疏水改性纳米材料在油田化学领域研究进展
Research Progress of Hydrophobically Modified Nanomaterials in Oilfield Chemistry
摘要: 岩石表面亲水特性会导致页岩发生剧烈水化作用,引起井壁失稳;此外,水分的侵入也会在储层中形成水相圈闭,造成含水饱和度升高,从而降低原油采收率。在油田化学领域,通过开发疏水改性纳米材料,可以改变井壁或储层岩石表面的润湿性,降低岩石表面的亲水性。从而达到抑制页岩水化、稳定井壁、提高储层油气渗流能力的目的,有效提高油气田的开发效果。本文将对疏水改性纳米材料的制备及其疏水原理进行分析,并详细阐述了疏水改性纳米材料在提高钻井液润滑性、稳定井壁、抑制页岩水化、提高原油采收率四个关于油田化学领域方面的研究进展。最后,随着对深地油气藏、非常规油气藏以及老油田等开发力度的不断加大,针对目前存在的挑战,展望了疏水改性纳米材料在未来发展方向,以满足其在油田化学领域中不断增长的需求。
Abstract: The hydrophilic property of the rock surface can lead to intense hydration of shale, causing instability of the wellbore. In addition, the intrusion of moisture will also form water phase traps in the reservoir, resulting in an increase in water saturation and thereby reducing the crude oil recovery rate. In the field of oilfield chemistry, by developing hydrophobic modified nanomaterials, the wettability of the wellbore or reservoir rock surface can be changed, and the hydrophilicity of the rock surface can be reduced. So as to achieve the purpose of inhibiting shale hydration, stabilizing the wellbore and improving the seepage capacity of oil and gas in the reservoir, and effectively enhancing the development effect of oil and gas fields. This paper will analyze the preparation of hydrophobic modified nanomaterials and their hydrophobic principles, and elaborate in detail the research progress of hydrophobic modified nanomaterials in four aspects related to oilfield chemistry: improving the lubricity of drilling fluid, stabilizing the wellbore, inhibiting shale hydration, and enhancing crude oil recovery rate. Finally, with the continuous increase in the development efforts of deep underground oil and gas reservoirs, unconventional oil and gas reservoirs, and old oil fields, in view of the current challenges, the future development directions of hydrophobic modified nanomaterials are expected to meet their growing demands in the field of oilfield chemistry.
文章引用:李思航, 秦灶均, 段芃杉, 杨淞, 王渐双, 徐建根. 疏水改性纳米材料在油田化学领域研究进展[J]. 矿山工程, 2025, 13(4): 721-728. https://doi.org/10.12677/me.2025.134082

参考文献

[1] 陆冲, 韩兴威, 郭帅, 等. 氧化石墨烯及其复合材料的应用研究进展[J]. 辽宁化工, 2025, 54(1): 142-145.
[2] 杨力铭, 高凤鸣, 高雪, 等. 新型水合物抑制剂HAY的研制与性能评价[J]. 辽宁化工, 2025, 54(2): 248-251.
[3] 李娇, 樊旭阳, 建伟伟, 等. 含碳纳米管混合纳米流体的热物性研究进展[J]. 辽宁化工, 2025, 54(2): 299-303.
[4] 张立, 张卫东, 沙鸥, 等. 改性纳米颗粒在提高原油采收率中的研究进展[J]. 石油化工, 2021, 50(9): 967-973.
[5] 李家豪, 范海明, 魏志毅, 等. 纳米材料在低渗透油藏中的研究进展及展望[J]. 化工进展, 2025, 44(3): 1485-1495.
[6] 应春业, 李新亮, 杨现禹, 等. 基于疏水型纳米二氧化硅的页岩气盐水钻井液[J]. 钻井液与完井液, 2016, 33(4): 41-46.
[7] 刘明辉, 马瑞廷, 魏莉. SiO2气凝胶绝热涂料的制备与绝热性能研究[J]. 辽宁化工, 2025, 54(2): 244-247.
[8] 李鑫林, 任永忠, 田佳苑, 等. 超疏水玉米秸秆粉末的制备及其油水分离性能[J]. 辽宁化工, 2024, 53(10): 1524-1527.
[9] Youm, J., Lee, S., Cho, I., Jeong, D., Bang, J., Park, H., et al. (2023) Highly Increased Hydrovoltaic Power Generation via Surfactant Optimization of Carbon Black Solution for Cellulose Microfiber Cylindrical Generator. Surfaces and Interfaces, 38, Article ID: 102853. [Google Scholar] [CrossRef
[10] Hoxha, B.B., van Oort, E. and Daigle, H. (2019) How Do Nanoparticles Stabilize Shale? SPE Drilling & Completion, 34, 143-158. [Google Scholar] [CrossRef
[11] 张亚, 吴宇, 侯珊珊. 多功能纳米材料在钻井液中的应用研究进展[J]. 化学与生物工程, 2024, 41(1): 13-20.
