萤石的矿物学特征及其资源分布
Mineralogical Characteristics and Resource Distribution of Fluorite
DOI: 10.12677/ag.2025.157095, PDF,   
作者: 杨桂芳:桂林理工大学地球科学学院,广西 桂林;刘宸羽:城乡院(广州)有限公司,广东 广州
关键词: 萤石观赏石资源分布矿物学特征Fluorite Decoration Stones Resource Distribution of Fluorite Mineralogical Characteristics
摘要: 萤石是一种常见的钙卤化物矿物,因其能在紫外线、阴极射线照射或加热状态下发出蓝绿色荧光而得名。化学成分是氟化钙(化学式CaF2),其中钙、氟含量分别约为51%和49%,含少量的硅、铝、锰等元素,是自然界中氟含量最高的矿物,因此又称为“氟石”。萤石形态多样,色彩纷呈,可依据颜色、净度及颗粒大小确定其用途。萤石用途广泛,主要用于氟化工业和高价值附加产品的制造。也有一部分萤石因其形态、光泽和颜色较好而成为宝石、观赏石。萤石在全球的储量丰富,已探明的萤石矿储量达到3.1亿吨,是一种不可再生的战略非金属矿产资源。萤石资源储量第一为墨西哥,6800万吨;中国以4200万吨位列第二;南非以4100万吨位列第三。品质好的精品萤石在全球均有产出,且各具特色。如欧洲的德国、英国、法国,美洲的加拿大、美国、墨西哥和秘鲁,亚洲的中国、俄罗斯等国家和地区,产出的精品萤石在矿晶收藏界颇受欢迎。本文综合前人的研究成果,对萤石的矿物学特征及资源分布做出概述。
Abstract: Fluorite, a common calcium halide mineral, is named for its ability to fluoresce blue-green when exposed to ultraviolet light, cathode rays or heat. The chemical composition is calcium fluoride (chemical formula CaF2), in which the content of calcium and fluorine is about 51% and 49% respectively, containing a small amount of silicon, aluminum, manganese and other elements, which has the highest content of fluorine in nature, so it is also called “fluorspar”. Fluorite has a variety of forms and colors, and its use can be determined by color, clarity and particle size. Fluorite is widely used in the fluorine industry and in the manufacture of high value add-on products. There are also some fluorite because of its shape, luster and color which makes it better and becomes gems, Decoration Stones. Fluorite is a non-renewable strategic nonmetallic mineral resource with abundant reserves in the world, and the proven reserves of fluorite ore reach 310 million tons. The first fluorite resource reserves is Mexico, 68 million tons; China was second with 42 million tons; South Africa was third with 41 million tonnes. Good quality boutique fluorite in the world is produced, and each has its own characteristics. Such as Germany, the United Kingdom, France in Europe, Canada, the United States, Mexico and Peru in the Americas, China, Russia and other countries and regions in Asia, the output of high-quality fluorite in the crystal collection industry is very popular. This paper summarizes the mineralogical characteristics and resource distribution of fluorite based on previous research results.
文章引用:杨桂芳, 刘宸羽. 萤石的矿物学特征及其资源分布[J]. 地球科学前沿, 2025, 15(7): 1016-1024. https://doi.org/10.12677/ag.2025.157095

参考文献

[1] 张超. 试论多彩宝石——萤石[J]. 华北自然资源, 2021(1): 24-25.
[2] 彭德祥. 幽幽萤石 烁烁闪锌[J]. 珠宝科技, 2001(3): 33-34.
[3] 刘如春. 闲话夜明珠[J]. 国土资源, 2004(8): 59.
[4] 白林宝, 贺巧玲. 萤石的开发利用及发展动向[J]. 内蒙古石油化工, 2008(14): 38-39.
[5] 常丽华, 陈曼云, 金巍. 透明矿物薄片鉴定手册[M]. 北京: 地质出版社, 2006.
[6] 刘宁. 河南嵩县竹园沟萤石矿的宝石矿物学特征研究[D]: [硕士学位论文]. 北京: 中国地质大学(北京), 2021.
[7] 张惠芬, 曹俊臣, 谢先德. 天然萤石的喇曼光谱和发光谱研究[J]. 矿物学报, 1996(4): 394-402.
