红外胶体量子点研究进展
Research Progress of Infrared Colloidal Quantum Dots
摘要: 胶体量子点由于其具有独特的量子效应,易于在多种衬底上沉积成为新一代红外探测的理想材料,被广泛应用于红外激光器、光通信、生物成像、夜视和遥感等领域。如何开发高工作效率的红外量子点器件是目前研究的热点。在本项工作中,综述了胶体量子点的制备方法、成核理论和器件制作方法,并且从量子点配体交换,改变量子点的表面配体影响其能带位置,从器件的能带结构入手提出选择合适配体构建能带结构,达到提升红外胶体量子点器件工作性能的目的,为红外胶体量子点的应用和器件设计具有重要的意义。
Abstract: Because of its unique quantum effect, colloidal quantum dots are easy to be deposited on a variety of substrates and become an ideal material for a new generation of infrared detection, which is widely used in infrared lasers, optical communication, biological imaging, night vision and remote sensing. How to develop infrared quantum dot devices with high working efficiency is the focus of current research. In this work, the preparation methods, nucleation theory and device fabrication methods of colloidal quantum dots are reviewed, and the energy band position is affected by the change of the surface ligands of the quantum dots through the ligand exchange of quantum dots, and the energy band structure of the device is proposed to select suitable ligands to construct the energy band structure, so as to improve the working performance of the infrared colloidal quantum dot device. It is of great significance for the application and device design of infrared colloidal quantum dots.
文章引用:陶建庆, 房丹, 闫昊, 楚学影, 翟英娇, 王晓华, 李金华. 红外胶体量子点研究进展[J]. 材料科学, 2025, 15(4): 879-888. https://doi.org/10.12677/ms.2025.154092

参考文献

[1] Brus, L.E. (1984) Electron-Electron and Electron-Hole Interactions in Small Semiconductor Crystallites: The Size Dependence of the Lowest Excited Electronic State. The Journal of Chemical Physics, 80, 4403-4409. [Google Scholar] [CrossRef
[2] Miller, E.M., Kroupa, D.M., Zhang, J., Schulz, P., Marshall, A.R., Kahn, A., et al. (2016) Revisiting the Valence and Conduction Band Size Dependence of Pbs Quantum Dot Thin Films. ACS Nano, 10, 3302-3311. [Google Scholar] [CrossRef] [PubMed]
[3] Cuharuc, A.S., Kulyuk, L.L., Lascova, R.I., Mitioglu, A.A. and Dikusar, A.I. (2012) Electrochemical Characterization of Pbs Quantum Dots Capped with Oleic Acid and Pbs Thin Films—A Comparative Study. Surface Engineering and Applied Electrochemistry, 48, 193-211. [Google Scholar] [CrossRef
[4] Ahn, Y., Eom, S.Y., Kim, G., Lee, J.H., Kim, B., Kim, D., et al. (2024) Silver Telluride Colloidal Quantum Dot Solid for Fast Extended Shortwave Infrared Photodetector. Advanced Science, 11, Article ID: 2407453. [Google Scholar] [CrossRef] [PubMed]
[5] Babu, K.S., Vijayan, C. and Devanathan, R. (2004) Strong Quantum Confinement Effects in Polymer-Based Pbs Nanostructures Prepared by Ion-Exchange Method. Materials Letters, 58, 1223-1226. [Google Scholar] [CrossRef
[6] Fan, J.Z., Vafaie, M., Bertens, K., Sytnyk, M., Pina, J.M., Sagar, L.K., et al. (2020) Micron Thick Colloidal Quantum Dot Solids. Nano Letters, 20, 5284-5291. [Google Scholar] [CrossRef] [PubMed]
[7] Hillhouse, H.W. and Beard, M.C. (2009) Solar Cells from Colloidal Nanocrystals: Fundamentals, Materials, Devices, and Economics. Current Opinion in Colloid & Interface Science, 14, 245-259. [Google Scholar] [CrossRef
[8] Son, J., Choi, D., Park, M., Kim, J. and Jeong, K.S. (2020) Transformation of Colloidal Quantum Dot: From Intraband Transition to Localized Surface Plasmon Resonance. Nano Letters, 20, 4985-4992. [Google Scholar] [CrossRef] [PubMed]
[9] Kagan, C.R. (2019) Flexible Colloidal Nanocrystal Electronics. Chemical Society Reviews, 48, 1626-1641. [Google Scholar] [CrossRef] [PubMed]
[10] Kim, J.Y., Voznyy, O., Zhitomirsky, D. and Sargent, E.H. (2013) 25th Anniversary Article: Colloidal Quantum Dot Materials and Devices: A Quarter‐century of Advances. Advanced Materials, 25, 4986-5010. [Google Scholar] [CrossRef] [PubMed]
[11] Maximov, M.V., Nadtochiy, A.M., Mintairov, S.A., Kalyuzhnyy, N.A., Kryzhanovskaya, N.V., Moiseev, E.I., et al. (2020) Light Emitting Devices Based on Quantum Well-dots. Applied Sciences, 10, Article 1038. [Google Scholar] [CrossRef
