湖泊热浪影响下锁磷剂对蔚然湖磷的钝化效果研究
Study on the Passivation Effect of Phosphorus Locking Agents on Phosphorus in Weiran Lake under the Influence of Lake Heatwaves
DOI: 10.12677/aep.2025.159137, PDF,    科研立项经费支持
作者: 王梓轩, 王毅鑫, 韩燕青*:滁州学院土木与建筑工程学院,安徽 滁州
关键词: 湖泊热浪锁磷剂Lake Heatwaves Phosphorus Phosphorus Locking Agents
摘要: 受持续的温室气体排放影响,全球气候不断变暖,湖泊热浪事件频发,深度影响湖泊各类功能的发挥。本研究以滁州学院校园湖泊蔚然湖为研究对象,探究镧系锁磷剂(LMB)在不同温度情景(常温25℃,热浪期35℃)下对磷的钝化效果和机制。室内模拟实验结果显示,30℃组水体总溶解性氮TDN、总溶解性磷TDP和可溶性磷酸盐SRP浓度分别比25℃组高11.26%、18.55%和15.11%,30℃ + LMB组水体TDN浓度比25℃ + LMB组高9.70%,水体TDP浓度和SRP浓度比25℃ + LMB组分别降低46.55%和77.74%。本研究表明湖泊热浪促进了蔚然湖沉积物氮磷释放,提高水体氮磷浓度,但镧系锁磷剂仍然有着较好的控磷效果,可显著抑制沉积物磷释放,降低蔚然湖水体磷浓度。
Abstract: Affected by persistent greenhouse gas emissions, global warming continues to intensify, leading to frequent lake heatwave events that profoundly impact various lake functions. This study focuses on Weiran Lake, a campus lake at Chuzhou University, to investigate the passivation effect and mechanisms of lanthanum-modified bentonite (LMB) on phosphorus under different temperature scenarios (normal temperature: 25˚C; heatwave period: 35˚C). Indoor simulation experiments revealed that the concentrations of total dissolved nitrogen (TDN), total dissolved phosphorus (TDP), and soluble reactive phosphorus (SRP) in the 30˚C group were 11.26%, 18.55%, and 15.11% higher, respectively, than those in the 25˚C group. In the 30˚C + LMB group, the TDN concentration was 9.70% higher than in the 25˚C + LMB group, while the TDP and SRP concentrations decreased by 46.55% and 77.74%, respectively, compared to the 25˚C + LMB group. The study reveals that lake heatwaves promote the release of nitrogen and phosphorus from sediments in Weiran Lake, increasing their concentrations in the water. However, LMB still demonstrates effective phosphorus control, significantly inhibiting sediment phosphorus release and reducing phosphorus levels in the lake water.
文章引用:王梓轩, 王毅鑫, 韩燕青. 湖泊热浪影响下锁磷剂对蔚然湖磷的钝化效果研究[J]. 环境保护前沿, 2025, 15(9): 1223-1230. https://doi.org/10.12677/aep.2025.159137

参考文献

[1] 朱广伟, 许海, 朱梦圆, 等. 三十年来长江中下游湖泊富营养化状况变迁及其影响因素[J]. 湖泊科学, 2019, 31(6): 1510-1524.
[2] 祁国华, 马晓双, 何诗瑜, 等. 基于多源遥感数据的巢湖水华长时序时空变化(2009-2018年)分析与发生概率预测[J]. 湖泊科学, 2021, 33(2): 414-427.