[8] 张冠英. 非金属矿产矿物学[M]. 武汉: 武汉工业大学出版社, 1989.
[9] 张蓓莉. 系统宝石学[M]. 北京: 地质出版社, 2006.
[10] Bill, H. and Calas, G. (1978) Color Centers, Associated Rare-Earth Ions and the Origin of Coloration in Natural Fluorites. Physics and Chemistry of Minerals, 3, 117-131. [Google Scholar] [CrossRef
[11] 黄从俊, 王奖臻, 李泽琴. 扬子西南缘拉拉10CG矿床萤石稀土元素地球化学特征[J]. 矿物学报, 2015, 35(1): 95-102.
[12] 刘文均. 花垣铅锌矿床中黑色萤石再研究[J]. 成都理工学院学报, 1999(2): 4-9.
[13] 马鸿文. 工业矿物与岩石[M]. 第2版. 北京: 化学工业出版社, 2005.
[14] 郑大中, 郑若锋. 萤石成矿机制的探讨[J]. 四川地质学报, 2005, 25(3): 149-155.
[15] Zhu, Z., Wang, D., Li, Y., Ke, C., Yu, H., Chen, Z., et al. (2024) Detail Mineralogical Study and Geochronological Framework of Bayan Obo (China) Nb Mineralization Recorded by in Situ U-Pb Dating of Columbite. Ore Geology Reviews, 165, Article ID: 105874. [Google Scholar] [CrossRef
[16] Morgan, J.W. and Wandless, G.A. (1980) Rare Earth Element Distribution in Some Hydrothermal Minerals: Evidence for Crystallographic Control. Geochimica et Cosmochimica Acta, 44, 973-980. [Google Scholar] [CrossRef
[17] 彭建堂, 胡瑞忠. 晴隆锑矿床中萤石的稀土元素特征及其指示意义[J]. 地质科学, 2002, 37(3): 277-287.
[18] 叶小蒙, 白峰. 英国威尔溪谷萤石的致色及发光机理研究[J]. 中国宝玉石, 2021(3): 7-12.
[19] 李新安, 刘铁庚, 赵云龙. 白云鄂博萤石染色机制研究[J]. 矿物学报, 1985(2): 164-168, 196.
[20] 郑惠, 李葆华, 罗英, 等. 萤石颜色研究现状[J]. 河南科技, 2015(12): 105-107.
[21] Harlan, C.J., Xu, Z., Walker, C.M., Michel, K.A., Reed, G.D. and Bankson, J.A. (2021) The Effect of Transmit B1 Inhomogeneity on Hyperpolarized [1‐13C]‐Pyruvate Metabolic MR Imaging Biomarkers. Medical Physics, 48, 4900-4908. [Google Scholar] [CrossRef] [PubMed]
[22] 张紫桐. 萤石的研究现状及其地质学意义[J]. 地球科学前沿(汉斯), 2021, 11(4): 473-479.
[23] 商朋强, 焦森, 屈云燕, 等. 世界萤石资源供需形势分析及对策建议[J]. 国土资源情报, 2020(10): 104-109.
[24] 李敬, 高永璋, 张浩. 中国萤石资源现状及可持续发展对策[J]. 中国矿业, 2017, 26(10): 7-14.
[25] 邢志芬, 申佳奇, 许博, 等. 西藏错那洞萤石的宝石矿物学特征[J]. 宝石和宝石学杂志(中英文), 2025, 27(1): 21-29.
[26] 张西文, 金中国, 郑明泓, 等. 黔西南白层萤石矿床成矿流体演化特征及其成因指示意义[J]. 矿物学报, 2025, 45(3): 500-511.
[27] 中华人民共和国国土资源部. 中国矿产资源报告2017 [M]. 北京: 地质出版社, 2017.
[28] 刘光华, 杰夫∙斯科费尔, 张亚男. 国际萤石晶体产地及特征[C]//国家珠宝玉石质量监督检验中心, 中国珠宝玉石首饰行业协会. 中国国际珠宝首饰学术交流会论文集(2017). 2017: 152-155.
[29] Carlson, E.H. (1991) Minerals of Ohio Divison of Geology Survey Bulletin. Ohio Department of Natural Resources.