at the end, and finally conclusions and outlook are given.
文章引用:薛博桂, 陆露, 叶向荣. 超级电容器用碳基材料的合成[J]. 材料化学前沿, 2025, 13(2): 236-248. https://doi.org/10.12677/amc.2025.132026

参考文献

[1] Naseer, A., Hussain, M., Shakir, I., Abbas, Q., Yilmaz, D., Zahra, M., et al. (2020) The Robust Catalysts (Ni1-x-Mox/Doped Ceria and Zn1-x-Mox/Doped Ceria, x = 0.1 and 0.3) for Efficient Natural Gas Reforming in Solid Oxide Fuel Cells. Electrochimica Acta, 361, Article 137033. [Google Scholar] [CrossRef
[2] Shabbir, I., Mirzaeian, M. and Sher, F. (2022) Energy Efficiency Improvement Potentials through Energy Benchmarking in Pulp and Paper Industry. Cleaner Chemical Engineering, 3, Article 100058. [Google Scholar] [CrossRef
[3] Erdiwansyah, Mahidin, Husin, H., Nasaruddin, Zaki, M. and Muhibbuddin, (2021) A Critical Review of the Integration of Renewable Energy Sources with Various Technologies. Protection and Control of Modern Power Systems, 6, Article Article Article No. 3. [Google Scholar] [CrossRef
[4] Wei, Z., Zhao, J., He, H., Ding, G., Cui, H. and Liu, L. (2021) Future Smart Battery and Management: Advanced Sensing from External to Embedded Multi-Dimensional Measurement. Journal of Power Sources, 489, Article 229462. [Google Scholar] [CrossRef
[5] Wei, Z., Hu, J., He, H., Yu, Y. and Marco, J. (2023) Embedded Distributed Temperature Sensing Enabled Multistate Joint Observation of Smart Lithium-Ion Battery. IEEE Transactions on Industrial Electronics, 70, 555-565. [Google Scholar] [CrossRef
[6] Liu, K., Wei, Z., Zhang, C., Shang, Y., Teodorescu, R. and Han, Q. (2022) Towards Long Lifetime Battery: AI-Based Manufacturing and Management. IEEE/CAA Journal of Automatica Sinica, 9, 1139-1165. [Google Scholar] [CrossRef
[7] Zhang, Q., Yan, B., Feng, L., Zheng, J., You, B., Chen, J., et al. (2022) Progress in the Use of Organic Potassium Salts for the Synthesis of Porous Carbon Nanomaterials: Microstructure Engineering for Advanced Supercapacitors. Nanoscale, 14, 8216-8244. [Google Scholar] [CrossRef] [PubMed]
[8] Yan, B., Feng, L., Zheng, J., Zhang, Q., Jiang, S., Zhang, C., et al. (2022) High Performance Supercapacitors Based on Wood-Derived Thick Carbon Electrodes Synthesized via Green Activation Process. Inorganic Chemistry Frontiers, 9, 6108-6123. [Google Scholar] [CrossRef
[9] Chaparro-Garnica, J., Salinas-Torres, D., Mostazo-López, M.J., Morallón, E. and Cazorla-Amorós, D. (2021) Biomass Waste Conversion into Low-Cost Carbon-Based Materials for Supercapacitors: A Sustainable Approach for the Energy Scenario. Journal of Electroanalytical Chemistry, 880, Article 114899. [Google Scholar] [CrossRef
[10] Zhao, C., Zhao, C., Liu, Q., Liu, X., Lu, X., Pang, C., et al. (2021) Investigation of the Mechanism of Small Size Effect in Carbon-Based Supercapacitors. Nanoscale, 13, 12697-12710. [Google Scholar] [CrossRef] [PubMed]
[11] Wang, R., Li, X., Nie, Z., Zhao, Y. and Wang, H. (2021) Metal/Metal Oxide Nanoparticles-Composited Porous Carbon for High-Performance Supercapacitors. Journal of Energy Storage, 38, Article 102479. [Google Scholar] [CrossRef
[12] Ruiz-Montoya, J.G., Quispe-Garrido, L.V., Calderón Gómez, J.C., Baena-Moncada, A.M. and Gonçalves, J.M. (2021) Recent Progress in and Prospects for Supercapacitor Materials Based on Metal Oxide or Hydroxide/Biomass-Derived Carbon Composites. Sustainable Energy & Fuels, 5, 5332-5365. [Google Scholar] [CrossRef
