铌酸钾钠基无铅压电陶瓷电学性能研究进展
Research Progress on the Electrical Properties of the Sodium Potassium Niobate Based Lead-Free Piezoelectric Ceramics
DOI: 10.12677/ms.2025.157162, PDF,    科研立项经费支持
作者: 陈 宏:武警工程大学基础部,陕西 西安
关键词: 铌酸钾钠无铅压电陶瓷电学性能Sodium Potassium Niobate Lead-Free Piezoelectric Ceramics Electrical Properties
摘要: 本文综述了铌酸钾钠(KNN)基无铅压电陶瓷电学性能的研究进展,分析了近年来相关研究成果的数据,探讨了影响其电学性能的因素及优化方法,旨在为该领域的进一步研究和应用提供参考。
Abstract: This paper reviewed the research progress on the electrical properties of the sodium potassium niobate (KNN) based lead-free piezoelectric ceramics, analyzed the data from recent relevant research achievements, and explored the factors influencing their electrical properties as well as optimization methods. The aim was to provide a reference for further research and application in this field.
文章引用:陈宏. 铌酸钾钠基无铅压电陶瓷电学性能研究进展[J]. 材料科学, 2025, 15(7): 1522-1529. https://doi.org/10.12677/ms.2025.157162

参考文献

[1] 姚方周, 吴超峰, 李敬锋, 等. 面向应用的(K, Na)NbO3基无铅压电陶瓷研究进展[J]. 硅酸盐学报, 2022, 50(3): 587-597.
[2] 肖舒琳, 戴中华, 李定妍, 等. 氧化镧掺杂铌酸钾钠陶瓷的电、光性能研究[J]. 无机材料学报, 2022, 37(5): 520-526.
[3] Guo, Y.P., Kakimoto, K. and Ohsato, H. (2004) Phase Transitional Behavior and Piezoelectric Properties of (Na0.5K0.5)NbO3-LiNbO3 Ceramics. Applied Physics Letters, 85, 4121-4123. [Google Scholar] [CrossRef
[4] 李香, 肖定全, 吴浪, 等. CuO对NKN基无铅压电陶瓷结构和性能的影响[J]. 功能材料, 2009, 40(3): 387-389.
[5] Wang, K., Yao, F.Z., Jo, W., et al. (2013) Temperature-Insensitive (K, Na) NbO3-Based Lead-Free Piezo Actuator Ceramics. Advanced Functional Materials, 23, 4079-4086. [Google Scholar] [CrossRef
[6] 陈宏. 碱土金属钛酸盐掺杂(K0.5Na0.5)NbO3陶瓷的烧结特性与电学性能[J]. 中国陶瓷, 2019, 55(5): 30-36.
[7] 徐泽, 娄路遥, 赵纯林, 等. Mn掺杂对KNbO3和(K0.5Na0.5)NbO3无铅钙钛矿陶瓷铁电压电性能的影响[J]. 物理学报, 2020, 69(12): 173-181.
[8] Hong, Y., Li, J., Wu, W.J., et al. (2018) Structure, Electricity, and Bandgap Modulation in Fe2O3-Doped Potassium Sodium Niobate Ceramics. Ceramics International, 44, 16069-16075. [Google Scholar] [CrossRef
[9] 陈燕, 江向平, 郑雪娟, 等. Co2O3掺杂对铌酸钾钠无铅压电陶瓷性能的影响[J]. 稀有金属材料与工程, 2009, 38(S2): 275-278.
[10] 张超, 任翔云, 周恒为, 等. 烧结温度对铌酸钾钠陶瓷的结构及压电性能的影响[J]. 伊犁师范学院学报(自然科学版), 2016, 10(3): 33-38.
[11] Egerton, L. and Dillon, D.M. (1959) Piezoelectric and Dielectric Properties of Ceramics in the System Potassium-Sodium Niobate. Journal of the American Ceramic Society, 42, 438-442. [Google Scholar] [CrossRef
[12] Li, J., Wang, K., Zhang, B. and Zhang, L. (2006) Ferroelectric and Piezoelectric Properties of Fine-Grained Na0.5K0.5NbO3 Lead-Free Piezoelectric Ceramics Prepared by Spark Plasma Sintering. Journal of the American Ceramic Society, 89, 706-709. [Google Scholar] [CrossRef
[13] 张辉, 王晓慧, 方建, 等. Li-, Sb-和Ta-共掺杂(K, Na)NbO3陶瓷的低温烧结[J]. 真空电子技术, 2014(1): 40-44.
[14] 黎露, 龚跃球, 龚伦军, 等. 溶剂热合成K0.5Na0.5Nb1xTaxO3粉体及其陶瓷的电学性能研究[C]//湘潭大学材料与光电物理学院. 第七届中国功能材料及其应用学术会议论文集(第5分册). 重庆: 《功能材料》期刊社, 2010: 196-199.
[15] 黎露. 铌酸钾钠基无铅压电陶瓷的制备及其电学性能研究[D]: [硕士学位论文]. 湘潭: 湘潭大学, 2011.
[16] Lv, X., Zhu, J.G., Xiao, D.Q., et al. (2020) Emerging New Phase Boundary in Potassium Sodium-Niobate Based Ceramics. Chemical Society Reviews, 49, 671-707. [Google Scholar] [CrossRef] [PubMed]
[17] Wang, X.P., Wu, J.G., Xiao, D.Q., et al. (2014) Giant Piezoelectricity in Potassium-Sodium Niobate Lead-Free Ceramics. Journal of the American Chemical Society, 136, 2905-2910. [Google Scholar] [CrossRef] [PubMed]
[18] Zhao, Z.H., Lv, Y.K., Dai, Y.J., Zhang, S.J., et al. (2020) Ultrahigh Electro-Strain in Acceptor-Doped KNN Lead-Free Piezoelectric Ceramics via Defect Engineering. SSRN Electronic Journal. [Google Scholar] [CrossRef
[19] Tian, S.S., Li, B. and Dai, Y.J. (2024) Defect Dipole Asymmetry Response Induces Electrobending Deformation in Thin Piezoceramics. Physical Review Letters, 133, Article ID: 186802. [Google Scholar] [CrossRef
[20] Tian, S.S., Wang, B.Q., Li, B., Guo, Y.P., Zhang, S. and Dai, Y. (2024) Defect Dipole Stretching Enables Ultrahigh Electrostrain. Science Advances, 10, eadn2829. [Google Scholar] [CrossRef] [PubMed]
[21] Zhang, M.H., Shen, C., Zhao, C.H., et al. (2022) Deciphering the Phase Transition-Induced Ultrahigh Piezoresponse in (K, Na)NbO3-Based Piezoceramics. Nature Communications, 13, Article No. 3434. [Google Scholar] [CrossRef] [PubMed]
[22] Liu, Y.X., Qu, W.B., Thong, H., Zhang, Y., Zhang, Y., Yao, F., et al. (2022) Isolated‐Oxygen-Vacancy Hardening in Lead‐Free Piezoelectrics. Advanced Materials, 34, Article 2202558. [Google Scholar] [CrossRef] [PubMed]