[12] Zhang, N., Tang, H., Shi, K., Wang, W., Deng, W., Xu, B., et al. (2019) High-Performance All-Solution-Processed Quantum Dot Near-Infrared-to-Visible Upconversion Devices for Harvesting Photogenerated Electrons. Applied Physics Letters, 115, Article ID: 221103. [Google Scholar] [CrossRef
[13] Meinardi, F., Bruni, F. and Brovelli, S. (2017) Luminescent Solar Concentrators for Building-Integrated Photovoltaics. Nature Reviews Materials, 2, Article No. 17072. [Google Scholar] [CrossRef
[14] Park, Y., Roh, J., Diroll, B.T., Schaller, R.D. and Klimov, V.I. (2021) Colloidal Quantum Dot Lasers. Nature Reviews Materials, 6, 382-401. [Google Scholar] [CrossRef
[15] Ji, C., Zhang, Y., Zhang, T., Liu, W., Zhang, X., Shen, H., et al. (2015) Temperature-Dependent Photoluminescence of Ag2se Quantum Dots. The Journal of Physical Chemistry C, 119, 13841-13846. [Google Scholar] [CrossRef
[16] Xue, X., Chen, M., Luo, Y., Qin, T., Tang, X. and Hao, Q. (2023) High-Operating-Temperature Mid-Infrared Photodetectors via Quantum Dot Gradient Homojunction. Light: Science & Applications, 12, Article No. 2. [Google Scholar] [CrossRef] [PubMed]
[17] Zhang, Y., Liu, B., Liu, Z. and Li, J. (2022) Research Progress in the Synthesis and Biological Application of Quantum Dots. New Journal of Chemistry, 46, 20515-20539. [Google Scholar] [CrossRef
[18] Hafiz, S.B., Al Mahfuz, M.M., Scimeca, M.R., Lee, S., Oh, S.J., Sahu, A., et al. (2020) Ligand Engineering of Mid-Infrared Ag2Se Colloidal Quantum Dots. Physica E: Low-Dimensional Systems and Nanostructures, 124, Article ID: 114223. [Google Scholar] [CrossRef
[19] Kagan, C.R., Lifshitz, E., Sargent, E.H. and Talapin, D.V. (2016) Building Devices from Colloidal Quantum Dots. Science, 353, aac5523. [Google Scholar] [CrossRef] [PubMed]
[20] Yang, H., Li, R., Zhang, Y., Yu, M., Wang, Z., Liu, X., et al. (2021) Colloidal Alloyed Quantum Dots with Enhanced Photoluminescence Quantum Yield in the NIR-II Window. Journal of the American Chemical Society, 143, 2601-2607. [Google Scholar] [CrossRef] [PubMed]
[21] Cibert, J., Petroff, P.M., Dolan, G.J., Pearton, S.J., Gossard, A.C. and English, J.H. (1986) Optically Detected Carrier Confinement to One and Zero Dimension in Gaas Quantum Well Wires and Boxes. Applied Physics Letters, 49, 1275-1277. [Google Scholar] [CrossRef
[22] Moreels, I., Justo, Y., De Geyter, B., Haustraete, K., Martins, J.C. and Hens, Z. (2011) Size-Tunable, Bright, and Stable Pbs Quantum Dots: A Surface Chemistry Study. ACS Nano, 5, 2004-2012. [Google Scholar] [CrossRef] [PubMed]
[23] Tang, J., Kemp, K.W., Hoogland, S., Jeong, K.S., Liu, H., Levina, L., et al. (2011) Colloidal-Quantum-Dot Photovoltaics Using Atomic-Ligand Passivation. Nature Materials, 10, 765-771. [Google Scholar] [CrossRef] [PubMed]
[24] Ba, K. and Wang, J. (2022) Advances in Solution-Processed Quantum Dots Based Hybrid Structures for Infrared Photodetector. Materials Today, 58, 119-134. [Google Scholar] [CrossRef
[25] Tamang, S., Lincheneau, C., Hermans, Y., Jeong, S. and Reiss, P. (2016) Chemistry of INP Nanocrystal Syntheses. Chemistry of Materials, 28, 2491-2506. [Google Scholar] [CrossRef
[26] Wang, F., Richards, V.N., Shields, S.P. and Buhro, W.E. (2013) Kinetics and Mechanisms of Aggregative Nanocrystal Growth. Chemistry of Materials, 26, 5-21. [Google Scholar] [CrossRef
[27] Qu, J., Goubet, N., Livache, C., Martinez, B., Amelot, D., Gréboval, C., et al. (2018) Intraband Mid-Infrared Transitions in Ag2Se Nanocrystals: Potential and Limitations for Hg-Free Low-Cost Photodetection. The Journal of Physical Chemistry C, 122, 18161-18167. [Google Scholar] [CrossRef
[28] Tang, H., Zhong, J., Chen, W., Shi, K., Mei, G., Zhang, Y., et al. (2019) Lead Sulfide Quantum Dot Photodetector with Enhanced Responsivity through a Two-Step Ligand-Exchange Method. ACS Applied Nano Materials, 2, 6135-6143. [Google Scholar] [CrossRef