[13] Forouzandeh, P., Kumaravel, V. and Pillai, S.C. (2020) Electrode Materials for Supercapacitors: A Review of Recent Advances. Catalysts, 10, Article 969. [Google Scholar] [CrossRef
[14] Liang, R., Du, Y., Xiao, P., Cheng, J., Yuan, S., Chen, Y., et al. (2021) Transition Metal Oxide Electrode Materials for Supercapacitors: A Review of Recent Developments. Nanomaterials, 11, Article 1248. [Google Scholar] [CrossRef] [PubMed]
[15] Kumar, S., Saeed, G., Zhu, L., Hui, K.N., Kim, N.H. and Lee, J.H. (2021) 0D to 3D Carbon-Based Networks Combined with Pseudocapacitive Electrode Material for High Energy Density Supercapacitor: A Review. Chemical Engineering Journal, 403, Article 126352. [Google Scholar] [CrossRef
[16] Qu, G., Wang, Z., Zhang, X., Zhao, S., Wang, C., Zhao, G., et al. (2022) Designing Flexible Asymmetric Supercapacitor with High Energy Density by Electrode Engineering and Charge Matching Mechanism. Chemical Engineering Journal, 429, Article 132406. [Google Scholar] [CrossRef
[17] Manasa, P., Sambasivam, S. and Ran, F. (2022) Recent Progress on Biomass Waste Derived Activated Carbon Electrode Materials for Supercapacitors Applications—A Review. Journal of Energy Storage, 54, Article 105290. [Google Scholar] [CrossRef
[18] Suriyakumar, S., Bhardwaj, P., Grace, A.N. and Stephan, A.M. (2021) Role of Polymers in Enhancing the Performance of Electrochemical Supercapacitors: A Review. Batteries & Supercaps, 4, 571-584. [Google Scholar] [CrossRef
[19] Kumar, R., Joanni, E., Sahoo, S., Shim, J., Tan, W.K., Matsuda, A., et al. (2022) An Overview of Recent Progress in Nanostructured Carbon-Based Supercapacitor Electrodes: From Zero to Bi-Dimensional Materials. Carbon, 193, 298-338. [Google Scholar] [CrossRef
[20] Abbas, Q., Mirzaeian, M., Abdelkareem, M.A., Al Makky, A., Yadav, A. and Olabi, A.G. (2022) Structural Tuneability and Electrochemical Energy Storage Applications of Resorcinol‐Formaldehyde‐Based Carbon Aerogels. International Journal of Energy Research, 46, 5478-5502. [Google Scholar] [CrossRef
[21] Abdelkareem, M.A., Abbas, Q., Mouselly, M., Alawadhi, H. and Olabi, A.G. (2022) High-Performance Effective Metal-Organic Frameworks for Electrochemical Applications. Journal of Science: Advanced Materials and Devices, 7, Article 100465. [Google Scholar] [CrossRef
[22] Saini, S., Chand, P. and Joshi, A. (2021) Biomass Derived Carbon for Supercapacitor Applications: Review. Journal of Energy Storage, 39, Article 102646. [Google Scholar] [CrossRef
[23] Jiang, G., Senthil, R.A., Sun, Y., Kumar, T.R. and Pan, J. (2022) Recent Progress on Porous Carbon and Its Derivatives from Plants as Advanced Electrode Materials for Supercapacitors. Journal of Power Sources, 520, Article 230886. [Google Scholar] [CrossRef
[24] Shao, Y., El-Kady, M.F., Sun, J., Li, Y., Zhang, Q., Zhu, M., et al. (2018) Design and Mechanisms of Asymmetric Supercapacitors. Chemical Reviews, 118, 9233-9280. [Google Scholar] [CrossRef] [PubMed]
[25] Miller, E.E., Hua, Y. and Tezel, F.H. (2018) Materials for Energy Storage: Review of Electrode Materials and Methods of Increasing Capacitance for Supercapacitors. Journal of Energy Storage, 20, 30-40. [Google Scholar] [CrossRef
[26] Wei, L., Deng, W., Li, S., Wu, Z., Cai, J. and Luo, J. (2022) Sandwich-Like Chitosan Porous Carbon Spheres/MXene Composite with High Specific Capacitance and Rate Performance for Supercapacitors. Journal of Bioresources and Bioproducts, 7, 63-72. [Google Scholar] [CrossRef
