PECVD技术制备石墨烯的进展及展望
Progress and Prospect of Graphene Preparation by PECVD Technology
DOI: 10.12677/ms.2025.157164, PDF,   
作者: 杨帆宇:西北大学化学与材料科学学院,陕西 西安
关键词: 等离子体化学气相沉积石墨烯Plasma Chemical Vapor Deposition Graphene
摘要: 石墨烯随着工业的发展在各个领域中具有广阔的应用前景,同时单原子层的特殊结构对其各种特性有着显著的影响。因此,稳定制备规模化高质量和可控层数的石墨烯薄膜是实现其在各个领域中应用的基础。根据前人的研究基础,PECVD技术制备石墨烯可以实现石墨烯制备的低温化及高质量生产,调整各个参数对于制备石墨烯至关重要,如衬底、碳前驱体等。本文通过前人对石墨烯制备的研究,结合其相应的研究方法等,归纳了石墨烯制备研究中的问题以及难点,指出了石墨烯的主要研究进展,探讨了不同参数对石墨烯制备的影响,并在此基础上对石墨烯制备的应用前景进行了展望。
Abstract: Graphene has broad application prospects in various fields with the development of industry. Meanwhile, the special structure of a single atomic layer has a significant impact on its various properties. Therefore, the stable preparation of large-scale, high-quality graphene films with controllable layer numbers is the foundation for their application in various fields. Based on the research foundation of predecessors, the PECVD technology for preparing graphene can achieve low-temperature preparation and high-quality production of graphene. Adjusting various parameters is crucial for the preparation of graphene, such as substrates and carbon precursors. Based on the previous research on the preparation of graphene, combined with the corresponding research methods, etc., this paper summarizes the problems and difficulties in the research of graphene preparation, points out the main research progress of graphene, discusses the influence of different parameters on the preparation of graphene, and on this basis, looks forward to the application prospects of graphene preparation.
文章引用:杨帆宇. PECVD技术制备石墨烯的进展及展望[J]. 材料科学, 2025, 15(7): 1538-1545. https://doi.org/10.12677/ms.2025.157164

参考文献

[1] Zhang, Y., Small, J.P., Pontius, W.V. and Kim, P. (2005) Fabrication and Electric-Field-Dependent Transport Measurements of Mesoscopic Graphite Devices. Applied Physics Letters, 86, Article ID: 073104. [Google Scholar] [CrossRef
[2] Machado, B.F. and Serp, P. (2012) Graphene-Based Materials for Catalysis. Catalysis Science & Technology, 2, 54-75. [Google Scholar] [CrossRef
[3] Novoselov, K.S., Jiang, Z., Zhang, Y., Morozov, S.V., Stormer, H.L., Zeitler, U., et al. (2007) Room-Temperature Quantum Hall Effect in Graphene. Science, 315, 1379-1379. [Google Scholar] [CrossRef] [PubMed]
[4] Curl, R.F. and Smalley, R.E. (1988) Probing C60. Science, 242, 1017-1022. [Google Scholar] [CrossRef] [PubMed]
[5] Krätschmer, W., Lamb, L.D., Fostiropoulos, K. and Huffman, D.R. (1990) Solid C60: A New Form of Carbon. Nature, 347, 354-358. [Google Scholar] [CrossRef
[6] Iijima, S. (1991) Helical Microtubules of Graphitic Carbon. Nature, 354, 56-58. [Google Scholar] [CrossRef
[7] Novoselov, K.S., Geim, A.K., Morozov, S.V., Jiang, D., Zhang, Y., Dubonos, S.V., et al. (2004) Electric Field Effect in Atomically Thin Carbon Films. Science, 306, 666-669. [Google Scholar] [CrossRef] [PubMed]
[8] Berger, C., Song, Z., Li, T., Li, X., Ogbazghi, A.Y., Feng, R., et al. (2004) Ultrathin Epitaxial Graphite: 2D Electron Gas Properties and a Route toward Graphene-Based Nanoelectronics. The Journal of Physical Chemistry B, 108, 19912-19916. [Google Scholar] [CrossRef
[9] Eda, G., Fanchini, G. and Chhowalla, M. (2008) Large-Area Ultrathin Films of Reduced Graphene Oxide as a Transparent and Flexible Electronic Material. Nature Nanotechnology, 3, 270-274. [Google Scholar] [CrossRef] [PubMed]
[10] Stankovich, S., Dikin, D.A., Piner, R.D., Kohlhaas, K.A., Kleinhammes, A., Jia, Y., et al. (2007) Synthesis of Graphene-Based Nanosheets via Chemical Reduction of Exfoliated Graphite Oxide. Carbon, 45, 1558-1565. [Google Scholar] [CrossRef
[11] Reina, A., Jia, X., Ho, J., Nezich, D., Son, H., Bulovic, V., et al. (2009) Large Area, Few-Layer Graphene Films on Arbitrary Substrates by Chemical Vapor Deposition. Nano Letters, 9, 30-35. [Google Scholar] [CrossRef] [PubMed]
[12] Bittencourt, J.A. (2010) Fundamentals of Plasma Physics. Springer.