[29] Yang, H., Ma, Z. and Wang, Q. (2024) Shortwave-Infrared Silver Chalcogenide Quantum Dots for Optoelectronic Devices. ACS Nano, 18, 30123-30131. [Google Scholar] [CrossRef] [PubMed]
[30] Zhang, H., Zhang, Y., Song, X., Yu, Y., Cao, M., Che, Y., et al. (2017) Highly Photosensitive Vertical Phototransistors Based on a Poly(3-Hexylthiophene) and PbS Quantum Dot Layered Heterojunction. ACS Photonics, 4, 584-592. [Google Scholar] [CrossRef
[31] Kim, M., Han, C., Yang, H. and Park, B. (2019) Band to Band Tunneling at the Zinc Oxide (ZnO) and Lead Selenide (PbSe) Quantum Dot Contact; Interfacial Charge Transfer at a ZnO/PbSe/ZnO Probe Device. Materials, 12, Article 2289. [Google Scholar] [CrossRef] [PubMed]
[32] Tang, X., Ackerman, M.M., Chen, M. and Guyot-Sionnest, P. (2019) Dual-Band Infrared Imaging Using Stacked Colloidal Quantum Dot Photodiodes. Nature Photonics, 13, 277-282. [Google Scholar] [CrossRef
[33] Zhang, Y., Li, Y., Xin, X., Wang, Y., Guo, P., Wang, R., et al. (2023) Internal Quantum Efficiency Higher than 100% Achieved by Combining Doping and Quantum Effects for Photocatalytic Overall Water Splitting. Nature Energy, 8, 504-514. [Google Scholar] [CrossRef
[34] Ning, Z., Voznyy, O., Pan, J., Hoogland, S., Adinolfi, V., Xu, J., et al. (2014) Air-Stable N-Type Colloidal Quantum Dot Solids. Nature Materials, 13, 822-828. [Google Scholar] [CrossRef] [PubMed]
[35] Lachance-Quirion, D., Tremblay, S., Lamarre, S.A., Méthot, V., Gingras, D., Camirand Lemyre, J., et al. (2014) Telegraphic Noise in Transport through Colloidal Quantum Dots. Nano Letters, 14, 882-887. [Google Scholar] [CrossRef] [PubMed]
[36] Song, J.H., Choi, H., Pham, H.T. and Jeong, S. (2018) Energy Level Tuned Indium Arsenide Colloidal Quantum Dot Films for Efficient Photovoltaics. Nature Communications, 9, Article No. 4267. [Google Scholar] [CrossRef] [PubMed]
[37] Choi, M., Kim, M., Lee, Y., Kim, T., Kim, J.H., Shin, D., et al. (2023) Tailored Band Edge Positions by Fractional Ligand Replacement of Nonconductive Colloidal Quantum Dot Films. The Journal of Physical Chemistry C, 127, 4825-4832. [Google Scholar] [CrossRef
[38] Boles, M.A., Ling, D., Hyeon, T. and Talapin, D.V. (2016) Erratum: The Surface Science of Nanocrystals. Nature Materials, 15, 364-364. [Google Scholar] [CrossRef] [PubMed]
[39] Ip, A.H., Kiani, A., Kramer, I.J., Voznyy, O., Movahed, H.F., Levina, L., et al. (2015) Infrared Colloidal Quantum Dot Photovoltaics via Coupling Enhancement and Agglomeration Suppression. ACS Nano, 9, 8833-8842. [Google Scholar] [CrossRef] [PubMed]
[40] Lan, X., Chen, M., Hudson, M.H., Kamysbayev, V., Wang, Y., Guyot-Sionnest, P., et al. (2020) Quantum Dot Solids Showing State-Resolved Band-Like Transport. Nature Materials, 19, 323-329. [Google Scholar] [CrossRef] [PubMed]
[41] Hafiz, S.B., Al Mahfuz, M.M. and Ko, D. (2020) Vertically Stacked Intraband Quantum Dot Devices for Mid-Wavelength Infrared Photodetection. ACS Applied Materials & Interfaces, 13, 937-943. [Google Scholar] [CrossRef] [PubMed]
[42] Hafiz, S.B., Al Mahfuz, M.M., Lee, S. and Ko, D. (2021) Midwavelength Infrared P-N Heterojunction Diodes Based on Intraband Colloidal Quantum Dots. ACS Applied Materials & Interfaces, 13, 49043-49049. [Google Scholar] [CrossRef] [PubMed]
[43] Brown, P.R., Kim, D., Lunt, R.R., Zhao, N., Bawendi, M.G., Grossman, J.C., et al. (2014) Energy Level Modification in Lead Sulfide Quantum Dot Thin Films through Ligand Exchange. ACS Nano, 8, 5863-5872. [Google Scholar] [CrossRef] [PubMed]
[44] Kroupa, D.M., Vörös, M., Brawand, N.P., McNichols, B.W., Miller, E.M., Gu, J., et al. (2017) Tuning Colloidal Quantum Dot Band Edge Positions through Solution-Phase Surface Chemistry Modification. Nature Communications, 8, Article No. 15257. [Google Scholar] [CrossRef] [PubMed]