[27] Groß, A. and Sakong, S. (2019) Modelling the Electric Double Layer at Electrode/Electrolyte Interfaces. Current Opinion in Electrochemistry, 14, 1-6. [Google Scholar] [CrossRef
[28] Wu, J. (2022) Understanding the Electric Double-Layer Structure, Capacitance, and Charging Dynamics. Chemical Reviews, 122, 10821-10859. [Google Scholar] [CrossRef] [PubMed]
[29] Zhang, L.L. and Zhao, X.S. (2009) Carbon-Based Materials as Supercapacitor Electrodes. Chemical Society Reviews, 38, 2520-2531. [Google Scholar] [CrossRef] [PubMed]
[30] Zhao, X., Sánchez, B.M., Dobson, P.J. and Grant, P.S. (2011) The Role of Nanomaterials in Redox-Based Supercapacitors for Next Generation Energy Storage Devices. Nanoscale, 3, 839-855. [Google Scholar] [CrossRef] [PubMed]
[31] Augustyn, V., Simon, P. and Dunn, B. (2014) Pseudocapacitive Oxide Materials for High-Rate Electrochemical Energy Storage. Energy & Environmental Science, 7, 1597-1614. [Google Scholar] [CrossRef
[32] Permatasari, F.A., Irham, M.A., Bisri, S.Z. and Iskandar, F. (2021) Carbon-Based Quantum Dots for Supercapacitors: Recent Advances and Future Challenges. Nanomaterials, 11, Article 91. [Google Scholar] [CrossRef] [PubMed]
[33] Brousse, T., Bélanger, D. and Long, J.W. (2015) To Be or Not to Be Pseudocapacitive? Journal of The Electrochemical Society, 162, A5185-A5189. [Google Scholar] [CrossRef
[34] Winter, M. and Brodd, R.J. (2005) What Are Batteries, Fuel Cells, and Supercapacitors? (Chem. Rev.2003, 104, 4245-4269. Published on the Web 09/28/2004.). Chemical Reviews, 105, 1021. [Google Scholar] [CrossRef
[35] Bi, R., Wu, X., Cao, F., Jiang, L., Guo, Y. and Wan, L. (2010) Highly Dispersed RuO2 Nanoparticles on Carbon Nanotubes: Facile Synthesis and Enhanced Supercapacitance Performance. The Journal of Physical Chemistry C, 114, 2448-2451. [Google Scholar] [CrossRef
[36] Augustyn, V., Come, J., Lowe, M.A., Kim, J.W., Taberna, P., Tolbert, S.H., et al. (2013) High-Rate Electrochemical Energy Storage through Li+ Intercalation Pseudocapacitance. Nature Materials, 12, 518-522. [Google Scholar] [CrossRef] [PubMed]
[37] Akinwolemiwa, B., Peng, C. and Chen, G.Z. (2015) Redox Electrolytes in Supercapacitors. Journal of The Electrochemical Society, 162, A5054-A5059. [Google Scholar] [CrossRef
[38] Shakil, R., Shaikh, M.N., Shah, S.S., Reaz, A.H., Roy, C.K., Chowdhury, A., et al. (2021) Development of a Novel Bio‐Based Redox Electrolyte Using Pivalic Acid and Ascorbic Acid for the Activated Carbon‐Based Supercapacitor Fabrication. Asian Journal of Organic Chemistry, 10, 2220-2230. [Google Scholar] [CrossRef
[39] Kumar, R., Sahoo, S., Joanni, E. and Singh, R.K. (2022) A Review on the Current Research on Microwave Processing Techniques Applied to Graphene-Based Supercapacitor Electrodes: An Emerging Approach Beyond Conventional Heating. Journal of Energy Chemistry, 74, 252-282. [Google Scholar] [CrossRef
[40] Jiang, K. and Gerhardt, R.A. (2021) Fabrication and Supercapacitor Applications of Multiwall Carbon Nanotube Thin Films. C, 7, Article 70. [Google Scholar] [CrossRef
[41] Tiwari, A., Mukhiya, T., Muthurasu, A., Chhetri, K., Lee, M., Dahal, B., et al. (2021) A Review of Electrospun Carbon Nanofiber-Based Negative Electrode Materials for Supercapacitors. Electrochem, 2, 236-250. [Google Scholar] [CrossRef