[13] Laroussi, M. (2015) Low-Temperature Plasma Jet for Biomedical Applications: A Review. IEEE Transactions on Plasma Science, 43, 703-712. [Google Scholar] [CrossRef
[14] Surowsky, B., Schlüter, O. and Knorr, D. (2014) Interactions of Non-Thermal Atmospheric Pressure Plasma with Solid and Liquid Food Systems: A Review. Food Engineering Reviews, 7, 82-108. [Google Scholar] [CrossRef
[15] 任想想. 等离子体增强化学气相沉积设备的技术要点及性能分析[J]. 模具制造, 2024, 24(7): 150-152.
[16] Sun, J., Schmidt, M.E., Muruganathan, M., Chong, H.M.H. and Mizuta, H. (2016) Large-Scale Nanoelectromechanical Switches Based on Directly Deposited Nanocrystalline Graphene on Insulating Substrates. Nanoscale, 8, 6659-6665. [Google Scholar] [CrossRef] [PubMed]
[17] Hong, H., Kim, N.Y., Yoon, A., Lee, S.W., Park, J., Yoo, J., et al. (2019) Synthesis of High-Quality Monolayer Graphene by Low-Power Plasma. Current Applied Physics, 19, 44-49. [Google Scholar] [CrossRef
[18] Siow, K.S., Britcher, L., Kumar, S. and Griesser, H.J. (2006) Plasma Methods for the Generation of Chemically Reactive Surfaces for Biomolecule Immobilization and Cell Colonization—A Review. Plasma Processes and Polymers, 3, 392-418. [Google Scholar] [CrossRef
[19] Hertwig, C., Reineke, K., Ehlbeck, J., Knorr, D. and Schlüter, O. (2015) Decontamination of Whole Black Pepper Using Different Cold Atmospheric Pressure Plasma Applications. Food Control, 55, 221-229. [Google Scholar] [CrossRef
[20] Geim, A.K. and Novoselov, K.S. (2007) The Rise of Graphene. Nature Materials, 6, 183-191. [Google Scholar] [CrossRef] [PubMed]
[21] Du, X., Skachko, I., Barker, A. and Andrei, E.Y. (2008) Approaching Ballistic Transport in Suspended Graphene. Nature Nanotechnology, 3, 491-495. [Google Scholar] [CrossRef] [PubMed]
[22] Bolotin, K.I., Sikes, K.J., Jiang, Z., Klima, M., Fudenberg, G., Hone, J., et al. (2008) Ultrahigh Electron Mobility in Suspended Graphene. Solid State Communications, 146, 351-355. [Google Scholar] [CrossRef
[23] Slonczewski, J.C. and Weiss, P.R. (1958) Band Structure of Graphite. Physical Review, 109, 272-279. [Google Scholar] [CrossRef
[24] 徐洋健, 肖润涵, 王浩敏, 于广辉. 化学气相沉积合成纯单层石墨烯的技术综述[J]. 固体电子学研究与进展, 2024, 44(6): 568-5751.
[25] Li, J., Wijaya, L.N.A., Jang, D.W., Hu, Y., You, J., Cai, Y., et al. (2024) 2D Materials‐Based Field‐Effect Transistor Biosensors for Healthcare. Small, 21, Article ID: 2408961. [Google Scholar] [CrossRef] [PubMed]
[26] Zhang, Y.H., Chen, Z.Y., Wang, B., Wu, Y.W., Jin, Z., Liu, X.Y., et al. (2013) Controllable Growth of Millimeter-Size Graphene Domains on Cufoil. Materials Letters, 96, 149-151. [Google Scholar] [CrossRef
[27] Yang, M., Sasaki, S., Suzuki, K. and Miura, H. (2016) Control of the Nucleation and Quality of Graphene Grown by Low-Pressure Chemical Vapor Deposition with Acetylene. Applied Surface Science, 366, 219-226. [Google Scholar] [CrossRef
[28] Han, Z., Kimouche, A., Kalita, D., Allain, A., Arjmandi‐Tash, H., Reserbat‐Plantey, A., et al. (2013) Homogeneous Optical and Electronic Properties of Graphene Due to the Suppression of Multilayer Patches during CVD on Copper Foils. Advanced Functional Materials, 24, 964-970. [Google Scholar] [CrossRef
[29] Reina, A., Jia, X., Ho, J., Nezich, D., Son, H., Bulovic, V., et al. (2009) Large Area, Few-Layer Graphene Films on Arbitrary Substrates by Chemical Vapor Deposition. Nano Letters, 9, 30-35. [Google Scholar] [CrossRef] [PubMed]
[30] Wu, T., Zhang, X., Yuan, Q., Xue, J., Lu, G., Liu, Z., et al. (2015) Fast Growth of Inch-Sized Single-Crystalline Graphene from a Controlled Single Nucleus on Cu-Ni Alloys. Nature Materials, 15, 43-47. [Google Scholar] [CrossRef] [PubMed]
[31] Guo, L., Zhang, Z., Sun, H., Dai, D., Cui, J., Li, M., et al. (2018) Direct Formation of Wafer-Scale Single-Layer Graphene Films on the Rough Surface Substrate by PECVD. Carbon, 129, 456-461. [Google Scholar] [CrossRef