[12] 信瑶, 黄艳茹. 基于溶胶凝胶法的超疏水纺织物的制备及其性能[J]. 辽宁石油化工大学学报, 2025, 45(1): 41-49.
[13] Sonn, J.S., Lee, J.Y., Jo, S.H., Yoon, I., Jung, C. and Lim, J.C. (2018) Effect of Surface Modification of Silica Nanoparticles by Silane Coupling Agent on Decontamination Foam Stability. Annals of Nuclear Energy, 114, 11-18. [Google Scholar] [CrossRef
[14] 张馨. 超支化聚合物接枝纳米二氧化硅的泥页岩稳定剂研制[D]: [硕士学位论文]. 东营: 中国石油大学(华东), 2018.
[15] 谷一鸣, 刘晗, 齐程远, 等. 疏水改性阳离子絮凝剂的制备及其对含污泥废水絮凝性能研究[J]. 辽宁化工, 2025, 54(1): 14-18.
[16] Liu, F., Yao, H., Liu, Q., Wang, X., Dai, X., Zhou, M., et al. (2021) Nano-Silica/Polymer Composite as Filtrate Reducer in Water-Based Drilling Fluids. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 627, Article ID: 127168. [Google Scholar] [CrossRef
[17] 黄昱昊, 徐建根, 步文洋, 等. 钻井液用纳米封堵剂的研究与进展[J]. 辽宁化工, 2023, 52(3): 436-438+449.
[18] 郭淼, 杨广彬, 张玉娟, 等. 纳米SiO2在钻井液中的应用研究进展[J]. 化学研究, 2020, 31(4): 283-289+377.
[19] 孙金声, 李贺, 吕开河, 等. 纳米材料提高水基钻井液页岩稳定性研究进展[J]. 中国石油大学学报(自然科学版), 2024, 48(2): 74-82.
[20] 龙海锋, 王平全, 李前贵, 等. 纳米材料在水基钻井液中的应用研究进展[J]. 应用化工, 2021, 50(S1): 274-277.
[21] 孙德, 王平全, 李早元, 等. 纳米材料在页岩钻井工作液中的应用进展[J]. 当代化工研究, 2023(19): 5-7.
[22] 刘云鹏, 杨清海, 石白茹, 等. 仿生超疏水材料在石油化工中的应用进展[J]. 油田化学, 2023, 40(2): 374-379.
[23] 齐美瑛. 基于改性纳米SiO2复合驱油剂的制备与性能研究[D]: [硕士学位论文]. 开封: 河南大学, 2023.
[24] 崔帅东, 田晓雨, 任慧敏, 等. 溶胶-凝胶法制备超疏水玻璃及性能研究[J]. 辽宁化工, 2024, 53(10): 1528-1532.
[25] 王伟吉, 邱正松, 钟汉毅, 等. 钻井液用新型纳米润滑剂SD-NR的制备及特性[J]. 断块油气田, 2016, 23(1): 113-116.
[26] 张帅. 石墨烯基固体润滑剂的制备及摩擦学性能探究[D]: [硕士学位论文]. 镇江: 江苏大学, 2018.
[27] 李新建. 基于纳米封堵材料的钻井液漏失控制技术研究[J]. 化学工程与装备, 2025(2): 83-86.
[28] 于庆河, 刘涛, 吴文兵. 钻井液用纳米复合封堵剂的研制[J]. 石油工程建设, 2024, 50(S1): 76-80.
[29] 贾永红, 吴家乐, 张蔚, 等. 一种自适应纳米封堵剂的研制在水基钻井液体系中的应用研究[J]. 石油科学通报, 2024, 9(6): 1034-1043.
[30] 倪晓骁. 超疏水/双疏纳米流体的制备及其在岩石表面的自清洁特性研究[D]: [博士学位论文]. 北京: 中国石油大学(北京), 2020.
[31] Liu, F., Zhang, C., Li, X., Zhang, Z., Wang, X., Dai, X., et al. (2022) Investigation of the Inhibition Mechanism of Polymer/Nano-Silica Composite as Shale Inhibitor in Water-Based Drilling Fluids. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 636, Article ID: 128099. [Google Scholar] [CrossRef
[32] 王宇昊, 谭慧静, 罗龙, 等. 改性纳米CaCO3/PVA钻井液体系的构建与性能评价[J]. 应用化工, 2025, 54(3): 717-724+735.
[33] 蒲万芬, 杨帆, 任豪, 等. 纳米颗粒驱油机理研究进展[J]. 特种油气藏, 2024, 31(6): 1-9.
[34] 刘炳圻, 张春生, 张审琴, 等. β-环糊精功能化聚丙烯酰胺纳米复合材料的制备及其在提高采收率中的应用[J]. 当代化工, 2021, 50(4): 795-798.
[35] Giraldo, L.J., Gallego, J., Villegas, J.P., Franco, C.A. and Cortés, F.B. (2019) Enhanced Waterflooding with NiO/SiO2 0-D Janus Nanoparticles at Low Concentration. Journal of Petroleum Science and Engineering, 174, 40-48. [Google Scholar] [CrossRef