[3] Smith, V.H. and Schindler, D.W. (2009) Eutrophication Science: Where Do We Go from Here? Trends in Ecology & Evolution, 24, 201-207. [Google Scholar] [CrossRef] [PubMed]
[4] Schindler, D.W., Hecky, R.E., Findlay, D.L., Stainton, M.P., Parker, B.R., Paterson, M.J., et al. (2008) Eutrophication of Lakes Cannot Be Controlled by Reducing Nitrogen Input: Results of a 37-Year Whole-Ecosystem Experiment. Proceedings of the National Academy of Sciences of the United States of America, 105, 11254-11258. [Google Scholar] [CrossRef] [PubMed]
[5] Schindler, D.W., Carpenter, S.R., Chapra, S.C., Hecky, R.E. and Orihel, D.M. (2016) Reducing Phosphorus to Curb Lake Eutrophication Is a Success. Environmental Science & Technology, 50, 8923-8929. [Google Scholar] [CrossRef] [PubMed]
[6] Mackay, E., Maberly, S., Pan, G., Reitzel, K., Bruere, A., Corker, N., et al. (2014) Geoengineering in Lakes: Welcome Attraction or Fatal Distraction? Inland Waters, 4, 349-356. [Google Scholar] [CrossRef
[7] 张巧颖, 杜瑛珣, 罗春燕, 刘正文. 镧改性膨润土钝化湖泊中的磷及其生态风险的研究进展[J]. 湖泊科学, 2019, 31(6): 1499-1509.
[8] Dithmer, L., Lipton, A.S., Reitzel, K., Warner, T.E., Lundberg, D. and Nielsen, U.G. (2015) Characterization of Phosphate Sequestration by a Lanthanum Modified Bentonite Clay: A Solid-State NMR, EXAFS, and PXRD Study. Environmental Science & Technology, 49, 4559-4566. [Google Scholar] [CrossRef] [PubMed]
[9] Woolway, R.I., Albergel, C., Frölicher, T.L. and Perroud, M. (2022) Severe Lake Heatwaves Attributable to Human‐induced Global Warming. Geophysical Research Letters, 49, e2021GL097031. [Google Scholar] [CrossRef
[10] Woolway, R.I., Jennings, E., Shatwell, T., Golub, M., Pierson, D.C. and Maberly, S.C. (2021) Lake Heatwaves under Climate Change. Nature, 589, 402-407. [Google Scholar] [CrossRef] [PubMed]
[11] Tassone, S.J., Besterman, A.F., Buelo, C.D., Ha, D.T., Walter, J.A. and Pace, M.L. (2022) Increasing Heatwave Frequency in Streams and Rivers of the United States. Limnology and Oceanography Letters, 8, 295-304. [Google Scholar] [CrossRef
[12] Ding, S., Chen, M., Gong, M., Fan, X., Qin, B., Xu, H., et al. (2018) Internal Phosphorus Loading from Sediments Causes Seasonal Nitrogen Limitation for Harmful Algal Blooms. Science of the Total Environment, 625, 872-884. [Google Scholar] [CrossRef] [PubMed]
[13] Yindong, T., Xiwen, X., Miao, Q., Jingjing, S., Yiyan, Z., Wei, Z., et al. (2021) Lake Warming Intensifies the Seasonal Pattern of Internal Nutrient Cycling in the Eutrophic Lake and Potential Impacts on Algal Blooms. Water Research, 188, Article ID: 116570. [Google Scholar] [CrossRef] [PubMed]
[14] Jeppesen, E., Kronvang, B., Meerhoff, M., Søndergaard, M., Hansen, K.M., Andersen, H.E., et al. (2009) Climate Change Effects on Runoff, Catchment Phosphorus Loading and Lake Ecological State, and Potential Adaptations. Journal of Environmental Quality, 38, 1930-1941. [Google Scholar] [CrossRef] [PubMed]
[15] Qin, B., Deng, J., Shi, K., Wang, J., Brookes, J., Zhou, J., et al. (2021) Extreme Climate Anomalies Enhancing Cyanobacterial Blooms in Eutrophic Lake Taihu, China. Water Resources Research, 57, e2020WR029371. [Google Scholar] [CrossRef
[16] Kraemer, B.M., Anneville, O., Chandra, S., Dix, M., Kuusisto, E., Livingstone, D.M., et al. (2015) Morphometry and Average Temperature Affect Lake Stratification Responses to Climate Change. Geophysical Research Letters, 42, 4981-4988. [Google Scholar] [CrossRef
[17] 尹大强, 覃秋荣, 阎航. 环境因子对五里湖沉积物磷释放的影响[J]. 湖泊科学, 1994, 6(3): 240-244.