[42] Heidarinejad, Z., Dehghani, M.H., Heidari, M., Javedan, G., Ali, I. and Sillanpää, M. (2020) Methods for Preparation and Activation of Activated Carbon: A Review. Environmental Chemistry Letters, 18, 393-415. [Google Scholar] [CrossRef
[43] Farma, R., Putri, A., Taer, E., Awitdrus, A. and Apriwandi, A. (2021) Synthesis of Highly Porous Activated Carbon Nanofibers Derived from Bamboo Waste Materials for Application in Supercapacitor. Journal of Materials Science: Materials in Electronics, 32, 7681-7691. [Google Scholar] [CrossRef
[44] Dı́az-Terán, J., Nevskaia, D.M., Fierro, J.L.G., López-Peinado, A.J. and Jerez, A. (2003) Study of Chemical Activation Process of a Lignocellulosic Material with KOH by XPS and XRD. Microporous and Mesoporous Materials, 60, 173-181. [Google Scholar] [CrossRef
[45] Gao, Y., Yue, Q., Gao, B. and Li, A. (2020) Insight into Activated Carbon from Different Kinds of Chemical Activating Agents: A Review. Science of The Total Environment, 746, Article 141094. [Google Scholar] [CrossRef] [PubMed]
[46] Zhang, L., Gu, H., Sun, H., Cao, F., Chen, Y. and Chen, G.Z. (2018) Molecular Level One-Step Activation of Agar to Activated Carbon for High Performance Supercapacitors. Carbon, 132, 573-579. [Google Scholar] [CrossRef
[47] Feng, X., Bai, Y., Liu, M., Li, Y., Yang, H., Wang, X., et al. (2021) Untangling the Respective Effects of Heteroatom-Doped Carbon Materials in Batteries, Supercapacitors and the ORR to Design High Performance Materials. Energy & Environmental Science, 14, 2036-2089. [Google Scholar] [CrossRef
[48] Mirzaeian, M., Abbas, Q., Gibson, D. and Mazur, M. (2019) Effect of Nitrogen Doping on the Electrochemical Performance of Resorcinol-Formaldehyde Based Carbon Aerogels as Electrode Material for Supercapacitor Applications. Energy, 173, 809-819. [Google Scholar] [CrossRef
[49] Dujearic-Stephane, K., Gupta, M., Kumar, A., Sharma, V., Pandit, S., Bocchetta, P., et al. (2022) The Effect of Modifications of Activated Carbon Materials on the Capacitive Performance: Surface, Microstructure, and Wettability. Journal of Composites Science, 5, Article 66. [Google Scholar] [CrossRef
[50] Wang, K., Chen, Y., Liu, Y., Zhang, H., Shen, Y., Pu, Z., et al. (2022) Plasma Boosted N, P, O Co-Doped Carbon Microspheres for High Performance Zn Ion Hybrid Supercapacitors. Journal of Alloys and Compounds, 901, Article 163588. [Google Scholar] [CrossRef
[51] Rehman, Z.U., Bilal, M., Hou, J., Ahmad, J., Ullah, S., Wang, X., et al. (2022) Metal Oxide-Carbon Composites for Supercapacitor Applications. In: Chaudhry, M.A., Hussain, R. and Butt, F.K., Eds., Metal Oxide-Carbon Hybrid Materials, Elsevier, 133-177. [Google Scholar] [CrossRef
[52] Sohouli, E., Adib, K., Maddah, B. and Najafi, M. (2022) Preparation of a Supercapacitor Electrode Based on Carbon Nano-Onions/Manganese Dioxide/Iron Oxide Nanocomposite. Journal of Energy Storage, 52, Article 104987. [Google Scholar] [CrossRef
[53] Shinde, P.A., Chodankar, N.R., Abdelkareem, M.A., Patil, S.J., Han, Y., Elsaid, K., et al. (2022) All Transition Metal Selenide Composed High‐Energy Solid‐State Hybrid Supercapacitor. Small, 18, Article 2200248. [Google Scholar] [CrossRef] [PubMed]
[54] Allado, K., Liu, M., Jayapalan, A., Arvapalli, D., Nowlin, K. and Wei, J. (2021) Binary MnO2/Co3O4 Metal Oxides Wrapped on Superaligned Electrospun Carbon Nanofibers as Binder Free Supercapacitor Electrodes. Energy & Fuels, 35, 8396-8405. [Google Scholar] [CrossRef