[18] Han, Y., Zhang, Y., He, H., Ning, X., Zhang, L. and Li, K. (2025) External Nitrogen Influxes Hinder the Efficacy of Lanthanum-Modified Bentonite (LMB) on Phosphorus and Algae Control in Shallow Lakes. Environmental Research, 264, Article ID: 120364. [Google Scholar] [CrossRef] [PubMed]
[19] Waajen, G., van Oosterhout, F., Douglas, G. and Lürling, M. (2016) Management of Eutrophication in Lake De Kuil (the Netherlands) Using Combined Flocculant—Lanthanum Modified Bentonite Treatment. Water Research, 97, 83-95. [Google Scholar] [CrossRef] [PubMed]
[20] Han, Y., Li, Q., He, H., Gu, J., Wu, Z., Huang, X., et al. (2021) Effect of Juvenile Omni-Benthivorous Fish (Carassius carassius) Disturbance on the Efficiency of Lanthanum-Modified Bentonite (LMB) for Eutrophication Control: A Mesocosm Study. Environmental Science and Pollution Research, 28, 21779-21788. [Google Scholar] [CrossRef] [PubMed]
[21] Copetti, D., Finsterle, K., Marziali, L., Stefani, F., Tartari, G., Douglas, G., et al. (2016) Eutrophication Management in Surface Waters Using Lanthanum Modified Bentonite: A Review. Water Research, 97, 162-174. [Google Scholar] [CrossRef] [PubMed]
[22] Han, Y., Zhang, Y., Li, Q., Lürling, M., Li, W., He, H., et al. (2021) Submerged Macrophytes Benefit from Lanthanum Modified Bentonite Treatment under Juvenile Omni‐Benthivorous Fish Disturbance: Implications for Shallow Lake Restoration. Freshwater Biology, 67, 672-683. [Google Scholar] [CrossRef
[23] Kang, L., Mucci, M. and Lürling, M. (2022) Influence of Temperature and Ph on Phosphate Removal Efficiency of Different Sorbents Used in Lake Restoration. Science of the Total Environment, 812, Article ID: 151489. [Google Scholar] [CrossRef] [PubMed]
[24] Ross, G., Haghseresht, F. and Cloete, T.E. (2008) The Effect of Ph and Anoxia on the Performance of Phoslock®, a Phosphorus Binding Clay. Harmful Algae, 7, 545-550. [Google Scholar] [CrossRef
[25] Mucci, M., Maliaka, V., Noyma, N.P., Marinho, M.M. and Lürling, M. (2018) Assessment of Possible Solid-Phase Phosphate Sorbents to Mitigate Eutrophication: Influence of pH and Anoxia. Science of the total Environment, 619, 1431-1440. [Google Scholar] [CrossRef] [PubMed]
[26] 郭禹慧, 黄晓军, 郑殿元, 李艳雨. 极端高温胁迫下中国城市脆弱性格局与影响因素[J]. 热带地理, 2021, 41(3): 596-608.
[27] 张玉星, 黄晓军, 郑殿元. 长江经济带高温热浪时空特征及脆弱性评价[J]. 长江流域资源与环境, 2023, 32(2): 440-450.
[28] Guo, G., Wang, D., Ren, Z., Yin, Q. and Gao, Y. (2021) A New Method to Estimate Heat Exposure Days and Its Impacts in China. Atmosphere, 12, Article 1294. [Google Scholar] [CrossRef
[29] Sun, Y., Zhang, X., Zwiers, F.W., Song, L., Wan, H., Hu, T., et al. (2014) Rapid Increase in the Risk of Extreme Summer Heat in Eastern China. Nature Climate Change, 4, 1082-1085. [Google Scholar] [CrossRef
[30] 谢志清, 杜银, 曾燕, 苗茜. 长江三角洲城市集群化发展对极端高温事件空间格局的影响[J]. 科学通报, 2017, 62(Z1): 233-244.